Preferred Language
Articles
/
jih-1381
Equilibrium, Kinetic and Mechanistic Studies of Formation of Cis- mono (AA)bis (oxaJato) Chromate (III) C,omplex (where AA is · glycine, alanine and histidine)In Monderately Aqueous Acidic Solution
...Show More Authors

Equilrium, kinetic  and mechanistic studies  for  thcoordination of

 

;

 

some amino acids  "'AA'1

 

glycine,  alanine, .a:ncl  histidine, to  Cr  (Ill)

 

center  of trans .[Cr(ox}2(B.2 0hr   {TJ'} cornplein monderarely  acidic

range ofpH=4.8-6-.7 ( p =Q.4M NaN03) are  reported.  The equili rium

c.onsta:nts   at  25°C   .were  found   logKequ.=4.95J ,5.206and5.128for glycine, alap.ine, md histidine, ligation. reactions  respectively..  The substitution reaction is kinetically  involve  rwo parallel  complex reactions, each  inch,tdes there  difierent e_onsecutive steps of different

·

 

species of Ct(III).  The  reactant,  Ti, branches  through  byrolysis  into, doubly  charged anion, conjugated    se of  trans[Cr(ox)22(H0)0Hr2

whlch  inleracts  with  (AAH)   to  from  outer-sphere  complex,   that  is followed  by interchange reaction  of one molecule H20 with one end of    AA-        ron   from                   an         active        intermediate         species   of              trans­ [Cr(Qx)2(AA)OHT3           which               cbanges       to        final           product ;                c.is­ [Cr(ox}1(AA)J?. While  the  remai ning  part  of reactant   interacts also

with zwitter i:on (AAH)  on  other  side  to form  another  outer-sphere

.complex  which  also  undergaes interchange  reaction of one  molecule

 

H10 wHh AA- ion to ive two· active  intennediates species, trans and cis-[Cr(ox)2(AA)H2 or, whlch later convert tp the same prod·uct .; cis­

fCr(ox)z(AA)]2-.      TI1e      interchange      rate      co.nstant    of     trans­ [Cr(ox)2(AA)OH]                                             formation  relatively   appears  much  larger  than (A H*=8.8kc 1/n1ol)         that                                 of    ds[Cr(.oxh  AA)H:z Ot                     formation

( l\ H*·=14.0Kca l/mol), wbile  the latter rate constant'is oeaily  (5-10)

time l(!I'ger than that oftrans-{Cr(ox)2(AA)H20t fennatlon

View Publication Preview PDF
Quick Preview PDF
Publication Date
Sat Oct 19 2019
Journal Name
Geotechnical And Geological Engineering
Local Scale Displacement Fields in Grains–Structure Interactions Under Cyclic Loading: Experiments and Simulations
...Show More Authors
Abstract<p>Soils encounter cyclic loading conditions in situ, for example during the earthquakes and in the construction sequences of pavements. Investigations on the local scale displacements of the soil grain and their failure patterns under the cyclic loading conditions are relatively scarce in the literature. In this study, the local displacement fields of a dense sand layer interacting with a rigid footing under the plane-strain condition are examined using both experiments and simulations. Three commonly used types of cyclic loading conditions were applied on the footing. Digital particle image velocimetry (DPIV) is used to measure the local scale displacement fields in the soil, and to understand the ev</p> ... Show More
View Publication
Scopus (10)
Crossref (10)
Scopus Clarivate Crossref
Publication Date
Tue Mar 30 2021
Journal Name
Iraqi Journal Of Science
Relationship Between Orexin-A and Insulin Resistance in Patients with Type 2 Diabetes Mellitus
...Show More Authors

Background: Orexin-A is an orexigenic hormone that plays an important role in the metabolism of blood glucose, insulin, and insulin resistance (IR). The pathogenesis of type 2 diabetes mellitus (T2DM) is related to the abnormality in insulin and IR. However, no sufficient studies to date have clearly shown the association of orexin-A with biochemical parameters related to T2DM.

Objectives: The aim of this study was to determine the relation of orexin-A with IR and how they associate with physiological changes in T2DM patients. Understanding this relation will offer some pharmacological tools to reduce some complications in diabetes.

Materials and Methods: A total of 41 T2

... Show More
View Publication Preview PDF
Scopus (2)
Crossref (2)
Scopus Crossref
Publication Date
Mon Feb 04 2019
Journal Name
Journal Of The College Of Education For Women
The Hygienic, natural and geographical significance in AL-Muntadham book for lbn AI-Jouzy
...Show More Authors

This study takes its importance in the area of systemic and historical
studies because it stands on presenting such aspects from the systematic
respect and now Ibn AL-Jouzy dealt with the text of this subject and how he
was exact in telling them.
Therefore, this study sheds light on the important aspects of this
method in his book through reading and studying such texts whether they had
direct or indirect relationship with this subject.
This study is not an easy task since it is based on contriving the
intellectual aspects in the methods of lbn AL-Jouzy and how he deals with the
text of this subject in its hygienic, natural and geographical aspects in
constructing a historical method in most scripts, the gen

... Show More
View Publication Preview PDF
Publication Date
Thu Nov 02 2017
Journal Name
Ibn Al-haitham Journal For Pure And Applied Sciences
The Relationship Between the Attitude and Achievement in Mathematics for Intermediate Second Class Students
...Show More Authors

Many studies mentioned that there is a decline in the a achievement of intermediate second class students in mathematics  . Parents and mathematics   teachers   had  emphasized   that  .  The  studies   related  this decline to the students weak attitude towards mathematics .

