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The 3-aminoacetophenone and 4-aminoantipyrine were used as precursors to prepare new six ligands. The three new ligands (L1,L2 and L3) were synthesis by reacting one mole of 3-aminoacetophenone with one mole of (Acetyl chloride), (benzoyl chloride), (4-methoxybenzoyl chloride) and ammonium thiocyanat in acetone as a solvent, they are:-
L1 (AAA) =[N-(3-acetylphenylcarbamothioyl)acetamide]
L2 (BAA) =[N-(3-acetylphenylcarbamothioyl)benzamide]
L3 (MAA) =[N-(3-acetylphenylcarbamothioyl)-4-methoxy benzamide]
Also three new derivatives of 4-aminoantipyrine were synthesis by reacting one mole of 4-aminoantipyrine with one mole of (Acetyl chloride), (benzoyl chloride), (4-methoxybenzoyl chloride) and ammonium thio
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