Background: This in vitro study was carried out to evaluate the effect of various endodontic irrigants (sodium hypochlorite, ethylene diaminetetracetic acid and normal saline) on sealing ability of (Biodentine, mineral trioxide aggregate, and amalgam) used to repair furcal perforations. Material and methods: One hundred and twenty extracted human molars with divergent roots were used in this study. A standard root canal access cavity was prepared in each tooth and furcal perforation was made and was standardized by using k file size 100 instrument to get a perforation of (1.32mm) in diameter .The teeth were randomly divided in to three groups of 40 teeth according to the type of material used to repair the perforations (Group A: The furcal perforations were repaired with Biodentine, Group B: The furcal perforations were repaired with MTA ,Group C: The furcal perforations were repaired with Amalgam). Each group was then subdivided into 4 subgroups according to irrigation regimens applied over the repair site (Subgroup 1: without irrigation, Subgroup 2: the pulp chamber was gently irrigated with 10 mL 5.25% Sodium hypochlorite for 10 minutes, Subgroup 3: Pulp chamber was gently irrigated with 10 mL 17% Ethylene Diaminetetracetic acid for 10 minutes, Subgroup 4: pulp chamber was gently irrigated with 10 mL normal saline for 10 minutes. Each tooth was coated with two layers of nail varnish and then sticky wax except 1 to 2 mm around the perforation site. Each tooth was placed in glass vial containing 3 ml of buffered Methylene blue dye at (37°C, pH 7) and kept in an incubator for 72 hour at 100% humidity. After dye application, the teeth were washed in running water for 5 min. Each tooth was sectioned longitudinally in a buccolingual direction. Results: The results showed that group A has least mean of dye penetration and the difference was highly significant with group C and non-significant with group B.Saline and NaOCl increase the sealing of all groups while EDTA significantly increased the dye penetration of Biodentine and MTA respectively. Conclusions: Biodentine has the best sealing ability of the tested materials while amalgam showed the highest dye penetration of all tested materials. Saline and NaOCl increase the sealing ability of Biodentine and MTA where as EDTA decreased the sealing efficacy of MTA and Biodentine.
(3)
(3)
(11)
(4)
(12)
(11)
(192)
(129)
This study presents, for the first time, an innovative Jet Plasma-assisted technique for the green synthesis of TiO₂@Ag core–shell nanoparticles using chard leaf extract as a natural reducing and stabilizing agent. The Jet Plasma provides a highly energetic environment that accelerates nucleation and core–shell formation at low temperatures without toxic precursors. The synthesized nanoparticles exhibited uniform and stable structures, as confirmed by comprehensive characterization techniques including X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), ultraviolet–visible (UV–Vis) spectroscopy, transmission electron microscopy (TEM), and zeta potential analysis. XRD patterns confirmed the crystalline anatase
... Show More
(3)
(1)
Humanity is confronted with a growing array of environmental challenges that demand immediate attention and cannot be disregarded. One of the issues the world faces is air pollution, which presents a significant risk to both the environment and human well-being. The capitalist system has a great impact on the exacerbation of air pollution and environmental deterioration. This impact is reflected in Caryl Churchill’s post-apocalyptic play Not Not Not Not Not Enough Oxygen (1971). The play presents a futuristic scenario in which humanity faces grave consequences due to the polluting practices of capitalism and the unsustainable exploitation of natural resources. It depicts a future in which environmental degradation drives people
... Show More
(3)
(3)
In this research, the theme for employing a simple and sensitive method is to employ a new Schiff base ligand (N’-(4- (dimethyl amino) benzylidene)-3, 5-dinitrobenzohydrazide) to estimate Ni (II) to form orange complex (N-(4-(dimethyl amino) benzylidene)-3, 5-dinitrobenzohydrazide nickel (II) chloride) in acid medium (hydrochloric acid), it gives an absorption peak at the wavelength 485 nm. The preferred conditions were studied to form the complex and obtain the highest absorbance including concentration of Schiff base ligand, the best medium for complex formation, effects of addition sequence on complex formation, the effect of temperature on the absorbance of the complex formed, and the setting time of the formed complex. The obtained r
... Show More
This paper aims to study the chemical degradation of Brilliant Green in water via photo-Fenton (H2O2/Fe2+/UV) and Fenton (H2O2/Fe2+) reaction. Fe- B nano particles are applied as incrustation in the inner wall surface of reactor. The data form X- Ray diffraction (XRD) analysis that Fe- B nanocomposite catalyst consist mainly of SiO2 (quartz) and Fe2O3 (hematite) crystallites. B.G dye degradation is estimated to discover the catalytic action of Fe- B synthesized surface in the presence of UVC light and hydrogen peroxide. B.G dye solution with 10 ppm primary concentration is reduced by 99.9% under the later parameter 2ml H2O2, pH= 7, temperature =25°C within 10 min. It is clear that pH of the solution affects the photo- catalytic degradation
... Show More