Apparent molar volume, V?, and viscosity B-coefficient of nicotinc acid in water and in aqueous NaCl solutions have been determined from density and viscosity measurements at (293.15, 298.15, 303.15 and 308.15) K. The experimental density data were evaluated by Masson equation, and the derived, apparent molar volume at infinite dilution, Vo?, and the slope Sv, were interpreted in term of solute-solvent and solute- solute interactions. Transfer apparent molar volumes at infinite dilution of nicotinic acid from water to NaCl solutions at various temperatures have been calculated.The viscosity data have been analyzed using Jones-Dole equation, and the derived parameters, Jones-Dolecoefficient, B,and Falkenhagen coefficient,A, have been also interpreted in terms of solute-solvent and solute-solute interactions respectively. The variation of B coefficient with temperature, (dB/dT), was also determined, the negative values indicate that nicotinic acid in aqueous NaCl solution is structure making. The results were interpreted in terms of complex vitamin-water-co-solute (NaCl) interactions. The free energy, enthalpy, andentropy of activation were calculated using the Nightingale, Benck, and Eyring equations. Free energies of activation of viscous flow ( *1) per mole, and, ( *2) per mole,of solvent and solute, respectively, were also calculated. The effects of soluteson the structure of water were interpreted in terms of viscositiesand the thermodynamic parameters.
Abstract: In this research we study the of added NaCl with concentration (0.2, 0.02)M on the spectral of cationically charged dye (cresyl violet) and anionically charged surfactant (sodium dodecyl sulphate) with different concentration, the result show two peaks appearance the first attributed to micelle and the other formation of dye surfactant complex, in addition to the increase in the quantum efficiency of emission spectrum and shifted toward long wavelength (λmax=692.5nm-626nm).
The need to constantly and consistently improve the quality and quantity of the educational system is essential. E-learning has emerged from the rapid cycle of change and the expansion of new technologies. Advances in information technology have increased network bandwidth, data access speed, and reduced data storage costs. In recent years, the implementation of cloud computing in educational settings has garnered the interest of major companies, leading to substantial investments in this area. Cloud computing improves engineering education by providing an environment that can be accessed from anywhere and allowing access to educational resources on demand. Cloud computing is a term used to describe the provision of hosting services
... Show MoreThe dramatic decrease in the cost of genome sequencing over the last two decades has led to an abundance of genomic data. This data has been used in research related to the discovery of genetic diseases and the production of medicines. At the same time, the huge space for storing the genome (2–3 GB) has led to it being considered one of the most important sources of big data, which has prompted research centers concerned with genetic research to take advantage of the cloud and its services in storing and managing this data. The cloud is a shared storage environment, which makes data stored in it vulnerable to unwanted tampering or disclosure. This leads to serious concerns about securing such data from tampering and unauthoriz
... Show MoreWe consider some nonlinear partial differential equations in higher dimensions, the negative order of the Calogero-Bogoyavelnskii-Schiff (nCBS) equationin (2+1) dimensions, the combined of the Calogero-Bogoyavelnskii-Schiff equation and the negative order of the Calogero-Bogoyavelnskii-Schiff equation (CBS-nCBS) in (2+1) dimensions, and two models of the negative order Korteweg de Vries (nKdV) equations in (3+1) dimensions. We show that these equations can be reduced to the same class of ordinary differential equations via wave reduction variable. Solutions in terms of symmetrical Fibonacci and Lucas functions are presented by implementation of the modified Kudryashov method.
<span>One of the main difficulties facing the certified documents documentary archiving system is checking the stamps system, but, that stamps may be contains complex background and surrounded by unwanted data. Therefore, the main objective of this paper is to isolate background and to remove noise that may be surrounded stamp. Our proposed method comprises of four phases, firstly, we apply k-means algorithm for clustering stamp image into a number of clusters and merged them using ISODATA algorithm. Secondly, we compute mean and standard deviation for each remaining cluster to isolate background cluster from stamp cluster. Thirdly, a region growing algorithm is applied to segment the image and then choosing the connected regi
... Show MoreThe impact of a Schiff base namely 2-((thiophen-2-ylmethylene)amino)benzenethiol to corrode mild steel in 1 M HCl resolved was evaluated using different weight loss technique and scanning electron microscopy (SEM).different weight measurements to expand that the 2-((thiophen-2-ylmethylene) amino) benzenethiol inhibits the corrosion of mild steel through adsorbing of top for mild steel and block the active locality. The inhibitive impacts of 2-((thiophen-2-ylmethylene)amino)benzenethiol increase with increasing concentration and decrease with increasing temperature. SEM to checking revealed that the alloy surface was quite unaffected and formed protective film on its surface. The investigated
... Show MoreIn petroleum industry, there are two major operations that can potentially impact the environment: Drilling and production. Both activities generate a significant volume of wastes include drill cuttings contaminated with hydrocarbons, wide variety of chemical additives, produced water and air pollutants. The potential impact depends primarily on the material, its concentration after release, and the biotic community that is exposed.
In this study, many drilling locations and production facilities have been investigated and examined for their adverse effects on the environment. Contamination with hydrocarbons, heavy metals, salts, other associated wastes and air pollution were detected at many sits.
Understanding of drilling and pro
A new method for determination of allopurinol in microgram level depending on its ability to reduce the yellow absorption spectrum of (I-3) at maximum wavelength ( ?max 350nm) . The optimum conditions such as "concentration of reactant materials , time of sitting and order of addition were studied to get a high sensitivity ( ? = 27229 l.mole-1.cm-1) sandal sensitivity : 0.0053 µg cm-2 ,with wide range of calibration curve ( 1 – 9 µg.ml-1 ) good stability (more then24 hr.) and repeatability ( RSD % : 2.1 -2.6 % ) , the Recovery % : ( 98.17 – 100.5 % ) , the Erel % ( 0.50 -1.83 % ) and the interference's of Xanthine , Cystein , Creatinine , Urea and the Glucose in 20 , 40 , 60 fold of analyate were also studied .