This work revealed the spherical aromaticity of some inorganic E4 cages and their protonated E4H+ ions (E=N, P, As, Sb, and Bi). For this purpose, we employed several evaluations like (0D-1D) nucleus independent chemical shift (NICS), multidimensional (2D-3D) off-nucleus isotropic shielding σiso(r), and natural bond orbital (NBO) analysis. The magnetic calculations involved gauge-including atomic orbitals (GIAO) with two density functionals B3LYP and WB97XD, and basis sets of Jorge-ATZP, 6-311+G(d,p), and Lanl2DZp. The Jorge-ATZP basis set showed the best consistency. Our findings disclosed non-classical aromatic characters in the above molecules, which decreased from N to Bi cages. Also, the results showed more aromaticity in E4 than E4H+

The reaction of 2-amino benzoic acid with 1,2-dichloroethane under reflux in methanol and KOH as a base to gave the precursor [H₄L]. The precursor under reflux and drops of CH₃COOH which reacted with (2mole) from salicycaldehyde in methanol to gave a new type N₂O₄ ligand [H₂L], this ligand was reacted with (MCl₂) Where [M= Co (II), Ni(II), Cu(II) and Zn(II)] in (1:1) ratio at reflux in methanol using KOH as a base, to give complexes of the general formula [M(L)]. All compounds have been characterized by spectroscopic methods [¹H NMR ( just to the ligand), FTIR, uv-vis, atomic absorption], melting point, conductivity, chloride content, as well as m

The reaction of 2-amino benzoic acid with 1,2-dichloroethane under reflux in methanol and KOH as a base to gave the precursor [H4L]. The precursor under reflux and drops of CH3COOH which reacted with (2mole) from salicycaldehyde in methanol to gave a new type N2O4 ligand [H2L], this ligand was reacted with (MCl2) Where [M= Co (II), Ni(II), Cu(II) and Zn(II)] in (1:1) ratio at reflux in methanol using KOH as a base, to give complexes of the general formula [M(L)]. All compounds have been characterized by spectroscopic methods [1H NMR ( just to the ligand), FTIR, uv-vis, atomic absorption], melting point, conductivity, chloride content, as well as magnetic susceptibility measurements. From the above data, the proposed molecular structu

سارت اليهودية على نهج التوحيد بعدما بعث الله تعالى موسى (عليه السلام) ليبلغهم رسالات ربهم، ليكونوا على هدى وصراط قويم، غير أن القوم لم يستقيموا على ذلك الصراط" فبدلوا وأولوا وتمردوا على موسى (عليه السلام) وصوروا الرب حسب أهواء أنفسهم لأنهم جبلوا على حب المادة والإيمان بالمشهود، فصوروا الرب بصور عدة بما يتماشى مع ما الفت عليهم نفوسهم .

تصنيع الطابوق الحراري الثقيل من خامات محلية

ملخـــص البحــــث

يرجع تأريخ ظهور الفساد إلى بداية الخلق والخليقة، إذ اهتم الأديان السماوية بها كثيراً; وذلك لتوعية الناس إلى أن جَلل المصاب تكمن وراء هذه الظاهرة.

والقرآن الكريم اهتم بهذا الجانب اهتماماً بالغاً، فقد ذكر تأثيرات الفساد على المجتمعات عموماً، وعلى الأفراد خصوصاً، ولم تأتِ آية كريمة تتحدث عن آثا

In fact, the main idea of ​​the manuscript is to take note of a branch of Islamic jurisprudence, which is the science of jurisprudential jurisprudence and this manuscript in its title and subject dealt to the men of knowledge of jurisprudence because of its ambiguity calls for thinking, and the brainstorming mood to test the intelligence of jurisprudence, Of students of knowledge jurisprudence. This section contains (14) questions starting with the question (26) and ending with (39) in the doors of pray.