Wires are commonly used for the construction of orthodontic appliances and occasionally as wrought clasps and rests on partial dentures. The corrosion resistance is the most important properties of dental alloy. Corrosion process reported to cause a numerous adverse effects on both living tissue and restoration .The conditions in the mouth are very suitable for the occurrence of corrosion. The main objective of this study was to evaluate the corrosion behavior of different gauges of stainless steel wire in artificial saliva .Four gauges of dental stainless steel wire used in orthodontic and removable partial denture were used in this study 0.6mm.,0.7mm.,0 .8mm.&1.0mm.).The specimens were divided according to gauge in to four groups(A,B,C,&D ) ,ten specimens in each group .Each wire was cut by using wire cutter to get wire with (1cm) in length .Artificial saliva of Fusayama Meyer type was used as the testing solution .Sensitive electronic balance was used to weight the sample before immersion in solution and recording the results.This this represents the first weight(W1).Each specimen was put inside a test tube , and held using dental floss in a way that the specimen was fully immersed in the solution from all sides . The specimens then were put inside an incubator ,which was adjusted at 37±2 and left for 14 days .At the end of immersion period ; the specimens were removed from the solution and then allowed to dry and were balanced then the results were recorded .This represents the second weight (W2) .After obtaining the (W1)&(W2) the corrosion rate was calculated . The results before and after immersion showed that the 0.6 mm.& 0.7mm stainless steel wire gave the highest and more corrosion resistance value than 0.8mm&1.0mm.stainless steel wire . The result showed there is a statistical significance between (W1&W2) of 0.8mm stainless steel wire and highly significant between (W1&W2) of 1.0mm. stainless steel wire . The comparison of the results after calculating results in corrosion rate formula showed that the 1.0mm stainless steel wire more corrosion resistance followed by 0.8mm wire ,from 0.6mm& 0.7 mm wire .
Two well-known fluorescent molecules: fluorescein sodium salt (FSS) and 2,7-dichloro fluorescein (DCF) were tried to prove the efficiency, trustability and repeatability of ISNAG fluorimeter by using discrete and continuous flow injection analysis modes.A linear range of 0.002-1 mmol/L for FSS and 0.003-0.7 mmol/L was for DCF, with LOD 0.0018 mmol/L and 0.002 mmol/L for FSS and DCF respectively, were obtained for discrete mode of analysis. While the continuous mode gave a linear range of 0.002-0.7 mmol/L and 0.003-0.5 mmol/L for FSS and DCF respectively, the LOD were 0.0016mmol/L and 0.0018 mmol/L for FSS and DCF respectively. The results were compared with classical method at variable λex for both fluorescent molecules at 95
... Show MoreThe effect of thickness variation on some physical properties of hematite α-Fe2O3 thin films was investigated. An Fe2O3 bulk in the form of pellet was prepared by cold pressing of Fe2O3 powder with subsequent sintering at 800 . Thin films with various thicknesses were obtained on glass substrates by pulsed laser deposition technique. The films properties were characterized by XRD, and FT-IR. The deposited iron oxide thin films showed a single hematite phase with polycrystalline rhombohedral crystal structure .The thickness of films were estimated by using spectrometer to be (185-232) nm. Using Debye Scherrerś formula, the average grain size for the samples was found to be (18-32) nm. Atomic force microscopy indicated that the films had
... Show MoreThe reaction oisolated and characterized by elemental analysis (C,H,N) , 1H-NMR, mass spectra and Fourier transform (Ft-IR). The reaction of the (L-AZD) with: [VO(II), Cr(III), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II)], has been investigated and was isolated as tri nuclear cluster and characterized by: Ft-IR, U. v- Visible, electrical conductivity, magnetic susceptibilities at 25 Co, atomic absorption and molar ratio. Spectroscopic evidence showed that the binding of metal ions were through azide and carbonyl moieties resulting in a six- coordinating metal ions in [Cr (III), Mn (II), Co (II) and Ni (II)]. The Vo (II), Cu (II), Zn (II), Cd (II) and Hg (II) were coordinated through azide group only forming square pyramidal
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