In the present study, activated carbon supported metal oxides was prepared for thiophene removal from model fuel (Thiophene in n-hexane) using adsorptive desulfurization technique. Commercial activated carbon was loaded individually with copper oxide in the form of Cu₂O/AC. A comparison of the kinetic and isotherm models of the sorption of thiophene from model fuel was made at different operating conditions including adsorbent dose, initial thiophene concentration and contact time. Various adsorption rate constants and isotherm parameters were calculated. Results indicated that the desulfurization was enhanced when copper was loaded onto activated carbon surface. The highest desulfurization percent for Cu₂O/AC and o

Aeration system in the cultivation of Chlorella Sp. Microalgae using dairy wastewater as culture media was addressed in the current study. This research aimed to study the effect of aeration in the bubble column bioreactor on the biological synergy between microalgae and bacteria if they are present in the same place. The results show that the sterilization stage is not the dominant step in the success of microalgae cultivation in water-rich organic waste. There is a clear convergence between the growth rate of Chlorella microalgae in the sterilized and non-sterilized culture media, which gives realism if the proposal is applied industrially. Through the information obtained the aerobic bacteria in the non-sterilized me

The analysis, behavior of two-phase flow incompressible fluid in T-juction is done by using "A Computational Fluid Dynamic (CFD) model" that application division of different in industries. The level set method was based in “Finite Element method”. In our search the behavior of two phase flow (oil and water) was studed. The two-phase flow is taken to simulate by using comsol software 4.3. The multivariable was studying such as velocity distribution, share rate, pressure and the fraction of volume at various times.  The velocity was employed at the inlet (0.2633, 0.1316, 0.0547 and 0.0283 m/s) for water and (0.1316 m/s) for oil, over and above the pressure set at outlet as a boundary condition. It was observed through the program

Avery large numbers of articles are made by powder metallurgical methods using electrolytically reduced metal powders. Iron powder is one of these powders which play an important role in this field. Its preparation by electrolytic method is economic in comparison with the traditional methods (Atomization and carbonyl processes).

An electrochemical cell consisting of two electrodes (stainless steel cathode and iron anode, 99.9%) was used to study the electrolytic preparation of iron powder with particle size less than 106µm directly as powde1y form. Ferrous sulphate electrolyte was used containing sodium chloride as a stabilizing agent. The produced powder was thoroughly washed with an acidified distilled water and absolute ethan

The inhibitive power of Polyvinyl Alcohol (PVA) was investigated toward the corrosion of carbon steel in 0.2N H₂SO₄ solution in the temperature range of 30-60˚C and PVA concentration range of 150-2000 ppm.

   The corrosion rate was measured using both the weight loss and the electrochemical techniques. The weight loss results showed that PVA could serve as a corrosion inhibitor but its inhibition power was found to be low for the corrosion of carbon steel in the acidic media. Electrochemical analysis of the corrosion process of carbon steel in an electrochemical corrosion cell was investigated using 3-Electrode corrosion cell. Polarization technique was used for carbon steel corrosion in 0.2N H

An investigation was conducted for the improvement of viscosity index of a lubricating oil fraction (SAE – 30) obtained from vacuum distillation unit of lube oil plant of Daura Refinery, using solvent extraction process. In this study two type of extraction solvents were used to extract the undesirable materials which reduce the viscosity index of raw lubricating oil fraction, the first solvent was furfural which is un use today in the Iraqi refineries and the second was NMP (N-methyl, 2, pyrrolidone) which is used for the first time in this work to extract the lubricating oil fraction produced from Iraqi crude oils. The studied effecting variables of extraction are extraction temperature range from 70 to 110 oC for furfural and NMP ex

تناول البحث الحالي تحديد المسار التكنولوجي لاسترداد مذيب الزايلين المستخدم في تحضير السبائك البوليمرية نوع (بولي اثيلين-بولي سايلوكسان) باعلى نسبة ممكنة. وتم ذلك من خلال دراسة تاثير المتغيرات الحاكمة باعتماد اسلوبين في الاسترداد وهما الاسترداد بالهواء الحار والاسترداد بالتبريد والترشيح. اظهرت النتائج ان اعتماد اسلوب التبريد والترشيح يعطي نتائج فضل من حيث نسبة الاسترداد والتي بلغت 75% ومن حيث

