A newly developed analytical method characterized by its speed and sensitivity for the determination of metformin-HCl via the formation of complex for metformin-HCl-OH--copper(II) ion from the gel bead system by continuous flow injection analysis. The method is based on the imbedded copper(II) ion in the gel bead structure can be used in the reaction for the formation of red –magneta colour complex(λmax. =530nm) formed by direct reaction of the drug with the released copper (II) ion from the gel bead in alkaline medium. Linear dynamic range for the absorbance versus metformin concentration was 0.001-1 mmol.L-1 while C.O.D was (r2% =95.33%) . The L.O.Q was 0.868mmol.L-1.L.O.D (S/N=3)=0.5μmol.L-1 from the step wise dilution for the minimum concentration of lowest concentration in the linear dynamic ranged of the calibration graph with R.S.D% lower than 0.5% for 0.01 mmol.L -1( n=8) concentration of metformin- HCl, throughput 30 sample.hr-1. The method was applied successfully for the determination of metformin in three pharmaceutical drugs. A comparison was made between the newly developed method of analysis with the classical method(Uv-spectrophotometry at wave length = 241nm) of analysis using the standard addition method via the use of paired t-test. It shows that there was no significant difference at α= 0.05 (95% confidence) between the two methods. Therefore the newly developed method(using the Metformin- OH- - Cu(II) entrapped inside gel bead) can be adopted as an alternative method for the analysis of metformin.
Piled raft is commonly used as foundation for high rise buildings. The design concept of piled raft foundation is to minimize the number of piles, and to utilize the entire bearing capacity. High axial stresses are therefore, concentrated at the region of connection between the piles and raft. Recently, an alternative technique is proposed to disconnect the piles from the raft in a so called unconnected piled raft (UCPR) foundation, in which a compacted soil layer (cushion) beneath the raft, is usually introduced. The piles of the new system are considered as reinforcement members for the subsoil rather than as structural members. In the current study, the behavior of unconnected piled rafts systems has been studie
... Show MoreGraphene-carbon nitride can be synthesized from thiourea in a single step at a temperature of four hours at a rate of 2.3 ℃/min. Graphene-carbon nitride was characterized by Fourier-transform infrared spectroscopy (FTIR), energy dispersive X-ray analysis (EDX), scanning electron microscopy, and spectrophotometry (UV-VIS). Graphene-carbon nitride was found to consist of triazine and heptazine structures, carbon, and nitrogen. The weight percentage of carbon and the atomic percentage of carbon are 40.08%, and the weight percentage of nitrogen and the atomic percentage of nitrogen are 40.08%. Therefore, the ratio and the dimensions of the graphene-carbon nitride were characterized by scanning electron microscopy, and it was found that the
... Show MoreIn this Paper, we proposed two new predictor corrector methods for solving Kepler's equation in hyperbolic case using quadrature formula which plays an important and significant rule in the evaluation of the integrals. The two procedures are developed that, in two or three iterations, solve the hyperbolic orbit equation in a very efficient manner, and to an accuracy that proves to be always better than 10-15. The solution is examined with and with grid size , using the first guesses hyperbolic eccentric anomaly is and , where is the eccentricity and is the hyperbolic mean anomaly.
Some nonlinear differential equations with fractional order are evaluated using a novel approach, the Sumudu and Adomian Decomposition Technique (STADM). To get the results of the given model, the Sumudu transformation and iterative technique are employed. The suggested method has an advantage over alternative strategies in that it does not require additional resources or calculations. This approach works well, is easy to use, and yields good results. Besides, the solution graphs are plotted using MATLAB software. Also, the true solution of the fractional Newell-Whitehead equation is shown together with the approximate solutions of STADM. The results showed our approach is a great, reliable, and easy method to deal with specific problems
... Show MoreWater quality sensors have recently received a lot of attention due to their impact on human health. Due to their distinct features, environmental sensors are based on carbon quantum dots (CQDs). In this study, CQDs were prepared using the electro-chemical method, where the structural and optical properties were studied. These quantum dots were used in the environmental sensor application after mixing them with three different materials: CQDs, Alq3 polymer and CQDs and Alq3 solutions using two different methods: drop casting and spin coating, and depositing them on silicon. The sensitivity of the water pollutants was studied for each case of the prepared samples after measuring the change in resistance of the samples at a temperature of
... Show MoreIn this paper, we have employed a computation of three technique to reduce the computational complexity and bit rate for compressed image. These techniques are bit plane coding based on two absolute values, vector quantization VQ technique using Cache codebook and Weber's low condition. The experimental results show that the proposed techniques achieve reduce the storage size of bit plane and low computational complexity.
In this paper, we are mainly concerned with estimating cascade reliability model (2+1) based on inverted exponential distribution and comparing among the estimation methods that are used . The maximum likelihood estimator and uniformly minimum variance unbiased estimators are used to get of the strengths and the stress ;k=1,2,3 respectively then, by using the unbiased estimators, we propose Preliminary test single stage shrinkage (PTSSS) estimator when a prior knowledge is available for the scale parameter as initial value due past experiences . The Mean Squared Error [MSE] for the proposed estimator is derived to compare among the methods. Numerical results about conduct of the considered
... Show MoreThe important device in the Wireless Sensor Network (WSN) is the Sink Node (SN). That is used to store, collect and analyze data from every sensor node in the network. Thus the main role of SN in WSN makes it a big target for traffic analysis attack. Therefore, securing the SN position is a substantial issue. This study presents Security for Mobile Sink Node location using Dynamic Routing Protocol called (SMSNDRP), in order to increase complexity for adversary trying to discover mobile SN location. In addition to that, it minimizes network energy consumption. The proposed protocol which is applied on WSN framework consists of 50 nodes with static and mobile SN. The results havw shown in each round a dynamic change in the route to reach mobi
... Show MoreThe main objective of e-learning platforms is to offer a high quality instructing, training and educational services. This purpose would never be achieved without taking the students' motivation into consideration. Examining the voice, we can decide the emotional states of the learners after we apply the famous theory of psychologist SDT (Self Determination Theory). This article will investigate certain difficulties and challenges which face e-learner: the problem of leaving their courses and the student's isolation.
Utilizing Gussian blending model (GMM) so as to tackle and to solve the problems of classification, we can determine the learning abnormal status for e-learner. Our framework is going to increase the students’ moti
The need for a flexible and cost effective biometric security system is the inspired of this paper. Face recognition is a good contactless biometric and it is suitable and applicable for Wireless Sensor Network (WSN). Image processing and image communication is a challenges task in WSN due to the heavy processing and communication that reduce the life time of the network. This paper proposed a face recognition algorithm on WSN depending on the principles of the unique algorithm that hold the capacity of the network to the sink node and compress the communication data to 89.5%. An efficient hybrid method is introduced based upon the advantage of Zak transform to offprint the farthest different features of the face and Eigen face method to
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