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1-[4-(2-Hydroxy-4, 6-dimethyl-phenylazo)-phenol]-ethanone (HL1) and 2-(4-methoxy-phenylazo)-3, 5-
dimethyl-phenol (HL2) were produced by combination the diazonium salts of amines with 3, 5-
dimethylphenol. The geometry of azo compounds was resolved on the basis of (C.H.N) analyses, 1H and
13CNMR, FT-IR and UV-Vis spectroscopic mechanisms. Complexes of La (III) and Rh (III) have been
performed and depicted. The formation of complexes has been identified by using elemental analysis, FTIR
and UV-Vis spectroscopic process as well, conductivity molar quantifications. Nature of complexes
produced have been studied obeyed mole ratio and continuous alteration ways, Beer's law followed
through a concentration scope (1×10-4 - 3×10-4 M). High molar
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