ABSTRACT. The reaction between benzil and hexamethylenediamine formed a new ligand [L], [(1Z,3Z)-2,3-diphenyl-5,6,7,8,9,10-hexahydro-1,4-diazecine], of the type [N2], was synthesized by the condensation reaction through Schiff base reaction between benzil and hexamethylenediamine. The new Schiff base ligand reacts with Mnп, Niп and Coп metal ions to give the complexes with the general formula: [M(L)Cl2]. The elemental investigations have been used to analyze the ligand and its complexes by CHN, FT-IR, UV-Vis, TLC, mass spectrum, melting point with the study of biological activity to the formed compounds. From the data obtained, the proposed molecular structure adopts square planar structure about the metal ions. The study reveals the formation of a new ligand type [N2] and it's metal ion complexes with square planar structures metal:ligand ratio of 1:1, which can be employed in a variety of fields such as medicine and industry. KEY WORDS: Benzil, Hexamethylenediamine, Metal complexes, Square planar structure Bull. Chem. Soc. Ethiop. 2022, 36(4), 791-799. DOI: https://dx.doi.org/10.4314/bcse.v36i4.6
Background: Implant stability is a mandatory factor for dental implant (DI) osseointegration and long-term success. The aim of this study was to evaluate the effect of implant length, diameter, and recipient jaw on the pre- and post-functional loading stability. Materials and methods: This study included 17 healthy patients with an age range of 24-61 years. Twenty-two DI were inserted into healed extraction sockets to replace missing tooth/ teeth in premolar and molar regions in upper and lower jaws. Implant stability was measured for each implant and was recorded as implant stability quotient (ISQ) immediately (ISQ0), and at 8 (ISQ8) and 12 (ISQ12) weeks postoperatively, as well as post-functional loading (ISQPFL). The pattern of implant
... Show MoreThe city is often discussed in barren, eviscerated terms and in technical jargon by urban professionals as if it were a lifeless, detached being. In fact, it is a sensory, emotional, lived experience. How often do strategic urban plans start with the words ‘beauty’, ‘love’, ‘happiness’ or ‘excitement’, as opposed to ‘bypass’, ‘spatial outcome’ or ‘planning framework, So the research problem was formed by the weakness of the sensory perception of cities and the weakness of the sense of different spaces, which in turn leads to weakness of belonging, identity and clarity, Therefor we focus here on the sensory perception. The hypothesis Recognize Senses as helpful tool in increasing people's understanding of differe
... Show MoreThis is a search for Al-Rwandiyah and its heretical deviant sects, and its destructive goals that targeted the Arab nation, and its true Islamic religion in order to exhale poisons of demolition and sabotage, leading to its racist, populist goals ( ) that the Magi aspire to to restore the so-called ancient Persian glories, and undermine the Abbasid caliphate.
Al-Biruni said: (And that a person will emerge who will restore the Magian state and seize all the land, and remove the king of the Arabs) (), and among the indications of Ibn Al-Nadim is that a populist man called Muhammad bin Al-Hussein who was turned into Zaidan () was (claiming... the transition of the Islamic state to a state Persia ..... and their religion, which is the rel
Most media studies on the development of the agenda have focused on the relationship between the content of the media and the audience of these media, and the extent of its impact on the agenda of the media, in addition to comparing it to the extent of interest in the agenda of those means. While in the construction of the agenda, we focus on the relationship between news sources and the media and the role of these sources in the process Building the agenda.These sources are institutions, parties, pressure groups, interest groups, the head of state and other media. The impact of these sources on the process of building the agenda are shown through the process of the selection of resources by the channel and communicators, and the technic
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