Complexes of the Cr(III), Fe(III), Rh(III), Ru (III), Mo hexagonal valence and Co(II) were prepared using the azo dye 1,1'-(1,3-phenylene bis(diazene-2,1-diyl))bis(2,4,6-trihydroxy-3,1-phenylene))bis(ethan-1-one), which was prepared newly from diazonium salt with 2,4,6-trihydroxyacetophenone, after isolation. The compounds were characterized using proton and carbon nuclear magnetic resonance of the ligand and fine elemental analysis, infrared, ultraviolet-visible, mass measurement, thermogravimetric analysis, differential thermal scanning, metal percentage determination, chlorine content determination, magnetic susceptibility, and molar conductivity. The results showed that the tetra coordinated anionic bond, when linked to metal ions via t

The research includes the preparation of a new Schiff base(4-methyl-2-((2-phenyl hydrazineylidene)methyl)naphthalen-1-ol), which was subsequently, used to prepare a series of complexes using chlorides of Mn2+, Co2+, Cu2+, Cr3+, and Fe3+ ions. The synthesized compounds were characterized using various techniques such as elemental microanalysis (C.H.N), chloride content determination using Mohr’s method, FT-IR spectroscopy, UV-Visible, mass spectra, conductivity, DSC (Differential Scanning Calorimetry), and thermogravimetric analysis. Overall, the decay of the ligand and its metal complexes was recorded to determine their thermal stability and weight-loss profiles. The results indicated that ligand acts as a bidentate doner, coordinating wi

Two nanocomposite corrosion inhibitors were synthesized from Aloe vera extract: one incorporating sodium thiosulfate and the other silver nitrate. Both nanocomposites were subjected to structural characterization using atomic force microscopy (AFM), which revealed distinct morphological features. The sodium thiosulfate-based nanocomposite exhibited uniform and well-dispersed nanoparticles with an average size of 47.51 nm, suggesting a stable and homogeneous distribution. In contrast, the silver nitrate-based nanocomposite displayed slightly larger particles with an average diameter of 58.34 nm, indicating a tendency toward moderate aggregation. The corrosion inhibition performance of these nanocomposites for carbon steel (CS1137) was invest

Mn₂O₃ was coated onto reduced titania nanotubes by reverse pulse electrodeposition, showing smooth and homogenous deposits without covering the opening of the nanotubes.

This paper presents a new Azo dye that was prepared from the reaction of the Benzene-1,2-diamine and 1-(2,4,6-Trihydroxy-phenyl)-ethanone, Azo dye was used to prepare a new series of complexes with general formula: [Co2(H4L) Cl2(H2O)4] and [M2(H4L)Cl4(H2O)2] (M= Cr+3, Fe+3,Rh+3 and Ru+3). The prepared materials were different measurements including to infrared, ultraviolet-visible, and mass spectrometry, as well as thermo gravimetric analysis, differential calorimetry, and elemental analysis. Conductivity, magnetic susceptibility, metal content, and chlorine content of the complexes were also assessed. The complexes prepared from the dye were used to determine their ability to inhibit free radicals by measuring their antioxidant capacity us

Because of the quick growth of electrical instruments used in noxious gas detection, the importance of gas sensors has increased. X-ray diffraction (XRD) can be used to examine the crystal phase structure of sensing materials, which affects the properties of gas sensing. This contributes to the study of the effect of electrochemical synthesis of titanium dioxide (TiO2) materials with various crystal phase shapes, such as rutile TiO2 (R-TiO2NTs) and anatase TiO2 (A-TiO2NTs). In this work, we have studied the effect of voltage on preparing TiO2 nanotube arrays via the anodization technique for gas sensor applications. The results acquired from XRD, energy dispersion spectroscopy (EDX), and field emission scanning electron microscopy

A new azo dye, 5,5-[1,2-phenylenebis(2,1-biazenediyl)]bis[8-quinolino], was synthesized by reacting the diazonium salt of o-phenylenediamine with 8-hydroxyquinoline. The ligand was subsequently used to prepare a series of metal complexes with V(IV), Fe(III), Cr(III), Mn(II), Mo(VI), and Ru(III). The ligand was characterized using 1H and 3C-NMR spectroscopy, while the metal complexes were analyzed using UV-Vis, FT-IR, and mass spectrometry, along with thermal analysis (TGA, DSC), (C.H.N.), conductivity measurements, magnetic susceptibility, and metal and chlorine content analysis, the results indicated that the ligand exhibits tetracoordination. The complexes predominantly formed octahedral geometries, except for the vanadium complex, which

The crystal structure, surface morphology, and optical properties of thin films made from a blend of polyvinylidene fluoride (PVDF) and poly(vinyl alcohol) (PVA), which were doped with zinc oxide nanoparticles (ZnO NPs) at weight ratios of 2, 4, 6, and 10 wt%, were investigated using the solution blending method. Undoped and doped PVDF-PVA polymer blend thin films were deposited using the spin-coating technique. The effect of the addition of ZnO NPs to PVDF-PVA polymer blends was investigated using X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), and UV-Vis spectroscopy to characterize the crystal structure, surface morphology, and optical properties of thin films. XRD results showed that the addition of ZnO

