Background: This study compared in vitro the marginal adaptation of three different, low shrink, direct posterior composites Filtek™ P60 (packable composite), Filtek™ P90 (Silorane-based composite) and Sonic fill™ (nanohybrid composite) at three different composite/enamel interface regions (occlusal, proximal and gingival regions) of a standardized Class II MO cavity after thermal changes and mechanical load cycling by scanning electron microscopy. Materials and methods:Thirty six sound human maxillary first premolars of approximately comparable sizes were divided into three main groups of (12 teeth) in each according to the type of restorative material that was used: group (A) the teeth were restored with Filtek™ P60 and single bond™ Universal adhesive using horizontal incremental technique, group (B)the teeth were restored with Filtek™ P90 and P90 system adhesive using horizontal incremental technique and group (C) the teeth were restored with Sonic fill™ composite and single bond™ Universal adhesive using bulk technique.After specimens were stored in distilled water at 37°C for 7 days, all specimens were subjected to thermocycling at (5° to 55 °C), then submitted to mechanical load cycling (intermittent axial force of 49N and a total of 50.000 cycles). The specimens were observed under scanning electron microscope at (2000 X) to measure marginal gap width (the distance between the dental wall and the restoration) at occlusal, proximal and gingival regions in micrometer using Tescan software, version 3.5. Data were analyzed statistically by one way ANOVA test and least significant difference tests. Results:The results showed that the silorane-based posterior composite (Filtek™ P90) showed significantly the least marginal gap width at the occlusal, proximal and gingival regions after the application of thermal changes and mechanical load cycling in comparison to the two methacrylate-based posterior composite Filtek™ P60 (packable) and the Sonic fill™ (nano-hybrid). Sonic fill™ bulk fill composite that relied on the vibration concept to lower the viscosity of high filler loaded composite material showed significantly lesser marginal gaps width at occlusal, proximal and gingival composite/enamel interface regions in comparison with Filtek™ P60 (packable composite) using horizontal incremental technique. The silorane-based composite (Filtek™ P90) showed non-significant difference in marginal gaps width at the three different regions. While, both methacrylate based Filtek™ P60 and Sonic fill™ composite showed significantly lesser marginal gap width at the occlusal region in comparison with gingival regions. Conclusion: None of the low-shrinkage composite restorative materials tested in this study totally prevented micro-gap formation at composite/enamel interfaces of Class II MO cavity.
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In this study, the preparation and characterization of hyacinth plant /chitosan composite, as a heavy metal removal, were done. Water hyacinth plant (Eichhorniacrasspes) was collected from Tigris river in Baghdad. The root and shoot parts of plant were ground to powder. Composite materials were prepared at different ratios of plant part (from 2.9% to 30.3%, wt /wt) which corresponds to (30-500mg) of hyacinth plant (root and shoot) and chitosan. The results showed that all examined ratios of plant parts have an excellent absorption to copper (Cu (II)). Moreover, it was observed that 2.9% corresponds (30mg) of plant root revealed highest removal (82.7%) of Pb (II), while 20.23% of shoot removed 61% of Cd (II) within 24 hr
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Nanocrystalline micro-mesoporous ZSM/MCM-41 composite was synthesized using alkaline treatment method and two step of crystallization in poly tetraflouroethylene (PTFE) lined autoclave. The synthesized zeolites was characterized by X-Ray diffraction (XRD), Scanning electron microscopy (SEM), Transmission electron microscopy (TEM), Atomic force microscopy (AFM), Fourier transport infrared (FTIR), and N2 adsorption-desorption (BET). It was approved that the best results for alkaline leaching can be got with 1.5M NaOH solution. High surface (BET) area of 630 m2/g with pore volume of 0.55 cm3/g has been got. AFM reports showed a nano-level size for average particle size of 50nm.
Ternary polymer blend of chitosan/poly vinyl alcohol/ poly vinyl pyrrolidone was prepared by solution castingmethod, nanocomposite was prepared by sonication method with nano Ag and Zn. All prepared compounds have been characterizedby FT-IR, SEM, DSC, as well as Biological activity. Antimicrobialactivity related to prepared blendsand Nanocomposites againstsix types of bacteria namely, Staphylococcus aureas, E. faecalis, S.typhi, P. aeruginosa, Bacillus subtilis, Escherichia coli andC. albicans fungal were examined and evaluated. The results reveal that the prepared polymer blends and nanocompositeshavegood antimicrobial activity against all kinds of microbials.
The synthesis of new substituted cobalt Phthalocyanine (CoPc) was carried out using starting materials Naphthalene-1,4,5, tetracarbonic acid dianhydride (NDI) employing dry process method. Metal oxides (MO) alloy of (60%Ni3O4 40%-Co3O4 ) have been functionalized with multiwall carbon nanotubes (F-MWCNTs) to produce (F-MWCNTs/MO) nanocomposite (E2) and mixed with CoPc to yield (F-MWCNT/CoPc/MO) (E3). These composites were investigated using different analytical and spectrophotometric methods such as 1H-NMR (0-18 ppm), FTIR spectroscopy in the range of (400-4000cm-1), powder X-rays diffraction (PXRD, 2θ o = 10-80), Raman spectroscopy (0-4000 cm-1), and UV-Visib
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