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Synthesis and characterization of (E)-4-(((4-(5-mercapto-1, 3, 4-oxadiazol-2-yl) phenyl) amino) methyl)-2-methoxyphenol as a novel corrosion inhibitor for mild-steel in acidic medium

Metal corrosion is a destructive process for many industrial operations, including oil well acidizing and acid pickling. Therefore, numerous efforts made by many researchers to control the steel corrosion. In the present work, A (E)-4-(((4-(5-mercapto-1,3,4-oxadiazol-2-yl) phenyl) amino) methyl)-2-methoxyphenol (MOPM) has been synthesized and characterized as a new corrosion inhibitor for mild steel in 0.1 M hydrochloric acid. FTIR and 1 HNMR were used in the diagnosis of MOPM, while electrochemical polarization technique was employed to test the performance of inhibitor at various temperatures and inhibitor concentrations. Electrochemical studies showed that MOPM acts as a mixed-type inhibitor with a maximum inhibition efficiency of 93.2% at 30 ◦C and 0.5 M MOPM. Furthermore, the presence of MOPM increased the polarization resistance and depressed the corrosive action. The inhibitory action of MOPM over mild-steel surface was according to Langmuir adsorption isotherm. The calculated free energy of adsorption was − 20.663 kJ.mol− 1 that suggested the spontaneous physical adsorption mode. Value of activation energy was higher in the presence of MOPM, which indicated the formation of protective layer on the metal surface. Quantum chemical calculations that carried out to the chemical structure of MOPM provides a reasonable support to the experimental results

Publication Date
Fri Sep 01 2023
Journal Name
Journal Of Engineering
A Review of Interface Bonding Testing Techniques

Interface bonding between asphalt layers has been a topic of international investigation over the last thirty years. In this condition, a number of researchers have made their own techniques and used them to examine the characteristics of pavement interfaces. It is obvious that test findings won't always be comparable to the lack of a globally standard methodology for interface bonding. Also, several kinds of research have shown that factors like temperature, loading conditions, materials, and others have an impact on surface qualities. This study aims to solve this problem by thoroughly investigating interface bond testing that might serve as a basis for a uniform strategy. First, a general explanation of how

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Publication Date
Tue Jun 16 2020
Journal Name
Journal Of The Faculty Of Medicine Baghdad
Illiterate Mother is a determinant of aggression

Most young children provoke negative reactions from parentral interference. These reactions worsen child's behavior. Starting a harmful pattern leading to emergence of an aggressive behavior. A cross sectional study was carried out in Al-Sadr city, Baghdad.  The target population was represented by all students attending governmental secondary schools, who are resident in Al-Sadr city aged between 13 and 21 year. The data collected by self-reported questionnaire (Aggression—Problem Behavior Frequency Scale). A total of 720 students contributed in this study. Out of the total, there were 257 (35.7%) students raised by illiterate mothers. Out of those, there were 241 (93.8%) students reported aggressive behavior.  

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Publication Date
Sun Jun 02 2019
Journal Name
Baghdad Science Journal
Properties of a Complete Fuzzy Normed Algebra

          The aim of this paper is to translate the basic properties of the classical complete normed algebra to the complete fuzzy normed algebra at this end a proof of multiplication fuzzy continuous is given. Also a proof of every fuzzy normed algebra  without identity can be embedded into fuzzy normed algebra  with identity  and  is an ideal in  is given. Moreover the proof of the resolvent set of a non zero element in complete fuzzy normed space is equal to the set of complex numbers is given. Finally basic properties of the resolvent space of a complete fuzzy normed algebra is given.