The aim of the present work is to develop a new class of natural fillers based polymer composites with sawdust (S.D) which used two particle sizes (1.2 μm & 2.3 μm) and different weight percentage from sawdust (10%, 15%, and 20%). The mechanical properties studied include hardness (shore D) for all samples at normal conditions (N.C). The unsaturated polyester (UPE) and its composites samples were immersed in water for  30 days to find the effect of particle size of sawdust (S.D) on the weight gain (Mt %) by water for all the samples, also to find the effect of water on their hardness. The results show that the composite materials of sawdust (S.D) fillers which has particle size (1.2 μm) better than (2.3 μm) particle size bef

This work aimed to use effective, low-cost, available, and natural adsorbents like eggshells for removal of  hazardous organic dye result from widely number of  industries and study the influence of different eggshell particle size (75, 150) Mm.  The adsorbent was characterized by SEM, EDX, BET and FTIR . The initial pH of dye solutions  varying from 4 to 10 , the initial concentrations of methyl violet (MV) 2B range (20-80) mg/L, dosage range (0.5-10) g, contact time (30-180) min, and particles size of the adsorbent (75, 150) Mm were selected to be studied. Two adsorption isotherms models have been used to fit the experimental data. Langmuir and Freunlich models were found to more represent the experiments with high

Nanocrystalline micro-mesoporous ZSM/MCM-41 composite was synthesized using alkaline treatment method and two step of crystallization in poly tetraflouroethylene (PTFE) lined autoclave. The synthesized zeolites was characterized by X-Ray diffraction (XRD), Scanning electron microscopy (SEM), Transmission electron microscopy (TEM), Atomic force microscopy (AFM), Fourier transport infrared (FTIR), and N₂ adsorption-desorption (BET). It was approved that the best results for alkaline leaching can be got with 1.5M NaOH solution. High surface (BET) area of 630 m²/g with pore volume of 0.55 cm³/g has been got. AFM reports showed a nano-level size for average particle size of 50nm.

This work deals with thermal cracking of three samples of extract lubricating oil produced as a by-product from furfural extraction process of lubricating oil base stock in AL-Dura refinery. The thermal cracking processes were carried out at a temperature range of 325-400 ºC and atmospheric pressure by batch laboratory reactor. The distillation of cracking liquid products was achieved by general ASTM distillation (ASTM D -86) for separation of gasoline fraction up to 220 ºC from light cycle oil fraction above 220 ºC. The comparison between the conversions at different operating conditions of thermal cracking processes indicates that a high conversion was obtained at 375°C, according to gasoline production. According to gasoline produ

The present study was conducted to evaluate the effect of variation of influent raw water turbidity, bed composition, and filtration rate on the performance of mono (sand) and dual media (sand and anthracite) rapid gravity filters in response to the effluent filtered water turbidity and headloss development. In order to evaluate each filter pe1formance, sieve analysis was made to characterize both media and to determine the effective size and uniformity coefficient. Effluent filtered water turbidity and the headloss development was recorded with time during each experiment.

   This study demonstrates a sustainable, "trash-to-treasure" approach by synthesizing silica (SiO₂) and alumina (Al₂O₃) nanoparticles (30–80 nm) from local waste materials—specifically bentonite clay and aluminum wire waste—and evaluating their performance as eco-friendly additives in 350 mL water-based drilling fluids at concentrations ranging from 0 to 1 g. Tested under harsh subsurface conditions, the incorporated nanoparticles significantly enhanced the fluids' rheological properties, lubricity, filtration control, and swelling inhibition, with performance scaling alongside nanoparticle concentration. Notably, at a 1 g dosage, the fluid's yield point spiked from a baseline of 9 to 42 for SiO<

   The performance of pomegranate peel treated with oleic acid (PPOA) was studied using a batch mode for ciprofloxacin (CIP) adsorption from an aqueous solution. Although other studies have investigated chemical modification with various chemical agents, the novel use of oleic acid for modification yields unprecedented results in terms of CIP removal efficiency. Dependent parameters were optimized using the sample pH, contact interval, initial CIP concentration, and adsorbent dose. Using response surface methodology (RSM) with a central composite design (CCD), a dose of 0.3 g/100 mL produced excellent removal efficiency (above 81%) for CIP concentrations of 60 mg/L after 90 minutes of contact at pH 6. With an R² (correlation

