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Metal Complexes Derived from Mixed Azo-linked Schiff-base Ligand with Dithiocarbamate Derivative: Formation, Spectral Characterization and Biological Study
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The study includes preparation and characterisation of mixed azo-linked Schiff-base and DTCs ligands and their complexes. The starting material was isolated from the mixing of naphthyl amine diazonium salt with 2-aminophenolein a 1:1 mole ratio in water. In this work, the formation of azo-linked Schiff-base and DTCs ligands are reported. Ligand of the azo-linked Schiff-base was achieved by the reaction of starting material with 4-(dimethylamino)benzaldehyde) (HL1). The DTCs was isolated by the reaction of (C6H5)2NH with carbon disulphide in potassium hydroxide (L2). The complexes were prepared by mixing the azo-linked Schiff-base ligand and DTCs ligand with the metal salts; CoII, NiII, ZnII and CdII in a 1:1:1 mole ratio. Ligands and complexes were characterised by analytical and spectroscopic analyses including; microanalysis, chloride content, thermal analysis, magnetic susceptibility for complexes, conductance, FTIR, UV-Vis and 1H-NMR spectroscopy. Physico-chemical techniques indicated complexes demonstrated four and six coordinate structures in the solid and solution state. Biological activity of the ligands and their metal complexes were screened for their antimicrobial activity against four bacterial species (Escherichia coli and Enterobacter Gram - ve, (Bacillus stubtilis and Staphylococcus aureus Garam + ve.

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Publication Date
Fri Mar 01 2019
Journal Name
Spatial Statistics
Efficient Bayesian modeling of large lattice data using spectral properties of Laplacian matrix
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Spatial data observed on a group of areal units is common in scientific applications. The usual hierarchical approach for modeling this kind of dataset is to introduce a spatial random effect with an autoregressive prior. However, the usual Markov chain Monte Carlo scheme for this hierarchical framework requires the spatial effects to be sampled from their full conditional posteriors one-by-one resulting in poor mixing. More importantly, it makes the model computationally inefficient for datasets with large number of units. In this article, we propose a Bayesian approach that uses the spectral structure of the adjacency to construct a low-rank expansion for modeling spatial dependence. We propose a pair of computationally efficient estimati

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Publication Date
Mon Sep 30 2024
Journal Name
Iraqi Journal Of Science
Effect of Atmospheric Mixing on Spectral Reflectivity in Sentinel Images of Baghdad Province
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The lowest layer of the atmosphere is called the atmospheric mixed layer, characterized by small-scale, irregular air motions defined by winds that change in speed and direction. Aerosol radiative effects impact the atmospheric boundary layer (ABL), which holds most aerosols in the lower atmosphere. Aerosol absorption and scattering both lower the quantity of solar energy that reaches the ground, which has an impact on the spectral signature of the land coverings. In this study, 51 locations in downtown Baghdad were chosen for four different types of land cover (water bodies, farms, open areas, and residential areas) for Sentinel 2 satellite imagery, and the time the pictures were taken was 8:00 am ( 22 March, 22 June, 20 September,

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Publication Date
Fri Mar 26 2021
Journal Name
Chemical Papers
DFT, anticancer, antioxidant and molecular docking investigations of some ternary Ni(II) complexes with 2‑[(E)‑[4‑(dimethylamino) phenyl]methyleneamino]phenol
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The biological activities of some ternary nickel complexes with a Schiff base obtained from 4-dimethylaminobenzaldehyde and 2-aminophenol have been reported. The Schiff base ( HL1) acts as a primary ligand whereas, anthranilic acid ( HL2), 2-nitroaniline ( HL3), alanine ( HL4) and histidine ( HL5) act as secondary ligand or co-ligand. The anticancer activity of these compounds was studied against human colon carcinoma (HCT-116), human hepatocellular liver carcinoma (HEPG-2) and human breast carcinoma (MCF-7) cell lines. As per the results, the compounds were active against the cell lines. The antioxidant activity of the same compounds was evaluated using DPPH (1,1-diphenyl-2-picryl-hydrazyl) radical scavenging and compared with ascorbic aci