This study investigates the nuclear structure of 12C, 15N, and 24Mg nuclei utilizing a shell model (SM) with the Skyrme Hartree–Fock (SHF) approach. The form factors for inelastic electron scattering were computed for low-lying states that change their parity. This study demonstrates the practicality of the strategy using the truncated large-scale spsdpf shell model space with WBP two-body effective interaction. The data for the M2 transition (2-,0),(2-,1) states indicate energy levels of 12.180 MeV and 16.660 MeV in 12C, 12.666 MeV in 24Mg, 10.062 MeV and 10.800 MeV for 3/2+(3) and 3/2+(4) states, and 7.153 MeV and 10.529 MeV for 5/2+(2) and 5/2+(4) states in 15N. Within Hartree-Fock theory, Skyrme interactions are utilized to derive

The present report depicts a convenient route for the synthesis of new N-Mannich bases from Ciprofloxacin (CP) drug. The synthetic route started from the reaction CP drug with 2-mercaptobenzimidazole to give compound [A], the N-Mannich bases analogs of CP [A1-A8] were prepared by the reaction of CP derivative [A] with primary and secondary amine derivatives. The structure of the analogs was confirmed by spectral (1 HNMR and FTIR) and analytical data. This study also includes calculations of total energy and electrostatic potential. In addition, this research aimed to determine the effects of CP derivatives on the activity of various transferase enzymes in sera, such as serum glutamic-oxaloacetic transaminase (GOT) and Glutamate Pyruvate Tra

The purpose of the study is to synthesize and characterize a new polytriazole derivative from polyacryloyl chloried, first reaction of polyacryloyl chloride with hydrazine hydrate in the presence of DMF as a solvent to obtained acid hydrazide (1) than reacted with different amide to give poly 1,2,4-triazole derivatives(1a-1c). Newly synthesized compounds were characterized by spectral methods [13C-NMR, 1H-NMR, and FTIR] and calculated some of its physical properties. Also, we worked theoretical study involving calculated the geometric configurations, total energy, dipole moment etc..,. In addition, the inhibition effect of the synthesized compounds (1a-1c) on corrosion of stainless steel in 1M HCl were studied by method of weight lo

A new poly chain derivative of polyacrolein has been synthesized from the two basic precursors, polyacrolein and aromatic amine/substituted amine in chloroform to prepare poly Schiff base compounds (A1-A4). The novel poly subs.β-lactam derivative is obtained via coupling of poly schiff base with chloroacetyl chloride and trimethylamine (B1-B4). Newly synthesized compound was identified via spectral methods; their [13C-NMR, 1H-NMR, and FTIR] also measurement of some of its physical properties. Furthermore the inhibition effect of synthesized compounds (B1-B4) on the corrosion of stainless steel in 1N HCl was studied by wight loss method. The results of weight loss measurements showed that corrosion inhibition efficiency by increasing the co

Constructing a geologically realistic reservoir model and accurately evaluating petrophysical properties are critical components for effective reservoir management. Such efforts enable reliable assessment of hydrocarbon potential and support predictive development scenarios through numerical simulations. This study aims to characterize the Yamama carbonate reservoir in the Ratawi Field, southern Iraq, and to build a static geological model as a foundation for future dynamic simulation. Comprehensive well data, including wireline logs, core analysis, and geological reports, were integrated to interpret petrophysical parameters such as shale volume, effective porosity, and water saturation. Additionally, facies classificat

The study examines temporal variation in water levels by calculating the surface area of the Al-Hammar Marsh in southern Iraq over 11 years (2013–2023), because of the consistent Landsat-8 and Landsat-9 data. Because it represents years of remarkable hydrological diversity in Iraq, it provides a trusted assessment for the surface changes of Al-Hammar marsh by using geographic information systems and remote sensing. The change in the surface was determined by utilizing supervised classification (maximum likelihood) to classify the region. Water and vegetation were the two land cover classes that we determined using ArcMap software. Then the thematic maps were created by the same software. The resulting signalize that th

This study presents a comprehensive methodology to improve monorail route selection in Kirkuk city, Iraq using a quantitative GIS-based multi-criteria decision analysis. The primary aim of this study is to develop and apply a quantitative, GIS-based multi-criteria decision analysis framework for optimizing and objectively selecting the most suitable monorail route in Kirkuk city, Iraq, by integrating spatial, topographic, accessibility, service coverage, and economic factors in order to support sustainable and cost-effective urban transport planning in a post-conflict context. The research area covers 460.89 km², including an extensive road network of 5,533.27 km and 3,193 points of interest (POI). Four different monora

