A theoretical calculation of the reorientation energy for non adiabatic electron transfer at
interface between metal and semiconductor system was carried out. The continuum outer
sphere theory of electron transfer reaction has been extensively used for electron transfer
between metal/semiconductor interface .It is found that in these calculations the reorientation
energy is proportional to the optical and statistical dielectric constant of semiconductor ,
properties of metal ,and the distance between metal and semiconductor .Results of
reorientation energy show that ZnO semiconductor with metal Au possess a good matching as
compared with ZnS and ZnSe . Theoretical calculation showed a good agreement with
experimental value.
In this work the strain energy of tetrahedrane and its nitrogen substituted molecules were calculated by isodesmic reaction method according to DFT quantum chemical fashion, the used basis set was 6-31G/B3-LYP, in addition all structures were optimized by RM1 semi-empirical method. From the obtained data we estimate an empirical equation connect between strain energy of the molecule with charge functions represented by dipole moment of the molecule plus accumulated charge density involved within the tetrahedron frame plus the number of nitrogen atoms. The results indicate the charge spreading factors by polarization and processes are the most important factors in decreasing the strain energy.
Liquid – liquid interface reaction is one of the method to prepare nanoparticles, the preparation of nanoparticles depends on the super saturation of ions which can satisfy by layered two immiscible liquid (toluene and deionized (DI) water). The XRD-diffraction analysis give a mix structure from hexagonal and cubic and the average grain size is 7.73 nm using Sherrer relation and 9.54 nm using Williamson –Hall method. Transmission electron microscopy (TEM) Showed that the size of particles around 3 nm which is comparable with Bohr radius of CdS.
From UV-Visible spectrum analysis which use two model to estimate the radius of particles , the first one is effective mass approximate (EMA) model and the second one is tight binding model
Assessment of annual wind energy potential for three selected sites in Iraq has been analyzed in the present work. The wind velocities data from August 2014 to July 2015 were collected from the website of Weather Underground Organization (WUO) at stations elevation (35m, 32m, and 17m) for Baghdad, Najaf, and Kut Al-Hai respectively. Extrapolation of stations elevation and wind velocities was used to estimate wind velocities at (60m, 90m, and 120m). The objectives are to analyze the wind speed data and assess the wind energy potential for wind energy applications. Computer code for MATLAB software has been developed to solve the mathematical model. The results are presented as a monthly and annual average for wind velocities, standard deviat
... Show MoreThe ion tail temperature of the comet ISON was calculated by using magneto-hydrodynamic MHD laws. From these equations the focus is concentrating on determine the ion tail temperature from the relations of dynamic and static pressures results.MHD equations are numerically solved using Matlab simulation code using cubic volume element method, based on three dimensionl Cartesian coordinates that devided into equal 15x15x15 equally spaced mesh. The simulation was performed using 3-D Lax explicit method considering normalised physical propreties relative to those of the solar wind at 1 AU. The results explained that it is possible to deduce two types of temperature, the first being the isotropic temperature which is shown to vary slowly with
... Show MoreBefore setting a turbine in a wind farms allocated for power generation, it must be know the appropriate turbine class for that site depending on the turbulence intensity of the winds in the studied area and the IEC-61400 standard. The importance of identifying a class of wind turbine is due to the complex environmental conditions that produce turbulent air which, in turn, may cause damage to the turbine blades and weakness in the performance. Therefore, the ambient turbulence intensity is a very important factor in determining the performance and productivity of the wind turbines.
In this research we calculate Turbulence Intensity "TI" in the province of Nasiriyah, south of Iraq (Lat. 31.052049 , Lon. 46.261021) for the years 2008, 2