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Publication Date
Fri Sep 02 2022
Journal Name
Journal Of Legal Sciences
Elements of a standard criminalizing domestic violence

          Domestic vilonce comprises a unique privacy regarding indictment and eliminating such a behviour requires a precise standard for the sake of punishing those involved and also requires to be controlled in order not to be mishandled by others. This is imprtant for this behviour  to be included by the lawful model that provides a punishment frame. This has drvied the researcher to start this study with this elements that formulate a criterion for indictment such a behviour. and in the same way the researcher has covered the family  limits that includes the history of the marriage relationship, ending with what has the lawgiver set    of limits and affinity degre

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Publication Date
Sun May 14 2017
Journal Name
Ibn Al-haitham Journal For Pure And Applied Sciences
A New Design of Fractal Optical Modulation

In this paper it was designed a new fractal optical modulation by using a new iteration of fractal function, the result was analyzed by MTF evaluation, and it compared with results of normal optical modulation.

The normal and fractal optical modulator is a circular disc which has a radius R=9cm, both of them consist of twenty sectors, ten sectors are opaque and the other ten sectors are transmitted for the light.

      The fractal optical modulator contains two patterns, the pattern two can be used to detect the target, and pattern one can be used to lock the target

The best similarity of MTF behavior for normal and fractal Reticle was evaluating the power transparent depends on the size o

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Publication Date
Sun Oct 01 2006
Journal Name
Journal Of The Faculty Of Medicine Baghdad
A trial Of Immunisation Against Cutaneous Leishmaniasis

Background: Cutaneous leishmaniasis is an endemic protozoal disease in Iraq. Recovery from the disease confers a solid and permanent immunity. Vaccination with a living inoculum of promastigotes isolated from culture reduce the incidence of disease.
Objective: To show the efficacy of different types of antigens for protection of Balb/c mice against cutaneous leishmaniasis.
Methods: Thirty Balb Ic mice were divided in to six groups, groups 1-4 were immunized with different types of antigens (heat killed, freezing-thawing, formalin fixed and ultrasonicated). Received June 2005 Group 5 was treated with freshly harvested viable promastigotes from liquid medium as positive Accepted Nov. 2005 control and group 6 was kept as negative con

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Publication Date
Sat Dec 24 2022
Journal Name
Journal Of Legal Sciences
Interception of Criminal Prescription : A Comparative Study

Criminal prescription is a legal idea that we find its applications in most laws, It means that a period of time has passed since the occurrence of the crime, which is called the prescription of the criminal case or the crime, or the lapse of a period of time since the issuance of a final judgment in the criminal case, and it is called the prescription of the penalty, the lapse of the prescribed period will result in the expiry of the criminal case in the first case, and the lapse of the penalty imposed in the second case. This system has been found since ancient times in the legislation of countries with their various legal and political systems because of its practical considerations, the most important of which is achieving legal stab

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Publication Date
Tue Jul 01 2014
Journal Name
Journal Of The Faculty Of Medicine Baghdad
Female Infertility: A Study of Risk Factors.

Background: Infertility is a relatively common condition. It can be attributed to factors in a female partner, a male partner, or in both partners. However, certain socio-demographic and life style factors have been linked to female infertility.

Objective: To determine the association between female infertility and selected risk factors.

J Fac Med Baghdad

2014; Vol.56, No. 2

Received June.2013

Accepted Oct.2013

 

Patients and Methods: This is a case

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Publication Date
Fri Sep 01 2023
Journal Name
Journal Of Surgical Case Reports
A rare variant of mirror hand deformity

Congenital hand and forearm anomalies pose a unique challenge in plastic and pediatric surgery. We present a case report of an 8- months-old girl with a congenital left sided hand and forearm anomaly, provisionally diagnosed as atypical left mirror hand anomaly. Classically there is absence of radius and duplication of ulna; however, our case had normal radius and ulna and a hand with seven digits arranged in two groups. We did a surgery which involved a ray amputation of the finger ulnar to the most radial digit, aiming to preserve an adequate first web space to reconstruct the thumb. The result of the surgical treatment in both functional and cosmetic aspects was, in authors’ opinion, good.

Publication Date
Mon May 11 2020
Journal Name
Journal Of Arts, Literature, Humanities And Social Sciences
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