A new ligand (5-(2-benzamido-N-methylacetamido)-4-((3,4,5-trimethoxycyclohexa-1,3-dien-1-yl) methyl) pyrimidine-2-yl) amino)boric acid was synthesized by the reaction of trimethoprim amide derivative with boric acid, as well as its metal complexes with Co (II), Ni (II), and Pt (IV). Spectral methods such as Fourier transform infrared spectroscopy, ultraviolet-visible spectroscopy, and proton nuclear magnetic resonance (¹H-NMR) spectra, along with thermal analysis (TG/DTA), elemental analysis (CHN), and melting point, were used to characterize the synthesized compounds. This study conducted additional examinations for metal complexes, including molar conductivity, magnetic susceptibility, chloride, and metal content. All synthe

     Transition ion complexes have various commercial and technical uses, including antibacterial, antifungal, and anticancer medications and catalysts; their characteristics are critical regarding their kinetic impact. This study aims to synthesize new complexes, copper and nickel complexes, characterize them using spectral techniques, determine their chloride content, evaluate their anti-oxidant effect, and examine the antibacterial activity of the ligands and their complexes against gram-positive bacteria (Staphylococcus), gram-negative bacteria (Escherichia coli), and Candida albicans. All chemicals were used strictly as provided, with no additional purification; CuCl₂.2H₂O and Ni(

Open sets may be viewed as an extension of semi-open sets by applying the notions of semi-open sets and grill nano to nGs-open sets, with the following four goals in mind: The objective is to characterize nGs-open sets by examining and proving numerous of its attributes and comments. And investigate and define new kinds of functions based on the concept of nGs-open sets, using sets of nGs-open sets, we will define a new  type of Compact type and call it nGs-open compact then we will find the relationship between these new types of Compact type with nano compact. We will also talk about the relationship between nano grill semi-open sets and continuous functions and the relationship between nano grill semi-open sets and irresolute fun

Automatic Number Plate Recognition (ANPR) technology has offered a good solution tool for automating toll collection system processing and contributing solutions to complications such as traffic congestion, environmental problems, and operational inefficiencies. The investigation focuses on improving and organizing an ANPR-based system to allow smooth toll charging and letting cars pass through toll gates without pausing. The suggested system uses a deep learning algorithm and developed image processing techniques to consistently detect and recognize license plates of vehicles in real-time, even in difficult conditions, for instance, fast motion, low lighting, and bad weather. The ANPR system is connected to a centralize

     The problem of estimating the number of clusters k is considered one of the major challenges for partition clustering. The k-means algorithm is a division-based clustering method where only objects are entered into a set of K, and the algorithm decides the number group initially, but there is no specific way to estimate the best number for the cluster. The outcome of the clustering process can be better after being performed in more than one attempt. Therefore, the optimal count of iterations can be identified through a steady method in advance that can determine the time and number of rounds. So, the problem is finding the optimal number (k) in an easy and fast way. The aim of this paper is to use a genetic algorithm (GA) with

    The summary purpose of this work: We extending certain results on α-centralizer of inverse semiring under specific conditions, achieve new results on lie ideal of inverse semiring with some consequent collieries, generalize assorted α-centralizer for lie ideal of inverse semiring with some collieries, investigate significant theorems on jordan α-centralizer of prime inverse semiring and we extend certain results of centralizers and jordan centralizers on lie-ideals of prime semi-rings to prime inverse semi-ring, we generalizing the results of Mary in to α-centralizer on semiring, Also we generalize our results on lie ideals of inverse semiring. We extending the results of Shafiq,  Aslam,  Javed to  centraliz

In this paper, the effect of a couple–stress and other variables on the peristaltic flow of Sutterby fluid in an inclined asymmetric channel containing a porous medium with heat transfer is examined. In the presence of rotation and couple–stress, mathematical modeling is developed using constitutive equations based on the model of Sutterby fluid. In flow analysis, assumptions such as long wavelength approximation and low Reynolds number are used. The resulting nonlinear equation was numerically solved using the perturbation method. The effects of various physical parameters such as the couple-stress parameter, the Grashof number, the Hartmann number, the Reynold number, the Froude number, the Hall parameter, the Darcy number, the mag

The main purpose of this paper is to study a predator – prey dynamical system consisting of three species prey, specialized predator and generalist predator namely H (t), I (t) and J (t) respectively, w food web and refuge for the prey and specialized predator population. The consider system has five equilibrium points  A₀=(0, 0, 0),  A₁=(1, 0, 0), A₂=(h, i, 0), A₃=(h, 0, j), and the positive equilibrium point A₄=(h, i, j)   .The stability and bifurcation of the equilibrium points was studied and the main influence was the qualitative behavior of the solution. It was found that A₀  was unstable while the other equilibrium points are stable

Severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) caused a rapid global demand for the development of several vaccines by the scientific community. Vaccination contributes to preventing infection associated with symptoms and reduces the risk of infection by stimulating the immune system to produce antibodies. This study aimed to determine the effectiveness of Pfizer and Sinopharm vaccines and their relationship to occupation, residence, pregnancy, mass index, and smoking. This study was conducted in Diyala Province, Iraq, for the period from April 2022 to May 2023. A total of 266 blood samples were collected. Written consent was obtained by the Research Ethics Committee in the Diyala Health Department(DHD/No-

     In this paper, the conditions under which the occurrence of the local bifurcation (such as saddle-node (SN), transcritical (TC), and pitchfork (PT)) of all stable points of a food web model have been investigated. Fear and anti-predator responses involving the Holling-type IV and Growly-Martin functional responses have been found. It has been shown that there are transcritical and pitchfork bifurcations near  H₃, H₄, and H₆  as well as a saddle-node bifurcation close to the positive equilibrium point. In addition, there is a saddle-node bifurcation in close to the positive equilibrium point. These divergences have materialised into existence. In conclusion, To prove that the analytical

     In the current research work, the prepared new ligand 3hydroxy-2-(3-(4-nitro-benzoyl) thiouriedo) propanoic acid (NTP) has undergone synthesis through the reactions of 4-nitrobenzol isothiocyanate with the serine amino acid; its complex has been studied by effects of the temperature ranging within (25-45 ^oC) and various concentrations on molar conductivity values from Arinus' law application, by which decomposition constant and uniform molar conductivity is determined. The thermo0dynamic parameters (i.e., ΔS, ΔG, and ΔH) have been estimated and then discussed. Results have shown that the level of the molar conductivity increases with the degree of temperature and decreases with the increase of the concentration usi

     Sulfamethoxazole and its derivatives are commonly utilized in the pharmaceutical and medicinal industry due to their biological and pharmaceutical activities, including anti-tubercular, anti-fungal, anti-cancer, anti-bacterial, and herbicidal activities. This review presents the latest and most promising studies related to synthesizing organic derivatives of sulfamethoxazole and their drug-metal complexes and the biological activity associated with these complexes. Some organic drugs, including sulfamethoxazole, exhibit toxicological and pharmacological properties that can be administered in the form of metal complexes. Many researchers have synthesized organic ligands derived from sulfamethoxazole in the forms of Sc

We conducted a study on the quality of non-diatom planktonic algae in the Tigris River during the autumn 2022 and winter 2023 seasons. The study focused on the impact of the medical city waste discharge to the Tigris River at three sites: Al-Sarafiya Bridge in the north, Medical City, and the Bab Al-Mu'adam Bridge in the south of Khader Elias. The study also examined some physical and chemical variables of the river water. Findings showed that there are 74 species (38 genera) of non-diatom algae in four orders. The blue-green algae Cyanophyceae and Chlorophyceae had the most species, with 35 species belonging to 19 genera and 16 genera per division, or 47% of all algae. Euglenophyceae had 5%, with 3 species and 2 genera, and Chrysophycea

     Due to superficial particles and remarkable packing technologies, the HALO-HILIC column outperformed regular porous columns in terms of analysis time. This study analyzes and identifies kaempferol and luteolin flavonoids in natural herbs. A fast, novel chromatographic method combining superficially porous silica particles packed in a column served as the separation tool for hydrophilic interaction liquid chromatography coupled with a UV detection system is being introduced in this work. Flavonoid separation and quantification took six minutes using only superficial porous particles in the HILIC column compared to hours using fully porous particles in the RP columns. The findings demonstrated that the HILIC mode

     Novel heterocyclic acid-base indicators 8-[3-(phenol)azo] theophylline (PAT) and 8[1-(6-sulfonic acid naphthalene) azo] theophylline (SAT) were synthesized through the reaction between m-amino phenol and 1-amino naphthalene -6-sulfonic acid with sodium nitrite to form the diazonium salt at a temperature 0-5˚C in an acidic medium, then a coupling process between the diazonium salt and theophylline compound to produce pigments at the same temperature while maintaining the PH level at 5-6. This study aims to prepare acid-base indicators based on azo dyes. The structural features of these indicators were examined via elemental analyses [FTIR, UV-Vis, and HNMR] spectroscopies, thermal analysis (TGA), and scanning el

