In recent years, the search for economic and environmentally friendly alternatives has become a global necessity to achieve sustainability and preserve raw materials. From this concept, natural bitumen (NB) derived from sulphur springs is now one of the most promising alternative energy resources for many applications, especially in asphalt pavement construction. Its low price and abundance characterise NB since sulphur springs produce thousands of tonnes of NB annually and are used in very limited fields. Two main objectives were adopted for this work. The first objective is to examine the virgin NB properties from five sulphur springs and compare them with petroleum asphalt. The second objective is to enhance NB properties by applying heat treatment. The experimental results reveal that heat treatment is highly effective in improving the NB properties. This was confirmed by conducting many tests, such as asphalt, Marshall, SEM-EDX, and indirect tensile strength tests. Based on the experimental test outcomes, virgin NB properties do not conform to asphalt specification limits and are unsuitable for flexible roads. Also, MS-NB significantly affected the mechanical properties of the asphalt mixture, as Marshall's stability increased by 41.3% compared to the conventional mixture. In addition, SS-NB was more effective in moisture damage resistance due to increasing the tensile strength ratio by 5.72 % and provided a higher stiffness index than the conventional mixture by 40.36%. In conclusion, the treated NB can successfully be used as a binder material in hot asphalt mixtures. ABSTRAK: Beberapa tahun kebelakangan, pencarian alternatif baharu ekonomi dan mesra alam telah menjadi satu keperluan global bagi mencapai kemampanan dan memelihara bahan mentah. Melalui konsep ini, bitumen asli (NB) yang diperoleh daripada mata air sulfur kini merupakan satu sumber tenaga alternatif yang berguna bagi digunakan dalam pelbagai aplikasi, terutamanya dalam pembinaan turapan asfalt. NB dicirikan oleh harga yang rendah dan kelimpahannya kerana mata air sulfur menghasilkan beribu-ribu tan NB setiap tahun dan digunakan dalam bidang terhad. Dua objektif utama telah dipakai untuk kajian ini. Objektif pertama adalah memeriksa sifat NB dara daripada lima mata air sulfur dan membandingkannya dengan asfalt petroleum. Objektif kedua adalah meningkatkan sifat NB dengan menggunakan rawatan haba. Dapatan eksperimen mendedahkan bahawa rawatan haba sangat berkesan dalam meningkatkan sifat NB. Ini disahkan dengan menjalankan pelbagai ujian, seperti ujian asfalt, ujian Marshall, ujian SEM-EDX, dan ujian kekuatan tegangan tidak langsung. Berdasarkan dapatan eksperimen, sifat NB dara tidak mematuhi had spesifikasi asfalt dan tidak sesuai untuk jalan fleksibel. Selain itu, MS-NB mempunyai kesan ketara pada sifat mekanikal campuran asfalt kerana kestabilan Marshalls meningkat sebanyak 41.3% berbanding campuran konvensional. Tambahan, SS-NB lebih berkesan dalam rintangan kerosakan lembapan kerana meningkatkan nisbah kekuatan tegangan sebanyak 5.72 % dan memberikan indeks kekukuhan yang lebih tinggi daripada campuran konvensional sebanyak 40.36%. Kesimpulannya, NB yang dirawat boleh berjaya digunakan sebagai bahan pengikat dalam campuran asfalt panas.
