In this research an experimental study has done for testing the thermal performance of selective surfaces used in solar collectors for substrate of iron, galvanized iron and aluminum which are commercially available. The coating process for the samples has done in two ways, the electroplating and the chemical spray pyrolysis. The results of the thermal performance test of these samples are comparing with the thermal performance of a sample without paint and other paint with black paint without shines commercially available. For the electroplated samples, the performance study has done for different immersion time in plating bath, the
distance between electrical poles, the current density, and area ratio of the sample plated area to the nickel pole face area. The chemical sprayed pyrolysis samples, study has done for different coating times, atomizing gas pressures, distance between the aperture of atomizer and the sample and the paint mass flow rate. The results showed that the best performance of the iron's
samples is the sample which is coated with two layers. The first layer is of zinc done by electroplating where the time of plating is (2 min.) and the second layer is of black nickel done by electroplating, where the time is (20 min.), the distance between the poles is (6 cm), the current density is (0.15 A/dm2 ) and area ratio of the sample plated area to the nickel pole face area is equal to (1). The percentage of the increasing in heat storage of electroplating sample to galvanized iron sample without paint at the beginning of testing the performance of samples and at the end were (58.23%& 44.97%) respectively. For aluminum samples, the best performance was regarded for two samples electroplating sample and chemical spray pyrolysis sample. The best electroplating sample was coated with a layer of black nickel where the time of plating is (20 min.), the distance between the poles is (6 cm), the current density is (0.15 A/dm2) and area ratio of the sample plated area to the nickel pole face area is equal to (1). While the best chemical spray pyrolysis sample has been coated with a layer of black nickel where the time of plating is (16 sec.) and the distance between the aperture of the reservoir and the surface of the sample is (27 cm), the amount of flow is (4.8 ml / min.), the atomizing gas pressure is (1 bar) and temperature of the sample surface is (290 0C).
Erratum for Organic acid concentration thresholds for ageing of carbonate minerals: Implications for CO2 trapping/storage.
A new, simple, sensitive and fast developed method was used for the determination of methyldopa in pure and pharmaceutical formulations by using continuous flow injection analysis. This method is based on formation a burgundy color complex between methyldopa andammonium ceric (IV) nitrate in aqueous medium using long distance chasing photometer NAG-ADF-300-2. The linear range for calibration graph was 0.05-8.3 mmol/L for cell A and 0.1-8.5 mmol/L for cell B, and LOD 952.8000 ng /200 µL for cell A and 3.3348 µg /200 µL for cell B respectively with correlation coefficient (r) 0.9994 for cell A and 0.9991 for cell B, RSD % was lower than 1 % for n=8. The results were compared with classical method UV-Spectrophotometric at λ max=280 n
... Show MoreThe effect of thickness variation on some physical properties of hematite α-Fe2O3 thin films was investigated. An Fe2O3 bulk in the form of pellet was prepared by cold pressing of Fe2O3 powder with subsequent sintering at 800 . Thin films with various thicknesses were obtained on glass substrates by pulsed laser deposition technique. The films properties were characterized by XRD, and FT-IR. The deposited iron oxide thin films showed a single hematite phase with polycrystalline rhombohedral crystal structure .The thickness of films were estimated by using spectrometer to be (185-232) nm. Using Debye Scherrerś formula, the average grain size for the samples was found to be (18-32) nm. Atomic force microscopy indicated that the films had
... Show MoreThe reaction oisolated and characterized by elemental analysis (C,H,N) , 1H-NMR, mass spectra and Fourier transform (Ft-IR). The reaction of the (L-AZD) with: [VO(II), Cr(III), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II)], has been investigated and was isolated as tri nuclear cluster and characterized by: Ft-IR, U. v- Visible, electrical conductivity, magnetic susceptibilities at 25 Co, atomic absorption and molar ratio. Spectroscopic evidence showed that the binding of metal ions were through azide and carbonyl moieties resulting in a six- coordinating metal ions in [Cr (III), Mn (II), Co (II) and Ni (II)]. The Vo (II), Cu (II), Zn (II), Cd (II) and Hg (II) were coordinated through azide group only forming square pyramidal
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