New isatinic hydrazone Schiff-base ligands,
namely furan-2-carboxylic acid (2-oxo-1,2-dihydro-indol-
3-ylidene)-hydrazide (L1), thiophene-2-carboxylic acid (2-
oxo-1,2-dihydro-indol-3-ylidene)-hydrazide (L2) and
2-(pyridine-2-yl-hydrazono)-1,2-dihydro-indol-3-one) (L3)
are reported. The ligands were prepared by the condensation of furan-2-carboxylic acid hydrazide (L1), thiophene-
2-carboxylic acid hydrazide (L2), and 2-hydrazino pyridine
(L3) with isatine. Monomeric complexes were prepared
from the reaction of the corresponding metal chloride with
the ligands. The ligands and their nine new complexes of
the general formulae [M(Ln)2]Cl2 [where M = Co(II),
Zn(II) and Cd(II); n = L1, L2 and L3] were characterised
by spectroscopic methods (FTI
...
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