The aim of the work is synthesis and characterization of bidentate ligand [dipotassium sodium7-((E)-2-(2-((Z)-1-carboxylatoethylideneamino)thiazol-4-yl)-2 (carboxylatemethoxyimino) acet amido)-8-oxo-3-vinyl-5- thia-1-azabicyclo[4.2.0] oct-2- ene-2- carboxylate] [Nak2L], from the reaction of cefixime with sodium pyruvet to produce the ligand [Nak2L], the reaction was carried out in methanol as a solvent under reflux. The prepared ligand [Nak2L] which was characterized by FT-IR, UV-Vis spectroscopy, 1H, 13C-NMR spectra, Mass spectra, (C.H.N) and melting point. The mixed ligand complexes were prepared from ligand [Nak2L] was used as a primary ligand while 8-hydroxy quinoline [Q] was used as a secondary ligand with metal ion M(?).Where M(?) = (Mn ,Co ,Ni ,Cu ,Zn and Cd) at reflux ,using methanol as a solvent, KOH as a base. Complexes of the composition [(M)2(Q)2(KL)(H2O)4] with (2:2:1) molar ratio were prepared. All the complexes were characterized by spectroscopic methods (FT-IR, UV-Vis spectroscopy) along with elemental analysis (A.A), chloride content and melting point measurements were carried out, together with conductivity and magnetic susceptibility. These measurements showed octahedral geometry around (Mn??, Co??, Ni??, Cu??, Zn?? and Cd??) ions. The biological activity of the ligands [NaK2L], [Q] and complexes [(M)2(Q)2(KL)(H2O)4] were studied by using inhibition method.
A general velocity profile for a laminar flow over a flat plate with zero incidence is obtained by employing a new boundary condition to the other available boundary conditions. The general velocity profile is mathematically simple and nearest to the exact solution. Also other related values, boundary layer thickness, displacement thickness, momentum thickness and coefficient of friction are nearest to the exact solution compared with other corresponding values for other researchers.
Image compression has become one of the most important applications of the image processing field because of the rapid growth in computer power. The corresponding growth in the multimedia market, and the advent of the World Wide Web, which makes the internet easily accessible for everyone. Since the early 1980, digital image sequence processing has been an attractive research area because an image sequence, as acollection of images, may provide much compression than a single image frame. The increased computational complexity and memory space required for image sequence processing, has in fact, becoming more attainable. this research absolute Moment Block Truncation compression technique which is depend on adopting the good points of oth
... Show MoreIn this article, an efficient reliable method, which is the residual power series method (RPSM), is used in order to investigate the approximate solutions of conformable time fractional nonlinear evolution equations with conformable derivatives under initial conditions. In particular, two types of equations are considered, which are time coupled diffusion-reaction equations (CD-REs) and MKdv equations coupled with conformable fractional time derivative of order α. The attitude of RPSM and the influence of different values of α are shown graphically.
Background: The main purpose of this study is to find if there is any correlation between the level of C-reactive protein (CRP) in gingival crevicular fluid with its serum level in chronic periodontitis patients and to explore the differences between them according to the probing depth. Materials and methods: Forty seven male subjects enrolled in this study. Thirty males with chronic periodontitis considered as study group whom further subdivided according to probing depth into subgroup 1 with pocket depth ≤6mm, subgroup 2 with pocket depth >6mm. The other 17 subjects considered as controls. For all subjects, clinical examination where done for periodontal parameters plaque index (PLI), gingival index (GI), bleeding on probing (BOP),
... Show MoreThis paper is concerned with the solution of the nanoscale structures consisting of the with an effective mass envelope function theory, the electronic states of the quantum ring are studied. In calculations, the effects due to the different effective masses of electrons in and out the rings are included. The energy levels of the electron are calculated in the different shapes of rings, i.e., that the inner radius of rings sensitively change the electronic states. The energy levels of the electron are not sensitively dependent on the outer radius for large rings. The structures of quantum rings are studied by the one electronic band Hamiltonian effective mass approximati
... Show MoreEnhancement of heat transfer in the tube heat exchanger is studied experimentally by using discrete twisted tapes. Three different positions were selected for inserting turbulators along tube section (horizontal position by α= 00, inclined position by α= 45 0 and vertical position by α= 900). The space between turbulators was fixed by distributing 5 pieces of these turbulators with pitch ratio PR = (0.44). Also, the factor of constant heat flux was applied as a boundary condition around the tube test section for all experiments of this investigation, while the flow rates were selected as a variable factor (Reynolds number values vary from 5000 to 15000). The results s
... Show MoreEstablishing coverage of the target sensing field and extending the network’s lifetime, together known as Coverage-lifetime is the key issue in wireless sensor networks (WSNs). Recent studies realize the important role of nature-inspired algorithms in handling coverage-lifetime problem with different optimization aspects. One of the main formulations is to define coverage-lifetime problem as a disjoint set covers problem. In this paper, we propose an evolutionary algorithm for solving coverage-lifetime problem as a disjoint set covers function. The main interest in this paper is to reflect both models of sensing: Boolean and probabilistic. Moreover, a heuristic operator is proposed as a local refinement operator to improve the quality
... Show MoreIn this paper, the classical continuous triple optimal control problem (CCTOCP) for the triple nonlinear parabolic boundary value problem (TNLPBVP) with state vector constraints (SVCs) is studied. The solvability theorem for the classical continuous triple optimal control vector CCTOCV with the SVCs is stated and proved. This is done under suitable conditions. The mathematical formulation of the adjoint triple boundary value problem (ATHBVP) associated with TNLPBVP is discovered. The Fréchet derivative of the Hamiltonian" is derived. Under suitable conditions, theorems of necessary and sufficient conditions for the optimality of the TNLPBVP with the SVCs are stated and proved.
The current paper aims to identify potential factors associated with employees’ intentions to leave information and communication technology companies in Iraq. There is evident variability in the literature regarding these factors; hence, a factor analysis approach was employed to identify these factors within the surveyed environment. Due to the difficulty in precisely delineating the size of the research population, a purposive sampling method was employed to reach an appropriate number of respondents within the aforementioned companies. A total of 288 employees responded to the survey conducted via Google Forms. The test results revealed the presence of five primary factors associated with employees’ intentions to leave, name
... Show MoreThe effect of high energy radiation on the energy gap of compound semiconductor Silicon Carbide (SiC) are viewed. Emphasis is placed on those effects which can be interpreted in terms of energy levels. The goal is to develop semiconductors operating at high temperature with low energy gaps by induced permanent damage in SiC irradiated by gamma source. TEACO2 laser used for producing SiC thin films. Spectrophotometer lambda - UV, Visible instrument is used to determine energy gap (Eg). Co-60, Cs-137, and Sr-90 are used to irradiate SiC samples for different time of irradiation. Possible interpretation of the changing in Eg values as the time of irradiation change is discussed