Preferred Language
Articles
/
bsj-2616
CMC Determination and Thermodynamic Micellisation Of NPE Surfactant In Aqueous And CH3OH – H2O Solvents
...Show More Authors

The critical micelle concentration (CMC) of nonylphenolethoxylate (NPE) surfactant has been determined by measuring the surface tension as a function of the molar concentration of the surfactant in aqueous and binary mixture of water + methanol solutions at a temperature range from 20?C to 35?C. The interfacial parameters ?max, Amin, ?cmc and ?G?ads were calculated. The results indicate that the CMC increases as the temperature increases and that the addition of methanol the CMC decreases. The thermodynamic parameters such as standard Gibbs free energy (?G?), enthalpy (?H?), and entropy (?S?) of micellization were estimated using the change of CMC with temperature. The enthalpy – entropy compensation behavior of the surfactant was evaluated and a good linearity in the compensation plot has been observed.

Crossref
View Publication Preview PDF
Quick Preview PDF
Publication Date
Thu Mar 30 2017
Journal Name
Iraqi Journal Of Pharmaceutical Sciences ( P-issn 1683 - 3597 E-issn 2521 - 3512)
Synthesis of New Opioid Analgesic Peptide Analogues to Enkephalin (Leucine- and Methionine-Enkephalin)
...Show More Authors

A small number of researches were done in the design and synthesis of enkephalin analogues that are able to resist degradation effect of proteolytic enzymes with good bioavailability and half-lives.Through studying structure activity relationships we tried to incorporate phthalyl group, tryptophan and lysine amino acids in different positions in the basic backbone structure of the naturally occurring opioid Leu5- and Met5- enkephalin, in the hope that such insertion of these amino acids could induce interesting addition in the biological activity of these analogues with enhancement of their bioavailability, in addition to decrease side effects as addiction liability.

These synthesized peptides are:

    ... Show More
    View Publication Preview PDF
    Crossref
    Publication Date
    Tue Dec 01 2020
    Journal Name
    Iraqi Journal Of Physics
    Enhancement of thermal stability and wettability for epoxy/Cu coated carbon fiber composites
    ...Show More Authors

        This research study the effect of surface modification and copper (Cu) plating carbon fiber (CF) surface on the thermal stability and wettability of carbon fiber (CF)/epoxy (EP) composites. The TGA result indicates that the thermal-stability of carbon fiber may be enhanced after Cu coating CF. TGA curve showed that the treatment temperature was enhanced thermal stability of Ep/CF, this is due to the oxidation during heating. The Cu plating increased the thermal conductivity, this increase might be due to reduce in contact resistance at the interface due to chemical modification and copper plating and tunneling resistance.

       The increase of surface polarity after coating cause decreas

    ... Show More
    View Publication Preview PDF
    Crossref (7)
    Crossref
    Publication Date
    Mon Mar 01 2021
    Journal Name
    Iraqi Journal Of Physics
    Antibacterial and morphological properties of polypyrrole/silver nanocomposites synthesized by chemical oxidative polymerization
    ...Show More Authors

    Polypyrrole/silver (PPy/Ag) nanocomposites was synthesized via a chemical oxidative method. The AFM analysis is performed to study the surface roughness, morphology and size distribution of the PPy particles and PPy-ag nanocomposites. The results indicated that as the concentration of Ag in the nanocomposite increases, the roughness also increases. The size of nanoparticles was also evaluated and found in the range of 15 nm to 125 nm. The PPy/Ag nanocomposites exhibited an effectiveness against Gram-negative Escherichia coli showing an inhibition zone of 4mm and displayed poor efficacy against Gram-positive Staphylococcus aureus. Based on given adequate antibacterial characteristics of PPy/Ag nanocomposites, it can be identified as a pro

    ... Show More
    View Publication Preview PDF
    Crossref (3)
    Crossref
    Publication Date
    Thu Oct 01 2009
    Journal Name
    Iraqi Journal Of Physics
    Preparation Cadmium Telluride Compound and Study Structural Properties of thermal evaporation thin films
    ...Show More Authors

    Polycrystalline ingots of cadmium telluride have been synthesized using the direct
    reaction technique, by fusing initial component consisting from pure elements in
    stoichiometric ratio inside quartz ampoule is evacuated 10-6 torr cadmium telluride has
    been grown under temperature at (1070) oC for (16) hr. was used in this study, the phases
    observed in growing CdTe compound depend on the temperature used during the growth
    process. Crystallography studies to CdTe compound was determined by X-ray diffraction
    technique, which it has zinc blend structure and cubic unit cell, which lattice constants is
    a=6.478
    oA

    View Publication Preview PDF
    Publication Date
    Tue Sep 01 2020
    Journal Name
    Iraqi Journal Of Physics
    Biosynthesis of silver nanoparticles using Thyme Vulgaris leaves extract and its Antibacterial activity
    ...Show More Authors

    In the current research, an eco-biosynthesis method for synthesizing silver nanoparticles (AgNPs) is reported using thymus vulgaris leaves (T. vulgaris) extracts. The optical and structural properties of the nanoparticles is determined using UV-visible, x-ray diffraction (XRD) and field emission scanning electron microscope (FESEM). In addition, the synthesis factors such as the temperature, the molar ratio of silver nitride and thymus vulgaris leaves extract have been investigated. The XRD pattern presented higher intensity for the five characteristic peaks of silver. FESEM images for same samples indicated that the particle size was distributed between 24-56 nm. In addition, it’s observed the formation of some aggregated Ag particles