In spite  of the  importance  of this subject  , it has not been given enough attention  in research in our country . This research is an attempt to know  th e relationships  between  the  intermediate  second  class  students  , attitude and their achievement  in mathematics .

Also, to know the statistical sign

... Show More
View Publication Preview PDF
Publication Date
Thu Mar 15 2018
Journal Name
Journal Of Baghdad College Of Dentistry
Gingival Condition and Enamel Defect Among Secondary School Female Students in Kirkuk City/Iraq
...Show More Authors

Background: Gingivitis is one of the most common and widely spread oral diseases in adolescents after dental caries occur in both developed and developing countries. Dental plaque is the main etiological factor of gingivitis. Another oral problem is enamel defect. The aim of this study was to estimate the oral hygiene (dental plaque), and determine the prevalence and severity of gingivitis and enamel defects among 16-17 years old secondary school female students in urban areas of Kirkuk city/Iraq. Materials and methods: A representative sample included in this study consisted of 750 secondary school female students distributed into 387 for the age sixteen and 363 for the age seventeen, they were selected randomly from different female secon

... Show More
View Publication
Crossref
Publication Date
Thu Mar 30 2023
Journal Name
Iraqi Journal Of Science
Acute HAV Infected Patient's Distribution According to Age and Sex in Wasit Province/Iraq.
...Show More Authors

Hepatitis A virus infection occurs globally and is causing a public health
concern, primarily in developing countries due to its persistent circulation in the
environment. A total of 120 individuals were included in this study, anti-HAV IgM
antibodies were detected in serum of 100 individuals of them (patients group) who
attended the Wasit central public health laboratory from different cities in Wasit
Province, Iraq, during the period from November 2013 to March 2014.While
another 20 individuals were considered as control group which anti – HAV IgM
antibody was negative in their serum.
Acute infection is confirmed by detection of IgM anti–hepatitis A virus (HAV),
which appears early in the course of infect

... Show More
View Publication Preview PDF
Publication Date
Wed Sep 20 2017
Journal Name
Ibn Al-haitham Journal For Pure And Applied Sciences
Modified Radial Based Neural Network for Clustering and Routing Optimal Path in Wireless Network
...Show More Authors

Several methods have been developed for routing problem in MANETs wireless network, because it considered very important problem in this network ,we suggested proposed method based on modified radial basis function networks RBFN and Kmean++ algorithm. The modification in RBFN for routing operation in order to find the optimal path between source and destination in MANETs clusters. Modified Radial Based Neural Network is very simple, adaptable and efficient method to increase the life time of nodes, packet delivery ratio and the throughput of the network will increase and connection become more useful because the optimal path has the best parameters from other paths including the best bitrate and best life link with minimum delays. The re

... Show More
View Publication Preview PDF
Publication Date
Sun Jun 02 2013
Journal Name
Baghdad Science Journal
Measurement Radon Concentration in Imported and Local Wood Using Solid State Nuclear Track Detectors
...Show More Authors

Abstract: The aim of the present work is to measure radon concentration in wood. Solid state nuclear track detectors of type CR – 39 was used as measurement device. Eight different samples of imported and local wood were collected from markets. Samples were grinded, dried in order to measure radon concentrations in it. Cylindrical diffusion tube was used as detection technique. Results show that the higher concentration was in Iraqi sample 1 which recorded (14.02 ± 0.9) Bq / m3, while the less was in Emirates Sample which recorded (5.35 ± 1.2) Bq / m3. From the present work, all wood samples were with lowest concentrations of radon gas than other building materials.

View Publication Preview PDF
Crossref
Publication Date
Thu Feb 01 2024
Journal Name
Baghdad Science Journal
Predict the Laser Power and Recovery Period in Treatment by Endovenous Laser Ablation (EVLA)
...Show More Authors

            Eight patients (3 male and 5 female) were treated in this study by Endovenous Laser Ablation (EVLA); Mathematical models are proposed to estimate the applied laser power and to assess the recovery period. The estimations of the applied laser power and recovery period in these models will be depended mainly on the diameter of the incompetent vein.  In addition, Excel Program was utilized to find the proposed models.  A 1470 nm diode laser up to 15W continuous power (CW) was used in the treatment of venous ulcers by EVLA procedure. Following up by duplex ultrasound was started in the 1st week after the first session until the vein is completely closed. The present study concluded that the relationship both between

... Show More
View Publication Preview PDF
Scopus Crossref
Publication Date
Tue Jun 15 2021
Journal Name
Al-academy
Formal trespass and its intellectual manifestations in the contemporary interior space: ريم باسل نوري
...Show More Authors

The Interior design is concerned with designing and creating internal spaces and reformulating their ideas, thus separating their capacities for influence and achieving suitability and comfort for their occupants, and enabling them to use them in a manner that achieves their goals and requirements, and this is unfolded by the integrity of the functional, aesthetic and expressive performance that these spaces achieve, The behavior of its users includes a variety of activities in harmony with the influence of those spaces and their forms, so the designer was keen to have these spaces in a form with an effective role in harmony with the needs of the times and its complexities in formation and construction, familiar with the strong cultural,

... Show More
View Publication Preview PDF
Crossref