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Publication Date
Wed Dec 30 2015
Journal Name
Al-kindy College Medical Journal
Estimation Of Left Ventricular Ejection Fraction Using Mitral Annular Displacement Derived By Speckle Tracking Echocardiography In Patients With Different Heart Diseases
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Background: Speckle tracking echocardiography (STE)-derived mitral annular displacement (MAD) utilizes the speckle tracking technique to measure strain vectors, which provides accurate estimates of left ventricular ejection fraction (LVEF).Objectives: To validate the accuracy of mitral annular displacement (MAD), assessed by Speckle Tracking Echocardiography (STE), as a surrogate for determination of left ventricular systolic function in comparison to 2-Dimensions Simpson method in patients with different heart diseases.Methods : This cross-sectional study included patients who referred to outpatient department of Ibn Albitar Center for Cardiac Surgery, Baghdad, Iraq, between October 2012 and April 2013. STE continuously tracked annular

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Publication Date
Wed Jan 01 2020
Journal Name
International Journal Of Software & Hardware Research In Engineering
Frontal Facial Image Compression of Hybrid Base
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Publication Date
Mon Jul 01 2019
Journal Name
International Journal Of Computer Science And Mobile Computing
Color Image Compression of Inter-Prediction Base
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Publication Date
Mon Oct 01 2018
Journal Name
International Journal Of Modern Trends In Engineering And Research
Quadtree Partitioning Scheme using Fixed Predictor Base
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Publication Date
Sat Apr 01 2017
Journal Name
Journal Of Alloys And Compounds
Structural and optical characteristics of pre- and post-annealed sol-gel derived CoCu-oxide coatings
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Sol-gel derived CuCo-oxide coatings as solar selective surfaces, synthesized onto aluminium substrates at various annealing temperatures, are analysed by correlating their structural, chemical bonding states, and surface morphological topographies. As the annealing progressed, all the coatings displayed a Cu0.56Co2.44O4 (ICSD 78-2175) phase with preferential orientation along (400) reflection plane. Rietveld refinement of X-ray diffraction (XRD) data indicate that residual stress and microstrains developed around the coating surfaces are reduced resulting in mechanically stable thin films. Enhancement of the crystallite size and preferred orientation of the surface were confirmed via XRD, field emission scanning electron microscopy (FESEM),

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Publication Date
Mon Oct 06 2025
Journal Name
Plasmonics
Removal of Mercury Hg(II) from Industrial Wastewater by Formation of TiO₂@Ag/HNT Nanocomposite Using Bio-microwaved Synthesized TiO₂@Ag NPs (Core Shell)
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An environmentally friendly technique was used to prepare titanium dioxide@ silver (core shell) (TiO₂@Ag NPs) using chard leaf extract, a natural stabilizer and reductant. A nanocomposite (NCs) of TiO₂@Ag supported by halloysite nanotubes (HNTs), TiO2@Ag/HNT NCs, was prepared under microwave irradiation. The microwave technique is used to accelerate the reaction and enhance the homogeneity of nanoparticle distribution. Spectroscopic and structural analyses were performed on the resulting nanocomposite. X-ray diffraction (XRD) revealed a clear crystalline structure with grain sizes ranging from 7 to 15 nm, with an average of ~11 nm, the transmission electron microscope (TEM) revealed that the size of nanoparticles in the TiO₂@Ag/HNT N

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Publication Date
Mon Oct 06 2025
Journal Name
Plasmonics
Removal of Mercury Hg(II) from Industrial Wastewater by Formation of TiO₂@Ag/HNT Nanocomposite Using Bio-microwaved Synthesized TiO₂@Ag NPs (Core Shell)
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