A new Turbidimetric method characterized by simplicity, accuracy and speed for determination of Hydronium ion by continuous flow injection analysis. The method was based on the formation of complex Zn3[Fe(CN)6] for Zinc(II) that was eluted by Hydronium ion from cation exchanger column with Potassium hexacyanoferrate(III) for the formation of a pale yellow precipitate and this precipitate was determined using homemade Linear Array Ayah-5SX1-T-1D continuous flow injection analyser. The optimum parameters were 2.7 mL.min-1 flow rate using H2O as a carrier stream, 1.7 mL.min-1 reagent stream, 110 L sample volume and open valve for the purge of the sample segment. Data treatment shows that linear range 0.01-0.1 mol.L-1 for each acids (HClO4,HNO3,HCl,H2SO4) while L.O.D 30, 50.01,29.75,51.41 μg/sample for HClO4,H2SO4,HCl,HNO3 respectively from the stepwise dilution for minimum concentration of lowest concentration in linear dynamic range of the calibration graph. The correlation coefficient (r) was 0.9891, 0.9930, 0.9917, 0.9940 while percentage linearity (%r2) was 97.85%, 98.81%, 98.61%, 98.36% for HClO4, H2SO4, HCl, HNO3 respectively. R.S.D. % for the repeatability (n=5) was < 2% for determination of Hydronium ion with concentration 20 and 80 mMol.L-1. The method was applied successfully for the determination of Hydronium ion in commercial samples. Using paired t-test between the newly developed method and classical method; shows that there were no significant differences between either methods. On this basis the new method can be accepted as an alternative analytical method for determination of Hydronium ion in commercial samples.
Fiber Bragg Grating has many advantages where it can be used as a temperature sensor, pressure sensor or even as a refractive index sensor. Designing each of this fiber Bragg grating sensors should include some requirements. Fiber Bragg grating refractive index sensor is a very important application. In order to increase the sensing ability of fiber Bragg gratings, many methods were followed. In our proposed work, the fiber Bragg grating was written in a D-shaped optical fiber by using a phase mask method with KrFexcimer. The resultant fiber Bragg grating has a high reflectivity 99.99% with a Bragg wavelength of 1551.2 nm as a best result obtained from a phase mask with a grating period of 1057 nm. In this work it was found that the rota
... Show MoreIn this paper we introduce a brief review about Box-Jenkins models. The acronym ARIMA stands for “autoregressive integrated moving averageâ€. It is a good method to forecast for stationary and non stationary time series. According to the data which obtained from Baghdad Water Authority, we are modelling two series, the first one about pure water consumption and the second about the number of participants. Then we determine an optimal model by depending on choosing minimum MSE as criterion.
Drilling fluid loss during drilling operation is undesirable, expensive and potentially hazardous problem.
Nasiriyah oil field is one of the Iraqi oil field that suffer from lost circulation problem. It is known that Dammam, um-Radoma, Tayarat, Shiranish and Hartha are the detecting layers of loss circulation problem. Different type of loss circulation materials (LCMs) ranging from granular, flakes and fibrous were used previously to treat this problem.
This study presents the application of rice as a lost circulation material that used to mitigate and stop the loss problem when partial or total losses occurred.
The experim
... Show MoreThis paper discusses the problem of decoding codeword in Reed- Muller Codes. We will use the Hadamard matrices as a method to decode codeword in Reed- Muller codes.In addition Reed- Muller Codes are defined and encoding matrices are discussed. Finally, a method of decoding is explained and an example is given to clarify this method, as well as, this method is compared with the classical method which is called Hamming distance.
In this paper, the series solution is applied to solve third order fuzzy differential equations with a fuzzy initial value. The proposed method applies Taylor expansion in solving the system and the approximate solution of the problem which is calculated in the form of a rapid convergent series; some definitions and theorems are reviewed as a basis in solving fuzzy differential equations. An example is applied to illustrate the proposed technical accuracy. Also, a comparison between the obtained results is made, in addition to the application of the crisp solution, when theï€ ï¡-level equals one.
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Attack stream cipher system , using cipher text only , depends on the characteristics of plain teKt language and the randomness of the key , that used in encryption , without having detailed k.nuwh:dgt:: uf cipher algorithm by benefiting from the balance between O's and I' in the key to reduce the probability of key space.
In this paper, we deal with games of fuzzy payoffs problem while there is uncertainty in data. We use the trapezoidal membership function to transform the data into fuzzy numbers and utilize the three different ranking function algorithms. Then we compare between these three ranking algorithms by using trapezoidal fuzzy numbers for the decision maker to get the best gains
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The paper presents a neural synchronization into intensive study in order to address challenges preventing from adopting it as an alternative key exchange algorithm. The results obtained from the implementation of neural synchronization with this proposed system address two challenges: namely the verification of establishing the synchronization between the two neural networks, and the public initiation of the input vector for each party. Solutions are presented and mathematical model is developed and presented, and as this proposed system focuses on stream cipher; a system of LFSRs (linear feedback shift registers) has been used with a balanced memory to generate the key. The initializations of these LFSRs are neural weights after achiev
... Show MoreThis investigation aims to determine whether it is feasible to use the limestone rocks found in the Al-Samawa stone quarry in southern Iraq as the stationary phase in column chromatography separation. Together with the chromatographic application, the physical and chemical characteristics of the rocks are examined. SiO2, SO4, PO4, NO3, and Cl are the negative ions, while Ca, Mg, Na, K, and Li are the positive ions. The limestone samples are characterized via chromatographic analysis. The results suggest that limestone samples could be used as an adsorbent material for chromatographic separation techniques. Additionally, samples from the Nasiriyah refinery's crude oil can be used to sep
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