   Aqueous mineral carbonation is one of the most important methods of permanent CO₂ sequestration in Carbon Capture, Utilization, and Storage (CCUS). This is carried out using alkaline pH-risers to neutralize the acidity of carbonic acid (H₂CO₃) to cause a change in the chemical balance to carbonate ions (CO₃^2-). This paper assesses the different sources of alkalinity with special reference to the performance of caustic soda (NaOH) and soda ash (Na₂CO₃) under industrial circumstances. It has been shown in experiments that caustic soda is the most effective reagent in quick mineralization. It causes a sudden early increase in pH (about 2.0 to 2.5 units per gra

   The paper introduces a state-of-the-art Physics Augmented Machine Learning framework to predict the critical geomechanical property – Unconfined Compressive Strength (UCS) – in the Zubair reservoir of the Zubair field for mitigating the risk of CO₂ storage. The geomechanical results and modeling workflow were obtained via an integrated software system that was developed in Python, while all computational processes and model training were conducted in the Deepnote interactive cloud computing environment; thus, all of the necessary libraries and the high-performance processing capacities were seamlessly integrated. Through the comparison of six ensemble algorithms which are Categorical Boosting (CatBoost), XGBoost )Extr

   The rising level of Carbon Dioxide (CO₂) concentration and the growing energy demand of the world have given a desperate necessity of carbon-neutral and sustainable energy sources. Carbon Capture, Utilization and Storage (CCUS), especially CO₂-Enhanced Gas Recovery (CO₂-EGR) has become an attractive technology to maximize hydrocarbon recovery with a minimal environmental impact. The paper introduces an AI-based system of recovering carbon-neutral gas by implementing CO₂ gas injection and storage. A number of supervised learning models, including XGBoost, Random Forest (RF), and a hybrid RF-XGBoost, were used in conjunction with data preprocessing and feature engineering to come up with the

   Petroleum refinery wastewater (PRW) is becoming a big problem for both people and the environment, so researchers have been trying harder to find better ways to treat it. One option that looks really promising is using advanced oxidation processes (AOPs) to break down all the pollutants inside this wastewater. In this study, new-designed photoreactor was used to conduct a photocatalysis approach that aimed to remove the chemical oxygen demand (COD) from PRW collected from Al-Diwaniya refinery in the south of Iraq. The geometrically optimized photoreactor enhances the formation of the free radicals required for efficient degradation by maximizing mass transfer and light dispersion. Bare TiO₂ and SiO₂/TiO₂ were fabricated as pho

   Given the environmental and health risks posed by sulfur pollutants, their removal and the production of lower sulfur hydrocarbon fuels are essential. Therefore, oxidative desulfurization (ODS) technology has become crucial as it operates efficiently under moderate conditions. This study focused on the synthesis of a (Fe₂O₃ + NiO)/SiO₂ catalyst via incipient wetness impregnation, followed by drying at 120°C and calcination at 600°C. Several tests were performed on the catalyst before its application: BET, TGA, and SEM-EDX. The BET results showed a decrease in surface area from 166.47 to 149.57 m² g⁻¹ after metal loading, confirming the fixation of iron and nickel oxides on the silica support. XRD and FTIR analyses confir

      Nanoporous-SnO₂ films were electrochemically prepared via anodizing of metallic tin electrodeposited on a cylindrical copper substrate using rotating cylinder electrode Technique. The effects of anodizing potential (4-7V), oxalic acid (OA) concentration (0.1-0.5M), time (10-20), and rotation speed (150-450 rpm) on the electrochemical activity of SnO₂ as an anode in degrading methylene blue (MB) were investigated. Results showed that increasing oxalic acid concentration gives better performance in degrading MB while increasing anodizing potential enhanced the electrode activity up to a potential of 5 V beyond which no enhancement of electrode activity towared MB degradation was noted. Longer time of anodizing has o

   Per- and polyfluoroalkyl substances (PFAS) are persistent and toxic contaminants that are difficult to remove from complex wastewater because dissolved organic matter, salts, co-pollutants, and membrane fouling reduce treatment efficiency. This study evaluated an integrated adsorption-membrane process for PFAS removal through combined Aspen Plus/MATLAB simulation and bench-scale validation using synthetic complex wastewater. Adsorbent dosage (0.10-1.00 g/L), transmembrane pressure (4-10 bar), and filtration time were investigated. Standalone adsorption was limited by its reduced affinity for short-chain PFAS and by competitive uptake of co-existing dissolved organic matter, whereas standalone nanofiltration was constrained by progre

