Background: Studying and investigating the transverse strength(Ts), impact strength(Is), hardness (Hr) and surface roughness(Ra) of conventional and modified autopolymerizing acrylic resin with different weight percentages of biopolymer kraftlignin, after curing in different water temperatures; 40°C and 80°C. Material and Methods: Standard acrylic specimens were fabricated according to ADA specification No.12 for transverse strength, ISO 179 was used for impact testing, Shore D for hardness and profilometerfor surface roughness. The material lignin first dispersed in the monomer, then the powder PMMA is immediately added. Ligninadded in different weight percentages. Then cured using pressure pot (Ivomet) in two temperatures;40°C and 80°C under 2 bar pressure, for 30 minutes.Atotal of 144samples were prepared for this study. Ts, Is, Ra, and Hr were tested, by using Instron universal testing machine, charpy impact tester, shore D tester, and profilometer respectively. Results: The transverse strength increased in both the conventional and modified onewhen compared with that cured in air. The addition of 0.5wt% lignin gave the higher effect (78.0017MPa) with highly significant difference found between groups at 40°C polymerizing temperature. While the impact strength in both temperatures in the modified resin revealed increased results than conventional one, 1.25wt% of kraft lignin gave the highest value (12.7355KJ/m2) with highly significant differences found between groups at 80°C polymerizing temperature. Hardness and surface roughness showed also highly significant differences found between groups at 40°C polymerizing temperature, all the groups had increased Hr. than the control one (78.95), while the Ra. decreased for 1.0% ,1.25,1.50 and 1.75 wt% lignin content to (0.26,0.10,0.063, 0.12µm) respectively in 40°C polymerizing temperature, the lowest value present in 1.75 wt% lignin (0.05 µm) at 80°Cpolymerizing temperature. Conclusions: It seems that increasing the polymerizing temperature to 40°C had a positive effect on the mechanical properties of autopolymerizing acrylic resin and the one enforced by kraft lignin biopolymer in low percentages. Increasing the polymerizing temperature to 80°C will doesn’t have much positive effect but it doesn’t deteriorate the mechanical properties. However, when submitted to increasing the temperature to 80°C, specimens showed a significant increase in impact strength.
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Synthesis of a new class of Schiff-base ligand with a tetrazole moiety to form polymeric metal complexes with CoII, NiII, ZnII, and CdII ions has been demonstrated. The ligand was synthesised by a multi-steps by treating 5-amino-2-chlorobenzonitrile and cyclohexane -1,3-dione, the 5,5'-(((1E,3E)-cyclohexane-1,3-diylidene)bis(azanylylidene))bis(2-chlorobenzonitrile) was obtained. The precursor (M) was prepared from the reaction 5,5'-(((1E,3E)-cyclohexane-1,3-diylidene)bis(azanylylidene))bis(2-chlorobenzonitrile) with NaN3 to obtained (1E,3E)-N1,N3-bis(4-chloro-3-(1H-tetrazol-5-yl)phenyl)cyclohexane-1,3-diimine (N). By reacting the precursor (M) with CS2
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In the present work, a study is carried out to remove chromium (III) from aqueous solution by: activated charcoal, attapulgite and date palm leaflet powder (pinnae). The effect of various parameters such as contact time, and temperature has been studied. The isotherm equilibrium data were well fitted by Freundlich and Langmuir isotherm models. The adsorption capacity of chromium (III) that was observed by activated charcoal, attapulgite and date palm leaflet powder (pinnae) increased with the rise of temperature when the concentrations of Cr (III) were 600, 700 and 100mg/L respectively. The greatest adsorption capacity ofactivated charcoal, attapulgite and date palm leaflet powder (pinnae) at 10°C was 7.51, 5.39 and 0.77mg.gˉ¹ respective
... Show MoreThis study presents a detailed morphology and taxonomic study of Polysiphonia subtilissima collected from Abdul Rehman Goth, Karachi coast, Pakistan. Polysiphonia is a filamentous heterotrichous red algae, characterized by its branching structures and attachment mechanisms. P. subtilissima is notable for its broad salinity tolerance and wide distribution across marine and freshwater ecosystems. This research provides an in-depth examination of the internal and external structures of P. subtilissima, contributing to its systematic study and documenting its first recorded occurrence in Pakistani coastal areas, bordering the northern Arabian Sea. The findings enhance the understanding of the species taxonomy and its ecological role in
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A novel planar type antenna printed on a high permittivity Rogers’ substrate is proposed for early stage microwave breast cancer detection. The design is based on a p-shaped wide-slot structure with microstrip feeding circuit to eliminate losses of transmission. The design parameters are optimized resulting in a good reflection coefficient at −10 dB from 4.5 to 10.9 GHz. Imaging result using inhomogeneous breast phantom indicates that the proposed antenna is capable of detecting a 5 mm size cancerous tumor embedded inside the fibroglandular region with dielectric contrast between the target and the surrounding materials ranging from 1.7 : 1 to 3.6 : 1.
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