  This study employed the biosynthetic technique for creating vanadium nanoparticles (VNPs), which are affordable and user-friendly; VNPs was synthesized using vanadium sulfate (VOSO₄.H₂O) and a plant extract derived from Fumaria Strumii Opiz (E2) at a NaOH concentration of 0.1 M. This study aims to investigate the potential applications of utilizing an adsorbent for metal ions to achieve environmentally friendly production and assess its antibacterial activity and cytotoxicity. The reaction was conducted in an alkaline environment with a pH range of 8–12. The resulting product was subjected to various characterization techniques, including Fourier transform infrared spectroscopy, ultraviolet-visible spe

It was collected 145 samples from a variety of clinical sources, including urinary tract infections, wounds, blood, respiratory tract infections, stool, sputum, and high vaginal swabs, from various hospitals in Baghdad. Following the collection, we conducted microscopic examinations, biochemical examinations, and diagnosis. The Vitek-2 Compact System conducted the final analysis. It was gotten 50 isolates of Escherichia coli, and 34% of those were from urinary tract infections, wounds, respiratory system infections, sputum, and vaginal swabs. 72% of the isolates were from urinary tract infections, 14% were from wounds, and 2% were from respiratory system infections. Next, we conducted genotyping and tested for beta-lactamase res

Time-delay differential equations-based mathematical modeling is a significant tool for understanding the effect of delay in biological systems and analyzing how it affects the dynamics of those systems' asymptotic behavior. The prey-predator model described in this paper includes disease in the prey species, harvesting in each population, and time delays in predation and gestation of the predator. The solutions of the model are positive and bounded for all times within a realistic region. The existence of all fixed points has been established. When a time delay is present, the essential requirements for the local stability of the positive equilibrium and the occurrence of Hopf bifurcation can be determined by analyzing the associated ch

The effect of couple stress, slip condition, changing rotation, and other variables on the peristaltic flow of Powell-Eyring fluid in an inclined asymmetric channel with an inclining magnetic field through a porous media is investigated in this study. Constitutive equations obeying the Powell-Eyring fluid model are employed. In flow analysis, assumptions such as a low Reynolds number and a long wavelength approximation are used. The stream function and mechanical efficiency have closed form expressions devised. The stream function is expressed mathematically. Through the collection of figures, the impact of various criteria is explained and graphically represented Through the collection of figures, the impact has been explained of the Ha

An inherited tendency is necessary for the manifestation of celiac disease (CD), an autoimmune, gluten-sensitive, inflammatory disorder of the small intestine. Gluten, a storage protein in cereals, causes CD. An increase in oxidant compound generation, surpassing the capacity of the endogenous antioxidant system, causes oxidative stress (OS). This study aims to evaluate some oxidants and antioxidants factors in Iraqi females with CD. This hospital-based cross-sectional study at Baghdad Educational Hospital in Baghdad, Iraq, involved 100 female participants of reproductive age. Tests have been measured, such as total oxidants (TOS), total antioxidants (TAS), malondialdehyde (MDA), catalase (CAT), nitric oxide (NO), total protein (TP), and

     Antibacterial substances belong to a group of compounds that attack dangerous microorganisms. Therefore, killing bacteria or reducing their metabolic activity will lessen their adverse effects on a biological system. They originated from either synthetic materials, microbes, or mold. Many of these medications treat the gram-negative bacteria from the critical precedence group, such as Pseudomonas, carbapenem-resistant Acinetobacter, and Enterobacterales. This study aims to investigate the simultaneous analysis of specific antibacterial spectrophotometrically. The WHO maintains this list of priority infections with antibiotic resistance. Drug combinations in single dosage forms are becoming increasingly popular in the pharmaceuti

Periodontitis is a common disorder caused by imbalanced plaque biofilms and associated with gradual deterioration of the teeth supporting apparatus. Obesity is documented as a significant health concern and considered a primary risk factor for the progression of many diseases, such as hypertension, diabetes, malignancies, and periodontitis. Proinflammatory cytokines released in response to these health conditions are of great importance and establish the link between diagnosis and treatment. The present study was conducted to assess levels of chemerin and visfatin in saliva and to evaluate the impact of obesity on periodontitis. Ninety participants were included in the study and dived into three groups: (Group I: obese and periodontitis

Sodium thiosulfate (STS) is a possible therapeutic candidate molecule in a range of diseases and drug-induced toxicities due to its antioxidant, anti-inflammatory, and anti-apoptotic capabilities. The current study aimed to find the effective dose of STS in adult male rats given nicotine by evaluating serum MDA and blood partial pressure of oxygen (PO₂) levels. Thirty-six adult male Wistar rats, Rattus norvegicus (weighing 190–220 g) with an age of 3–3.5 months,  were chosen randomly and separated into six equal groups, administered for 28 days. Animals in the control group were administered an intraperitoneal (i.p.) injection of normal saline, while those in groups 1, 2, 3, 4, and 5 received repeated doses of an