Thermal management has become a major issue in the latest high performance computing machines because high CPU temperatures result in inefficient performance and decreased hardware life span. In this work, the cooling performance of a finned metal foam heat sink (FMFHS) was examined. The pore density values of tested copper metal foam (CMF) samples with different values of PPI 5, 10 and 20, with a constant porosity of 90%. For reference, these samples were measured by a conventional Aluminum plate-fin heat sink (CHS). The work was performed under experimental conditions in which air directed over the heat sink surface at air velocities (2.5, 3.0 and 3.5 m/s). The environmental temperature was fixed at 27 °

  يعد محمد بن منكلي (ت784هـ/1282م) واحداً من المؤرخين المسلمين القلائل الذين وجدوا لهم طريقاً خاصاً في التأليف  وتحديداً  التخصص في الكتابة بالشؤون العسكرية وإعداد الجيوش , بل انه يعد الابرز من بين هؤلاء المؤرخين على الاطلاق نظراً لما تركه من ثروة علمية هائلة في هذا الحقل النادر من الكتابات التاريخية.

        ان هذا المؤرخ  الذي كان سليل عائلة قد مارست العمل في الجيش وامتهان الحرفة ا

Pressure ulcers are one of the most common hospital-acquired major conditions that occur in patients with mobility limitations and result in endangering patient safety, prolonging hospital stay, disability, and death. This study aims to examine the level of nurses’ practices and perceived barriers for preventing pressure ulcers among critically ill patients.

Titanium dioxide nanotubes were synthesized by anodizing Ti sheets in the ethylene glycol solution and were covered in Pt nanoparticles onto the surface of TiO2NTs using electrodeposition method from using five derivatives of Mannich base Pt complexes which have been used as precursor of platinum. The mean size, shape, elemental composition of the titanium dioxide nanotubes and platinum deposited on the template were evaluated by different techniques such as field emission scanning electron microscope (FE-SEM), transmission electron microscopy (TEM), X-ray diffraction pattern (XRD), and energy dispersive X-ray (EDX) technique. From all these analyses, the TiO2NTs prepared and Ptnanoparticles deposited on it were identified. The diagnoses pr

In composite steel-concrete structures, shear connectors in the form of headed steel studs are commonly utilized to transfer longitudinal shear force developed at the interface between the two materials. To overcome the shortcomings of design codes, which frequently understate shear capacity and fail to take advantage of sophisticated computational methods, this paper presents an optimization attempt to estimate the shear strength of headed steel studs utilizing the Grey Wolf Optimizer (GWO) technique using MATLAB software. Data from 234 experimental tests are employed to identify and highlight key input parameters influencing the shear strength of headed steel studs. These key parameters include concrete compressive strength (f’c

The main reason for the emergence of a deepfake (deep learning and fake) term is the evolution in artificial intelligence techniques, especially deep learning. Deep learning algorithms, which auto-solve problems when giving large sets of data, are used to swap faces in digital media to create fake media with a realistic appearance. To increase the accuracy of distinguishing a real video from fake one, a new model has been developed based on deep learning and noise residuals. By using Steganalysis Rich Model (SRM) filters, we can gather a low-level noise map that is used as input to a light Convolution neural network (CNN) to classify a real face from fake one. The results of our work show that the training accuracy of the CNN model

TiO₂ famous the very best uranium elimination performance due to its excessive surface region, chemical balance, and photocatalytic effectiveness. Titanium dioxide (TiO₂) has proven promise as a photocatalyst and adsorbent for disposing of uranium from radioactively contaminated water. The goal of this study was to synthesize and evaluate TiO₂ nanoparticles for uranium removal from radioactively infected water using sol–gel and hydrothermal techniques. Under top-quality conditions, the synthesized TiO₂ done uranium removal efficiencies exceeding 70%, demonstrating its potential as a fee-effective and environmentally friendly fabric for radioactive wastewater treatment. The synthesis and amendment of TiO₂ to i

This study investigated the challenges of implementing Building Information Modeling (BIM) in residential complexes in Iraq. The research will aim at determining the most prominent challenges that have affected the implementation of BIM, evaluating the challenges based on the perceptions of the professionals, and presenting practical insights that can be used to realize successful implementation. The mixed-method research design was applied, and it included the literature review, expert interviews, and a questionnaire survey of 67 professionals who were involved in the construction projects. The identified challenges were ranked using the collected data with the help of Reliability testing and Relative Importance Index (

This paper proposes a hybrid speech enhancement estimator that integrates the Perceptually-motivated Karhunen–Loève Transform (PKLT) with the Dual-Masking Harmonic-based (DMH) algorithm in a unified framework termed PKDMH. The main novelty lies in combining perceptual subspace projection with harmonic-residual suppression, enabling the system to jointly remove noise while preserving speech-relevant spectral cues. PKLT first performs perceptual subspace projection and suppresses inaudible components, after which DMH eliminates remaining broadband and harmonic residuals. The proposed PKDMH system was evaluated using the TIMIT dataset contaminated with five noise types: White, Pink, F16, Airport, and Car noise—across f