In this paper, we propose a new and efficient ferroelectric nanostructure metal oxide lithium niobate [(Li1.075Nb0.625Ti0.45O3), (LNTO)] solid film as a saturable absorber (SA) for modulating passive Q-switched erbium-doped fiber laser (EDFL). The SA is fabricated as a nanocomposite solid film by the drop-casting process in which the LNTO is planted within polyvinylidene fluoride-trifluoroethylene [P(VDF-TrFE)] as host copolymer. The optical and physical characteristics of the solid film are experimentally established. The SA is incorporated within the cavity of EDFL to examine its capability for producing multi-wavelength laser. The experimental results proved that a multi-wavelength laser is produced, where stable four lines with central wavelengths at 1529.5, 1530.5, 1531.5, and 1532 nm are observed on the laser spectrum at 157 mW pumped power. Furthermore, at maximum available pumped power (157 mW), laser pulses are running with a rate of 178 kHz and pulse width of 2.64 μs. The output power of 3.7 mW is attained at pumped power of 157 mW. The result proved that the LNTO-SA could be a potential candidate for generating multi-wavelength passive Q-switched fiber laser pulses.