   Conversion of waste tires and date stones into char through co-pyrolysis is an effective way to safely remove and recycle these materials. This study tested char as a low-cost adsorbent for removing nitrate and phosphate in fixed-bed systems, offering a way to reuse waste tires and date stones. The effects of inlet pollutant concentration (50, 150, and 300 mg/L), flow rate (5, 10, and 15 ml/min), and bed height (5, 10, and 15 cm) on the adsorption system’s breakthrough were measured. Characteristics of char were analyzed via the Fourier transform of infrared (FTIR), Brunauer-Emmett-Teller (BET), and zeta potential. The fixed-bed analysis demonstrated superior correlation of breakthrough data with both the Yoon-Nelson and Thomas mo

   The cost of raw materials and the production process remain major challenges hindering the expansion of biodiesel production on a large scale. Several technologies have been developed to reduce production costs. This research aims to investigate the energy recovery and economic aspects of biodiesel production from used cooking oil (WCO) using conventional and microwave (batch and continuous) transesterification technology. Used cooking oils are an alternative source of energy, given their high potential for use in biofuels production, especially biodiesel. The production of biodiesel in this study relies on a basic esterification reaction using calcium oxide prepared from willow leaves as a catalyst. The results showed that the opti

   Drilling operations in the Halfaya oilfield frequently encounter severe wellbore instability challenges. When navigating shale deposits, wellbore instability remains the primary operational concern. Based on the analysis of the wellbore instability intervals, low-strength shale and marlstone formations are identified as the principal unstable zones that lead to non-productive time and higher drilling costs. By planning a safe operating mud window, these non-productive times and drilling costs can be mitigated. Several wellbore instability concerns have been found in a southern Iraqi oil field. A problem-diagnostic technique was done by evaluating well log data, drilling reports, mud logging reports, and pore pressure readings. In we

In this work, the possibility of utilizing osmosis phenomenon to produce energy as a type of the renewable energy using Thin Film Composite Ultra Low Pressure membrane TFC-ULP was studied. Where by forward osmosis water passes through the membrane toward the concentrated brine solution, this will lead to raise the head of the high brine solution. This developed static head may be used to produce energy. The aim of the present work is to study the static head developed and the flux on the high brine water solution side when using forward and reverse osmosis membranes for an initial concentration range from 35-300 g/l for each type of membrane used at room temperature and pressure conditions, and finally calculating the maximum possible po

The water injection of the most important technologies to increase oil production from petroleum reservoirs. In this research, we developed a model for oil tank using the software RUBIS for reservoir simulation. This model was used to make comparison in the production of oil and the reservoir pressure for two case studies where the water was not injected in the first case study but adding new vertical wells while, later, it was injected in the second case study. It represents the results of this work that if the water is not injected, the reservoir model that has been upgraded can produce only 2.9% of the original oil in the tank. This case study also represents a drop in reservoir pressure, which was not enough to support oil production

Different additives are used in drilling fluids when the demanded properties cannot be gotten with clays. Drilling muds needs several additives and materials to give good characteristics. There are local alternatives more suitable for enhancing the rheology and filtration of drilling fluids. An experimental work had been conducted to assess the suitability of using potato starch to enhance rheological properties and filtration in drilling mud. This study investigated the potato starch as a viscosifier and fluid losses agent in drilling fluid. Results from this study proved that rheological properties of potato starch mud increased when pH of drilling fluid is increased.  Potato starch could be used to enhance gel strength at low pH

   This research investigated the two-phase flow behavior and mass transfer of CO₂ bubbles in a water-sucrose solution in a horizontal pipe. The process used A Computational Fluid Dynamic (CFD) model that offers diverse applications in numerous industries. The simulation of two-phase flow with mass transfer is carried out using COMSOL^® software version 5.6 and compared with experimental results. The model verified satisfactory concurrence with the experimental data. Multivariable such as concentration, velocity, and share rate were studied under different conditions (gas flow rate, liquid flow rate, bubble diameter, pipe diameter, and sucrose concentration). The gas flow rate was varied at the inlet, with val