    ... Show More
    View Publication Preview PDF
    Crossref (5)
    Crossref
    Publication Date
    Mon Dec 30 2013
    Journal Name
    Iraqi Journal Of Chemical And Petroleum Engineering
    Kinetic Study and Simulation of Oleic Acid Esterification over Prepared NaY Zeolite Catalyst
    ...Show More Authors

    Esterification considers the most important reaction in biodiesel production. In this study, oleic acid was used as a suggested feedstock in order to study and simulate production of biodiesel. The batch esterification reaction of oleic acid was carried out at various operating conditions; temperature from 40 to 70 °C, ethanol to oleic acid molar ratio from 3/1 and 6/1 and a reaction time up to 180 min.
    The catalyst used was prepared NaY zeolite, which is added to the reaction mixture as 2, 5 and 10 wt.% of oleic acid.
    The results show that the optimum conditions, gives 0.81 conversion of oleic acid, were 6/1 molar ratio of ethanol/oleic acid, 5 wt.% NaY relative to initial oleic acid, 70°C and 60 minutes. The activation energy o

    ... Show More
    View Publication Preview PDF
    Publication Date
    Mon Feb 27 2023
    Journal Name
    Drug Development & Registration
    Cytotoxic Effect of 6-Ethyl-Chenodeoxycholic Acid and Cabazitaxel on PC-3 Cells
    ...Show More Authors

    Introduction. Chemotherapy with Cabazitaxel (CBZ) is a typical first-line treatment option for naïive castration-resistant prostate cancer resistant to docetaxel. On the other hand, Cabazitaxel's therapeutic success is constrained by chemoresistance and side effects.

    Aim. To assess whether 6 alpha-ethylchenodeoxycholic acid (6-ECDCA), a selective agonist for bile acid receptors will enhance the efficacy of CBZ in androgen-independent prostate cancer cells.

    Materials and methods. The 3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) viability assay was used to assess the cytotoxicity of 6-ECDCA and CBZ medicines or t

    ... Show More
    View Publication
    Scopus (4)
    Crossref (1)
    Scopus Crossref
    Publication Date
    Sun Jan 01 2023
    Journal Name
    Journal Of The Mechanical Behavior Of Materials
    Simulation and assessment of water supply network for specified districts at Najaf Governorate
    ...Show More Authors
    Abstract<p>This study aims to simulate and assess the hydraulic characteristics and residual chlorine in the water supply network of a selected area in Al-Najaf City using WaterGEMS software. Field and laboratory work were conducted to measure the pressure heads and velocities, and water was sampled from different sites in the network and then tested to estimate chlorine residual. Records and field measurements were utilized to validate WaterGEMS software. Good agreement was obtained between the observed and predicted values of pressure with RMSE range between 0.09–0.17 and 0.08–0.09 for chlorine residual. The results of the analysis of water distribution systems (WDS) during maximum demand </p> ... Show More
    View Publication
    Scopus (4)
    Crossref (2)
    Scopus Clarivate Crossref
    Publication Date
    Thu Aug 31 2023
    Journal Name
    Iraqi Geological Journal
    The Effect of Nickel, Vanadium, Asphaltene, NSO and Sulfur on Crude Oil Quality
    ...Show More Authors

    The Mishrif reservoir (Cenomanian - Turonian) in the Z, H, B and N oilfields in southern Iraq was investigated to clarify how nickel, vanadium, asphaltene, NSO and sulfur content affect the crude oil quality. The GC-Mass and ICP-MS analyses were used to provide fruitful hydrocarbon results. Classification of crude oil based on API gravity broadly indicates the oil's density and general properties. Typically, lighter crude oils are easier to refine, yield higher percentages of valuable products such as gasoline and diesel, and have a higher market value. Heavier crude oils require more processing and may yield more residual products, such as heavy fuel oil and asphalt. The Mishrif crude oil was classified as a medium sour crude oil c

    ... Show More
    View Publication
    Scopus (7)
    Scopus Crossref
    Publication Date
    Wed Mar 25 2015
    Journal Name
    Comptes Rendus Chimie
    A novel method for the synthesis of biodiesel from soybean oil and urea
    ...Show More Authors

    The increasing demand for energy has encouraged the development of renewable resources and environmentally benign fuel such as biodiesel. In this study, ethyl fatty esters (EFEs), a major component of biodiesel fuel, were synthesized from soybean oil using sodium ethoxide as a catalyst. By-products were glycerol and difatty acyl urea (DFAU), which has biological characteristics, as antibiotics and antifungal medications. Both EFEs and DFAU have been characterized using Fourier transform infrared (FTIR) spectroscopy, and 1H nuclear magnetic resonance (NMR) technique. The optimum conditions were studied as a function of reaction time, reactant molar ratios, catalyst percentage and the effect of organic solvents. The conversion ratio of soybea

    ... Show More
    Preview PDF
    Scopus (11)
    Scopus