This study estimated seven heavy metals (Fe, Cu, Zn, Pb, Ni, Cd, Cr) in water (dissolved and particulate phase), sediments and some aquatic organisms including two species from aquatic plants (Ceratophyllum demersum&Phragmites australis); one species of clam (Psedontopeses euphratics) and two species from fish (Oreochromis aureus& Leuciscus vorax)in four sites within Mashroo AL- Musayyib channel project/ branch of Euphrates river, Babylon , medial of Iraq . This aims to show the concentration of these elements, their fate and the mechanisms of their transmission through the food chain in this lotic aquatic system ; also in addition to examining some physicochemical properties of river water such as water temperature (WT),air temperature (AT),pH , electrical conductivity ( EC) , salinity ,total dissolved solid ( TDS), total solid suspended (TSS) , dissolved oxygen (DO) and biological oxygen demand ( BOD5) .The occurrence in heavy metals in water was found in the order in the Dissolved phase :- Zn> Fe > Cu> Ni>Pb> Cr > Cd, the zinc element recorded the highest rate in site two for spring season while the cadmium element recorded the lowest rate in site one for spring season. In the particulate phase:- Zn> Cu >Fe > Ni>Pb> Cr > Cd, the zinc element recorded the highest rate in site two for spring season while the cadmium element recorded the lowest rate in site four for spring season. The sediment order was Zn> Cu >Fe >Pb> Ni > Cd > Cr where the zinc element recorded the highest rate in site two for spring season where as the chromium element recorded the lowest rate in site two for spring. In aquatic plant the order was in C. demersum :Zn> Fe > Cu>Pb> Cr > Ni > Cd, the zinc element recorded the highest rate in site four for winter season while the cadmium element recorded the lowest rate in site one for autumn season. In P. australis: Zn> Fe > Cu>Pb> Cd > Ni > Cr , the zinc element recorded the highest rate in site two for spring season while the chromium element recorded the lowest rate in site two for spring season. In clam the order was: Zn> Fe > Cu> Ni >Pb> Cd > Cr where the zinc element recorded the highest rate in site two for spring season while the chromium recorded the lowest value in site 3 through winter 2021.In fish species (O. aureas) the order was Fe > Zn > Cu>Pb> Cr > Cd > Ni. The iron element recorded as the highest rate in site 2 in spring 2021 whilethe element that recorded the lowest rate was Ni in site 2for spring in L. vorax. The iron element recorded the highest rate in site one for summer season where as the Nickel was recorded a lower value in site four in spring2021.
Amebiasis, related to the pathogenic parasite Entamoeba histolytica, is a prominent cause of diarrhea globally. Amebiasis is primarily a disease of impoverished communities in developing nations, although it has recently arisen as a significant infection among returning tourists and immigrants. Severe cases are linked to a high case fatality rate. Although polymerase chain reaction (PCR)-based diagnosis is becoming more widely available, it is still underutilized. Treatment with nitroimidazoles is now suggested, however novel parasite medication research is a top priority. To avoid problems, amebiasis should be considered before corticosteroid therapy. Because there is no effective vaccination, sanitation and availability to clean w
... Show MoreAmebiasis, related to the pathogenic parasite Entamoeba histolytica, is a prominent cause of diarrhea globally. Amebiasis is primarily a disease of impoverished communities in developing nations, although it has recently arisen as a significant infection among returning tourists and immigrants. Severe cases are linked to a high case fatality rate. Although polymerase chain reaction (PCR)-based diagnosis is becoming more widely available, it is still underutilized. Treatment with nitroimidazoles is now suggested, however novel parasite medication research is a top priority. To avoid problems, amebiasis should be considered before corticosteroid therapy. Because there is no effective vaccination, sanitation and availability to clean w
... Show MoreThis paper shews how to estimate the parameter of generalized exponential Rayleigh (GER) distribution by three estimation methods. The first one is maximum likelihood estimator method the second one is moment employing estimation method (MEM), the third one is rank set sampling estimator method (RSSEM)The simulation technique is used for all these estimation methods to find the parameters for generalized exponential Rayleigh distribution. Finally using the mean squares error criterion to compare between these estimation methods to find which of these methods are best to the others
In this paper, a new analytical method is introduced to find the general solution of linear partial differential equations. In this method, each Laplace transform (LT) and Sumudu transform (ST) is used independently along with canonical coordinates. The strength of this method is that it is easy to implement and does not require initial conditions.
Chloroacetamide derivatives (2a-g) have been prepared through reaction of chloroacetyl chloride(1) (which prepared by the reaction of chloroacetic acid with thionyl chloride) with primary aromatic amines and sulfa compounds to afford compounds (2a-g) which then reacted with p-hydroxy benzaldehyde via Williamson reaction to obtaine the new compounds 2-(4-formyl phenoxy)-N-aryl acetamide (3a-g). Finally , compounds (3a-g) will be use as a good synthon to prepare the Schiff bases represented by compounds 2-(4-aryliminophenoxy)-N-arylacetamide (4a-g). through , reaction with some primary aromatic amine. All the prepared compounds were investigated by the available physical and spectroscopic methods.
In this work, new Schiff bases of quinazolinone derivatives (Q1-Q5) were synthesized from methyl anthranilate. The synthesis involved three steps. In the first step, methyl anthranilate was reacted with isothiocyanatobenzene, producing the thiourea derivative K1. The second step entailed reacting K1 with hydrazine hydrate, synthesizing 3-amino-2-(phenylamino) quinazolin-4(3H)-one (K2). The third step involved reaction of K2 with various aromatic aldehydes, yielding the Schiff bases derivatives Q1-Q5. The chemical structures of these compounds were identified by FT-IR,1H NMR and 13C NMR spectroscopy. The newly synthesized derivatives (Q1-Q5) were subjected to rigorous evaluation to assess their efficacy as corrosion inhibitors for ca
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