This research is addressing the effect of different ferrocene concentration (0.00, 2.15x10-3, 4.30x10-3, 8.60x10-3, and 12.9x10-3) on the bulk free radical polymerization of methyl methacrylate monomer in benzene using benzoyl peroxide as initiator. The polymerization was conducted at 60º C under free oxygen atmosphere. The resulting polymers were characterized by FTIR. The results were compared with the presence and absence of ferrocene at 10% conversion. The %conversion was 3.04% with no ferrocene present in the polymerization medium and its increase to 9.06 with a first lowest ferrocene concentration added, i.e. 2.15 x10-3mol/l. This was positively reflected on the poly(methyl methacrylate) molecular weight measured by viscosity techniq

Let R be a Γ-ring and G be an R_Γ-module. A proper R_Γ-submodule S of G is said to be semiprime R_Γ-submodule if for any ideal I of a Γ-ring R and for any R_Γ-submodule A of G such that or which implies that . The purpose of this paper is to introduce interesting results of semiprime R_Γ-submodule of R_Γ-module which represents a generalization of semiprime submodules.

Let be a commutative ring with unity and let be a submodule of anon zero left R-module , is called semiprime if whenever , implies . In this paper we say that is nearly semiprime, if whenever , implies ( ),(in short ),where ( )is the Jacobson radical of . We give many results of this type of submodules.

Let R be any ring with identity, and let M be a unitary left R-module. A submodule K of M is called generalized coessential submodule of N in M, if Rad( ). A module M is called generalized hollow-lifting module, if every submodule N of M with is a hollow module, has a generalized coessential submodule of N in M that is a direct summand of M. In this paper, we study some properties of this type of modules.

Let R be a commutative ring with identity 1 and M be a unitary left R-module. A submodule N of an R-module M is said to be approximately pure submodule of an R-module, if for each ideal I of R. The main purpose of this paper is to study the properties of the following concepts: approximately pure essentialsubmodules, approximately pure closedsubmodules and relative approximately pure complement submodules. We prove that: when an R-module M is an approximately purely extending modules and N be Ap-puresubmodulein M, if M has the Ap-pure intersection property then N is Ap purely extending.

In this work, We introduce the concepts of an FP-Extending, FP-Continuous and FP-Quasi-Continuous which are stronger than P-Extending, P-Continuous and P-Quasi-Continuous. characterizations and properties of FP-Extending, FP-Continuous and FP-Quasi-Continuous are obtained . A module M is called FP-Extending ( FP-Continuous, FP-Quasi-Continuous) if every submodule is P-Extending (P-Continuous, P-Quasi-Continuous) .

   Let  be a right module over an arbitrary ring  with identity and  . In this work, the coclosed rickart modules as a generalization of  rickart  modules is given. We say  a module  over   coclosed rickart if for each ,   is a coclosed submodule of  . Basic results over this paper are introduced and connections between these modules and otherwise notions are investigated.

A new ligand complexes have been synthesis from reaction of metal ions of Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Hg(II), Pd(II) and Pt(II) with schiff base LH. 5-[(2-Hydroxy-naphthalen-1-ylmethylene)-amino]-2-phenyl-2,4-dihydro-pyrazol-3-one, this ligand was characterized by Fourier transform infrared (FTIR), UV-vis, 1H, 13CNMR, and mass spectra. All complexes were characterized by techniques micro analysis C.H.N, UV-vis and FTIR spectral studies, atomic absorption, chloride content, molar conductivity measurements and magnetic susceptibility. The ligand acts as bidentate, coordination through nitrogen atom from azomethin group and deprotonated phenolic oxygen atom. The spectroscopic and analytical measurements showed that

Metal complexes of Mn(II), Co(II), Ni(II), Cu(II), Cd(II), Zn(II), Hg(II), Pd(II), and Pt(II) with Schiff base ligand (LH) derived from 2,5-dichloroaniline and 2-hydroxy-5-metheylbenzalaldehyde were synthesized and characterized using a variety of spectrophotometric techniques The findings of the spectroscopic analysis indicated that (LH) behaved as a binary coordinating agent to the metal ion by the N and O atoms, and the geometry shape of the complexes was octahedral, with the exception of the Pd and Pt complexes, which had a square planar geometry. Using the DPPH radical scavenging method, we investigated the antimicrobial activity of the compound against Staphylococcus aureus and Escherichia coli, as well as the antifungal activity of t

An experimental of kinetics investigation of the solution free radical polymerization of isopropylacrylamide (IPAM) initiated with potassium persulfate (PPS) was conducted. The reactions were carried out at constant temperature of 60 °C in distilled water under unstirred and inert conditions. Using the well-known conversion vs. time technique, the effects of initiator and monomer concentration on the rate of polymerization (Rp) were investigated over a wide range. Under the conditions of our work, the orders 0.38 and 1.68 were found with respect to initiator and monomer, respectively. However, the rate of polymerization (Rp) is not straight forwardly corresponding monomer concentration. The value 46.11 kJ mol1 was determined as the o