A new flow injection spectrophotometric method is described for the determination of copper ion Cu(II) in water samples (tap water and river water).The proposed method based on the formation of red complex [Cu(L)2(NO3)2] which has a maximum absorption at λmax=490 nm. Linear range for Cu (II) was from 5-70μg/mL with detection limit 2.55μg/mL. The effect of physical and chemical parameters were evaluated .The proposed method was applied successfully for determination of copper (II) in the tap and river water. [Cu(L)2(NO3)2] complex was prepared in a (2:1) mole ratio as ( reagent: copper (II)).The analytical reagent formed by reaction of thymol with 4-aminoantipyrine at room temperature. The metal complex was characterized by IR, UV-Visible spectra. The metal percentage, electrical conductivity and magnetic properties of the formed complex confirmed that this chromogenic reagent was coordinated with copper (II) metal ion through oxygen and nitrogen atoms of the phenol and amine group as a bidentate ligand with octahedral geometry.
The formation of Zn(II), Cd(II) and Hg(II) complexes was studied with two new hetrocyclic azo ligands 2-[4-(1-sulfonaphthalene)azo]-L-Histidine (L1) and 2-[7-(1-hydroxy3-sulfonaphthalene)azo]-L-Histidine (L2) derived from coupling reaction of diazonium salt of naphthionic acid and 7-amino-1-naphthol-5-sulfonic acid with L-Histidine in an alkaline ethanolic solution. The structural features of all new compounds have been characterized from their elemental analyses, metal content, magnetic moment measurement, molar conductance & FT-IR, UV-Vis. and 1HNMR spectral studies. Furthermore,the composition of complexes have been studied following the mole ratio method after fixing the optimum condition (pH and concentration).Beer’s law
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The integration of decision-making will lead to the robust of its decisions, and then determination optimum inventory level to the required materials to produce and reduce the total cost by the cooperation of purchasing department with inventory department and also with other company,s departments. Two models are suggested to determine Optimum Inventory Level (OIL), the first model (OIL-model 1) assumed that the inventory level for materials quantities equal to the required materials, while the second model (OIL-model 2) assumed that the inventory level for materials quantities more than the required materials for the next period. &nb
... Show MoreIn this work, a modified water displacement method (MWDM) was designed and used alongside geometry method (GEM), overflow method (OFM) and water displacement method (WDM) for determination of bulk volume of a porous solid. Their results were analyzed graphically and statistically. On testing against the data obtained by Suspension/Buoyancy Method (SBM) used as gold standard, it was found that only those generated by the modified water displacement method (MWDM) were of very high accuracy and precision. Apart from its reproducibility being within the recommended range for acceptability of a test method, the technique is cost-effective and easy to apply even with an ungraduated glass cylindrical tube. This can go a long way in enhancing th
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This paper present a study about effect of the random phase and expansion of the scale sampling factors to improve the monochrome image hologram and compared it with previous produced others. Matlab software is used to synthesize and reconstruction hologram.
In this paper, we construct a new mathematical system as Multiplicative Cyclic Group (MCG), called a New Digital Algebraic Generator (NDAG) Unit, which would generate digital sequences with good statistical properties. This new Unit can be considered as a new basic unit of stream ciphers.
A (NDAG) system can be constructed from collection of (NDAG) units using a Boolean function as a combining function of the system. This system could be used in cryptography as like as Linear Feedback Shift Register (LFSR) unit. This unit is basic component of a stream cipher system.
The Adaptive Optics technique has been developed to obtain the correction of atmospheric seeing. The purpose of this study is to use the MATLAB program to investigate the performance of an AO system with the most recent AO simulation tools, Objected-Oriented Matlab Adaptive Optics (OOMAO). This was achieved by studying the variables that impact image quality correction, such as observation wavelength bands, atmospheric parameters, telescope parameters, deformable mirror parameters, wavefront sensor parameters, and noise parameters. The results presented a detailed analysis of the factors that influence the image correction process as well as the impact of the AO components on that process
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This paper propose the semi - analytic technique using two point osculatory interpolation to construct polynomial solution for solving some well-known classes of Lane-Emden type equations which are linear ordinary differential equations, and disusse the behavior of the solution in the neighborhood of the singular points along with its numerical approximation. Many examples are presented to demonstrate the applicability and efficiency of the methods. Finally , we discuss behavior of the solution in the neighborhood of the singularity point which appears to perform satisfactorily for singular problems.