Iraq is one of the Arabian area countries, which considered from the drier areas
on the earth, though it has two main rivers that pass through(Tigris and Euphrates);
it suffers the same problem as them (drought), only the rivers' nearby regions make
use of their water for (domestic, agricultural, and industrial purposes(.
One of the usable solutions is to utilize the groundwater (especially in the desert
regions). Using the Remote Sensing and geographic information system is a rapid
and coast effective techniques, they provide information of large and inaccessible
area within short span for assessing, monitoring, and management of groundwater
resources. In this study, an adaptive algorithm based on Canny edge detector noise
reduction idea and directional filters scheme submitted for lineaments automatically
extraction from LandSat7 (Enhanced Thematic Mapper Plus) ETM+ band 7 data
considering the lineaments spatial and spectral characteristics, yet the algorithm
validation examined using ancillary data of the same interest (Iraq tectonic map and
90m SRTM DEM). The analysis process achieved using Arc GIS 9.3 to recognize
the potential groundwater renewal and/ or accumulative zones in the selected arid to
semi-arid area (AL-Dibdibba formation basin).
An Adaptive Automatic Algorithm for Extracting Geological Lineaments in AL-Dibdibba Formation Basin
lineaments
automatically extraction algorithm
groundwater flow
and renewal groundwater
Publication Date
Sat Sep 01 2018
Journal Name
Polyhedron
Novel dichloro (bis {2-[1-(4-methylphenyl)-1H-1, 2, 3-triazol-4-yl-κN3] pyridine-κN}) metal (II) coordination compounds of seven transition metals (Mn, Fe, Co, Ni, Cu, Zn and Cd)
The 1
3-dipolar cycloaddition “click” reaction between an azide and an alkyne to give a 1
2
3-triazole was reported by Huisgen in 1961 [1]. In 2002 the Copper(I)-catalyzed Azide-Alkyne Cycloaddition (CuAAC) to prepare a 1
2
3-triazole was reported [2]
[3]. The existence of relatively basic nitrogen atoms in the 1
2
3-triazole rings
and the possibility of introducing additional donor groups in the substituents (Fig. 1)
made the CuAAC “click” reaction an attractive method to prepare differently substituted 1
2
3-triazoles. These compounds have been used as ligands to coordinate to various metal ions that display a range of applications such as in electrochemical and photochemical studies
in supramolecular chemistry
magnetism
metal-ion sensing and catalysis [4]. The reasons for the success of the “click” reaction
is that it is easy to carry out and is widely applicable. It is not affected by a variety of functional groups
and can be carried out with a variety of Cu(I) catalysts and solvents
including aqueous conditions. The Cu(I) catalysts overcome the high activation energy barrier of the non-catalyzed Huisgen reaction by changing the mechanism of the reaction. A large variety of copper catalysts can be used for the CuAAC reaction
on condition that the maximum concentration of Cu(I) species is generated during the reaction. The pre-catalyst can be a Cu(II) salt (usually CuSO4) together with a reducing agent (often sodium ascorbate) or a Cu(I) compound in the presence of a base or amine ligand and a reducing agent to prevent oxidation to Cu(II). Some strong oxidising cupric salts or complexes such as Cu(OAc)2 also work. The solvent is very flexible from organic to aqueous
with the most commonly used combination water + an alcohol (t-BuOH
MeOH or EtOH). The key role of the solvent or solvent mixture is to solubilize the substrates and Cu(I) catalyst in order to ensure rapid reactions. Such aqueous conditions are very useful for biochemical conjugations
as well as for organic syntheses.
We recently reported on the synthesis of a series of differently substituted 1
2
3-triazole chromophores
the substituted 2-(1-phenyl-1H-1
2
3-triazol-4-yl)pyridine ligands [5]
see Fig. 2 middle
with substituents R = H (L1)
CH3 (L2)
OCH3 (L3)
COOH
F
Cl
CN
CF3
O(CH2)3CH3 and N(CH3)2. These versatile ligands were found to coordinate to various first row transition metals
such as manganese
cobalt and nickel [6]. Here we extend the series to include more first row transition metal(II) coordination compounds
iron
copper and zinc
as well as a second row transition metal(II) coordination compound
cadmium
containing the 2-(1-(4-methyl-phenyl)-1H-1
2
3-triazol-1-yl)pyridine chromophore (Fig. 2 right with R = CH3). This series of seven novel coordination compounds is the first series of pyridyl-triazole based transition metal coordination compounds where seven different transition metals are coordinated to the same 1
2
3-triazole chromophore
namely 2-(1-(4-methyl-phenyl)-1H-1
2
3-triazol-1-yl)pyridine.
Publication Date
Wed Jan 02 2019
Journal Name
Journal Of The College Of Languages (jcl)
A traditional model of translation: Critical analysis: Традиционные модели перевода: критический анализ
traditional translation models
theory of formal and dynamic equivalence
theory of regular correspondences
informative
situational-denotative
functional-pragmatic theory of communication levels.
традиционные модели перевода
теория формальной и динамической эквивалентности
теория закономерных соответствий
информативная
ситуативно-денотативная
функционально-прагматическая теория уровней коммуникации
The article critically analyzes traditional translation models. The most influential models of translation in the second half of the 20th century have been mentioned, among which the theory of formal and dynamic equivalence, the theory of regular correspondences, informative, situational-denotative, functional-pragmatic theory of communication levels have been considered. The selected models have been analyzed from the point of view of the universality of their use for different types and types of translation, as well as the ability to comprehend the deep links established between the original and the translation.
Аннотация
Publication Date
Sun Jun 01 2014
Journal Name
Baghdad Science Journal
Preparation and Identification of some new Pyrazolopyrin derivatives and their Polymerizations study
Synthesis
Fused Pyrazoles
1-(3
6-dimethyl-4-oxo-1
4-dihydro-5H-pyrazolo [4
3-C] pyridin-5-yl)-1H-pyrrole-2
5-Dione S1
1-[2-(3
6-dimethyl-4-oxo-1-phenyl-1
4-dihydro-5H-pyrazolo[4
3-C]pyridin-5-yl)ethyl]-1H-pyrrole-2
5-DioneS2 and 1-(3
6-dimethyl-4-oxo-1-phenyl-1
4-dihydro-5H-pyrazolo[4
3-C]pyridin-5-yl)-1H-pyrrole-2
5-Dione S3
reactivity ratios
copolymer composition
Mean Sequence lengths.
Preparation and Identification of some new Pyrazolopyrin derivatives and their Polymerizations study