An experimental study was conducted with low cost natural waste adsorbent materials, barley husks and eggshells, for the removal of Levofloxacine (LEVX) antibacterial from synthetic waste water. Batch sorption tests were conducted to study their isothermal adsorption capacity and compared with conventional activated carbon which were, activated carbon > barley husks > eggshells with removal efficiencies 74, 71 and 42 % with adsorbents doses of 5, 5 and 50 g/L of activated carbon, barley husks, and eggshells respectively. The equilibrium sorption isotherms had been analyzed by Langmuir, Freundlich, and Sips models, and their parameters were evaluated. The experimental data were correlated well with the Langmuir model which gives the best fit for LEVX adsorption / biosorption on to activated carbon, barley husks, and eggshells respectively.
The adsorption capacity was almost dependent on temperature. The thermodynamic parameters associated with the adsorption process, ΔGo , ΔHº and ΔSº were reported and it is suggested to be physisorption, and of exothermic nature.
The physiochemical properties are considered to be as important guidelines for quality of water and their use for social, agricultural and different ecological applications. Fourteen properties were investigated in this study, including (PH, Electrical Conductivity (EC), Total Dissolved Salts(TDS), Turbidity,Total Hard ness(TH),Sodium(Na),Calcium(Ca),Magnesium(Mg),Carbonate(CO3),Chloride (Cl),Phosphate(PO4),Nitrite(NO2),Nitrate(NO3),and Sulphate(SO4) for the wells water at Albualwan region in Al - Anbar province east of Iraq . The results showed that the studied properties recorded values since were (7.3,2230.5Ms\Cm ,869.5ppm,0.32NTU,521.31ppm,3.6gr\L,111.5ppm,139.05ppm,296.86ppm, 116 .6ppm,0.42ppm,0,02ppm,4.7ppm and 4
... Show MoreZubair area is located at the extreme part of the south of Iraq and represents the southern part of the western desert, bounded by the north latitudes 30o05'-30o25' and east longitudes 47o30'- 47â—¦55'. Groundwater is a major natural resource in the study area because no perennial river exists. Groundwater from twenty wells in the study area were analyzed in order to determine some of chemical variables such as major cations (Ca+2, Mg+2 ,Na+ ,K+ ) and major anions (CL- ,SO4-2 ,HCO3- ,CO3-2 ,NO3-) along with several physical variables such as hydrogen ion concentration (pH) , total dissolved solids (TDS), and electrical conductivity (EC). Hydro-chemical analysis showed that the groundwater of the study area is excessively minera
... Show MoreThe natural radioactivity levels in water samples along the Tigris river (one of the major rivers of the world) within Baghdad city were investigated to determine and evaluate the radioactivity risks in the water of the river. The specific activity of the radionuclides (238U, 232Th, 40K, and 137Cs) for thirty different water samples from Tigris river within Baghdad city were measured using gamma-ray spectrometer, employing a NaI(Tl) scintillation detector. The results showed that the average value of the specific activity for 238U, 232Th, 40K, and 137Cs were (24.20, 16.70, 329.22, and 19.40) Bq/l, respectively. The calculated average annual effec
... Show MoreSediment samples were collected from main water processing and supply plants in Baghdad, and tested for radioactivity from both natural and artificial sources. These stations are: East Dijla (Tigris), Al-Kadisia, Al-Karama, Al-Rasheed, Al-Sader, Al-Wathba, and Al-Wihda supply stations. Qualitative measurements were made, and the results showed that most sediments exhibited natural radioactive level and sometimes less than the international regular standards. Specially, K-40 and Ra-226 results were much less than the standards for radioactive concentrations. Ac-228 concentration was found rather than Th-232 (in Al-Sader and Al-Wihda samples) but with low concentrations of about 10-15 Bg/kg and detection confidence ~45% , and Ce-141 and Be
... Show MorePersistence of antibiotics in the aquatic environment has raised concerns regarding their potential influence on potable water quality and human health. This study analyzes the presence of antibiotics in potable water from two treatment plants in Baghdad City. The collected samples were separated using a solid-phase extraction method with hydrophilic-lipophilic balance (HLB) cartridge before being analyzed. The detected antibiotics in the raw and finished drinking water were analyzed and assessed using high-performance liquid chromatography (HPLC), with fluorometric detector and UV detector. The results confirmed that different antibiotics including fluoroquinolones and
To evaluate and improve the efficiency of photovoltaic solar modules connected with linear pipes for water supply, a three-dimensional numerical simulation is created and simulated via commercial software (Ansys-Fluent). The optimization utilizes the principles of the 1st and 2nd laws of thermodynamics by employing the Response Surface Method (RSM). Various design parameters, including the coolant inlet velocity, tube diameter, panel dimensions, and solar radiation intensity, are systematically varied to investigate their impacts on energetic and exergitic efficiencies and destroyed exergy. The relationship between the design parameters and the system responses is validated through the development of a predictive model. Both single and mult
... Show MoreIraq, home of the Tigris and Euphrates rivers, has survived an extreme deficiency of surface water assets over the years. The gap is due to the decline of the Iraqi water share every year, as well as a high demand for water use from different sectors, particularly agriculture.
Dam development has long given significant economic benefits to Iraq in circulating low‐priced electricity and supporting low‐income farmers by supplying them with a free irrigation system (Zakaria et al, 2012). This encouraged domestic consumption and investment.
Despite the fact that numerous advantages are expected from dam construction, it should be painstakingly assessed, utilizing cost
For hydrochemical assessment of water resources at Baquba City, Diyala Governorate, four surface water samples were collected from the Diyala River and eight groundwater samples inside the city of Baquba. The samples were collected in the two periods, the dry period in October 2018 and the wet period in February 2019. The pH, EC, TH, turbidity, the major ions and trace elements (Fe, Cu, Co, Cd, Pb, Zn and Ni) were investigated. The results showed that the surface and groundwater are turbid, very hard and slightly brackish to moderately saltine in the groundwater, while it is hard to very hard and fresh in surface water. Heavy element analyzes revealed contamination of surface water samples and groundwater with the elements Cadmi
... Show MoreThe climate parameters annual rainfall and average mean temperature are investigated from 2000 to 2019 for Kut, Hilla and Iskandaryia. Evidence of climate change is noticed by decreasing the mean annual rainfall and relative humidity with an increase in the annual mean temperature. The climate water balance has been calculated. Due to high temperature, increased evaporation, and low precipitation rates, there was a large water deficit. The total water surplus in the Kut area is 32.86 mm from November to February, and in Hilla and Iskandaryia is 20.4 and 27.8 mm from December to February, respectively. The climate classification for the three stations was semi-dry to dry climates. The region has a significant water deficit of u
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