Although considered a good alternative to organophosphate pesticides, there are reports indicating adverse effects of neonicotinoid insecticides on reproduction. The present work was designed to determine the chronic effects of orally administered for treated with 20 mg/kg/b.w. of imidacloprid pesticides and treated with 20 mg/kg/b.w. of nano-imidacloprid on biochemical blood profile in male rats for a duration of 60 d. Result: the exposure caused a significant decline in red blood cells (RBCs) and hemoglobin (H.b.) in all treated groups compared with the control, while causing an increase in blood platelets (PLT) and white blood cells (WBCs) in all rats treated as compared with the control rats. Furthermore, oxidative stress parameters

        The goal of this work, is to examine the concept of a double centralizer, and double Jordan centralizer on prime and semiprime Г-rings, this is done by studying examples, remarks and results related to that concepts and looking for the conditions under which T equal S, we prove the results, the first result, let A be a semiprime Γ-ring and T is a left centralizer, S is a right centralizer, and they fulfilling x  T(y) = S (x)  y,  for each x  A,    Γ, thence (T,S) is a double centralizer. The second, let A be a prime Γ-ring, U be a not equal zero ideal of A, such that, T is a left centralizer, S is a right centralizer, and fulfilling x T(y) = S (x)  y, for each x,

In this present study, a clinically isolated of Pseudomonas spp. from a variety of sources, such as burn patients, wound infections, and UTI patients, that can produce melanin pigment in the presence of 2 % L-tyrosine in both liquid and solid media. These bacteria were identified as Pseudomonas aeruginosa based on morphological, biochemical, and VITEK-2 compact system analysis. The higher melanin producer isolate Ps81, which produces melanin at rate of 3.018933 µg/ml, has been chosen for further investigation steps. The pigment was extracted by several steps of alkali dissolving and acid precipitation followed by washing with organic solvents. Chemical analysis of the pigment particles revealed that they were acid resistant, al

In response to the water crisis, further research is necessary to comprehend the impact of human activities on nutrient concentrations in aquatic ecosystems, building on the extensive studies already conducted to understand these impacts on the water quality of various aquatic ecosystems. We hypothesized that human activities in the Tigris River's catchments could alter the nutrient concentrations in the water along the river. The results showed that phosphate concentration differed significantly among the studied sites due to distributed human activities, while nitrate concentration did not. Water temperature did not affect phosphate and nitrate concentrations. We concluded that human activities on the surrounding landscapes could be mo

     Flucloxacillin (Flx) derivative metal complexes(2S,5R,6R)-6-({[3-(2-chloro-5-fluorophenyl)-5-methylisoxazol-4-yl] carbonyl}amino)-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo [3.2.0] heptane-2-methyl aster and proline with CoII, NiII, CuII, ZnII and CdII. They were synthesized and identified using physicochemical techniques, including elemental analysis CHNS, metal analysis AA, Uv-Vis, FTIR, TGA, magnetic susceptibility, and conductivity measurement. This study aims to investigate the coordination behavior of flucloxacillin and proline, analyze their structural and electronic properties, and evaluate their potential biological activities against bacterial and fungal strains. Additionally, theoretical calculations usin

     Doxycycline is one of the tetracycline-class antibiotics used to treat bacterial and protozoan infections. The development method aimed to determine the Doxycycline hyclate in pharmaceutical drugs using a novel, rapid, and sensitive colorimetric-flow injection approach. The adopted method depended on forming a purplish violet colour complex for the doxycycline hyclate-ammonium chloroaurate reagent in an alkali medium, which a homemade SFI Analyzer measured. Both the physical and chemical variables were analyzed and improved. The calibration plot was linear in the 5-70 μg.mL-1 for the green light source, with a correlation coefficient r=0.9976 using the peak height of green light. The limit of detection was 0.5

     Melatonin (Mel) is a conserved chemical that has been found in far-removed evolutionary organisms. Additionally, it has been proposed that Mel is a stand-alone plant growth regulator whose action is presumably similar to that of IAA and may moderate the effects of other plant growth regulators. Twelve medicinal herbs were divided into parts, and their melatonin concentrations were measured. These plants Ziziphus spina-christi, , Eucalyptus comaldulensis, Melissa officinalis,  Alhagi maurorum, Lavandula angustifolia, Vitex agnus-sactus, Piper nigrum, Hordeum vulgare, Matricaria chamomilla, Borago  officinalis, Solanum lycopersicum and Citrus aurantium  . Methanol was used to extract melatoni