This research aims to investigate the effect of four types of nanomaterial on the Marshall properties and durability of warm mix asphalt (WMA). These types are; nano silica(NS), nano carbonate calcium (NCC), nano clay(NC), and nanoplatelets (NP). For each type of Nanomaterial, three contents are tried as following; NS(1%, 3%, and 5%), NCC(2%, 4%, and 6%), NC(3%, 5%, and 7%), and NP (2%, 4%, and 6%) by weight of asphalt cement. Following Marhsall mix design method, the optimum asphalt cement content is determined, thereafter the optimum dosage for each nanomaterial is obtained based on the highest Marshall stability value. The durability of the control mix (no nanomaterial) and modified mixtures have been compared based on moisture damage, resilient modulus, and permanent deformation. These properties are evaluated using indirect tensile strength(ITS) and uniaxial repeated load test. The findings of this research emphasize the potential of nanomaterials to significantly improve the Marshall properties and the durability of WMA. Also, the findings showed that the use of nanomaterials in the construction of asphalt concrete surface course extended the service life of pavement structures. Compared to CM, the modification of asphalt concrete by one of the nanomaterials, NC, NS, NCC, and NP, improved the design life by 59.6, 43.1, 24.4, and 12.2%, respectively. However, the improvement rate for each property depends on the nanomaterial dosage as well type. Therefore, this work provides a basis for producing more durable and sustainable paving mixtures using nanomaterials to offer better resistance to distress.
Two simple methods for the determination of eugenol were developed. The first depends on the oxidative coupling of eugenol with p-amino-N,N-dimethylaniline (PADA) in the presence of K3[Fe(CN)6]. A linear regression calibration plot for eugenol was constructed at 600 nm, within a concentration range of 0.25-2.50 μg.mL–1 and a correlation coefficient (r) value of 0.9988. The limits of detection (LOD) and quantitation (LOQ) were 0.086 and 0.284 μg.mL–1, respectively. The second method is based on the dispersive liquid-liquid microextraction of the derivatized oxidative coupling product of eugenol with PADA. Under the optimized extraction procedure, the extracted colored product was determined spectrophotometrically at 618 nm. A l
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