The estimation of the parameters of linear regression is based on the usual Least Square method, as this method is based on the estimation of several basic assumptions. Therefore, the accuracy of estimating the parameters of the model depends on the validity of these hypotheses. The most successful technique was the robust estimation method which is minimizing maximum likelihood estimator (MM-estimator) that proved its efficiency in this purpose. However, the use of the model becomes unrealistic and one of these assumptions is the uniformity of the variance and the normal distribution of the error. These assumptions are not achievable in the case of studying a specific problem that may include complex data of more than one model. To
... Show MoreCurrent studies interested on the biosynthesis of zinc oxide nanoparticles (ZnO-NPs) using hot plants extracts of Allium sativum and characterization of them using: Atomic Force Microscopy (AFM), X-ray diffractions (XRD), Fourier Transform Infrared Spectroscopy (FT- IR), UV–visible spectral and Hot stage. The results found that all NPs are had nano-size. ZnO NPs was produced by four procedures using hot extract of Allium sativum. The average diameters were: 101.59 nm, 110.33 nm, 75.69 nm, 88.67 nm for first, second, third and fourth procedures respectively compared with 47.57 nm for standard NPs. The Roughness averages (Ra) were: 10.8 nm, 6.83 nm, 13.8 nm, 0.541 nm for first, second, third and fourth respectively. The Root mean square (Sq
... Show MoreThe mechanical properties and microstructure of hot-rolled steel are critical in determining its performance in industrial applications, particularly when exposed to elevated temperatures. This study examines the effects of varying temperatures and soaking times on these properties through a series of controlled experiments. The primary objective was to optimize the key response parameters, including tensile strength, yield strength, and elongation, by analyzing the influence of temperature and time. A full factorial design approach was used, applying the desirability function theory to explore all possible combinations and identify optimal processing conditions. The experimental results showed that the soaking time played a critica
... Show MoreIn this paper to isolate and study the properties of the cyclooxygenase-2 (EC: 1.14.99.1) enzyme in the blood of a patient suffering from rheumatoid arthritis and study the effect of natural products of the Soapwort on the activity of purified enzyme. The study involves taking 30 ml of blood from an adult woman 40 years old, who suffers from rheumatoid arthritis disease for 13 years. Serum is separated and subjected to a series of purification processes including: precipitation by ammonium sulfate, filtration by centrifugation radiator, dialysis in presence of ammonium bicarbonate, separation using the technology of ion exchange, lipholization and then estimating approximate molecular weight of the enzyme using gel filtration techni
... Show MoreThe removal of COD from wastewater generated by petroleum refinery has been investigated by adopting electrocoagulation (EC) combined with adsorption using activated carbon (AC) derived from avocado seeds. The process variables influencing COD removal were studied: current density (2–10 mA/cm2), pH (4–9), and AC dosage (0.2–1 g/L). Response surface methodology (RSM) based on Box–Behnken design (BBD) was used to construct a mathematical model of the EC/AC process. Results showed that current density has the major effect on the COD removal with a percent of contribution 32.78% followed by pH while AC dosage has not a remarkable effect due to the good characteristics of AC derived from avocado seeds. Increasing current density gives be
... Show MoreQuick and accurate quaternary mixture resolution of furosemide (FURO), carbamazepine (CARB), diazepam (DIAZ) and carvedilol (CARV) by using derivative spectrophotometric method was performed. FURO and CARV were determined by means of first (D1), second (D2), third (D3) and fourth (D4) derivative spectrophotometric methods, CARB was determined by using D1, D2, D3 derivatives, while D1 and D2 were used for the determination of DIAZ. The recommended methods were verified using laboratory prepared mixtures and then successfully applied for the pharmaceutical formulations analysis of the cited drugs. The results obtained revealed the efficiency of the proposed methods as quantitative tool of analysis of the quaternary mixture with no requirement
... Show MoreThe physicochemical behaviour of dodecyltrimethylammonium bromide (DTAB) in water and ethanol-water mixture in the presence and absence of ZnSO4 were studied by measuring the conductivity at 298.15 K. The pre-micellar (S1) and post-micellar slopes (S2) were obtained and calculated the degree of dissociation (α) and the critical micelle concentration (cmc). With an increase in ethanol content, the cmc and α of DTAB increased whereas, in the presence of ZnSO4, the cmc and α decreased. By using cmc and α, thermodynamic properties as the standard free energy of micellization ( ) were evaluated. With an increase in ethanol content, the negative values of are decreased indicating less spont
... Show MoreThe present investigation aims to study the effect of heat treatment by quenching in different quenching media (salt water, water and oil) following by tempering on wear resistance of EN25 steel. EN25 steel is an alloy of medium carbon low alloy steel which is used for many applications requiring high tensile strength and wear resistance such as connecting rods, adapters and in power sectors extensively. The specimens are machined to 20 mm in length and 10 mm in diameter. This study is done by two stages: The first stage is done by austenitizing EN25 steel to 850 for 1 hr by quenching the specimens in three different quenching media and then tempered at 300 in air. While the second stage is performed by wear
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