An investigation into the implications of partial substitution of selenium with lead on the thermal properties for S60Se40-XPbX Chalcogenide Compound

doi:10.1088/1742-6596/2857/1/012007

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Publication Date

Tue Oct 01 2024

Journal Name

Journal Of Physics: Conference Series

Volume

2857

Issue Number

1

DOI

10.1088/1742-6596/2857/1/012007

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An investigation into the implications of partial substitution of selenium with lead on the thermal properties for S60Se40-XPbX Chalcogenide Compound

Engineering controlled terms Electric arc furnaces

Glass manufacture

Lead alloys

Melting point

Selenium compounds Engineering uncontrolled terms 950° C

Chalcogenide compound

Melting point method

Partial substitution

Property

Quartz ampoule

Quartz tubes

Rapid cooling

Thermal

Weight ratios Engineering main heading Heat flux

Kareem A.Jasim

Mohamed Muthana

...Show More Authors

AbstractThis study includes the manufacture of four ternary alloys represented S60Se40-XPbX with weight ratios x = 0, 10, 20, and 30 by the melting point method. The components of each alloy were mixed separately, then placed in quartz ampoules and vacuumed out with a vacuum of roger that 10−4 Torr. The ampule was heated in two stages to avoid sudden dissipation and precipitation of selenium on the inner mass of the quartz tube. The ampoule was gradually heated and kept at 450°C for approximately 4 hours followed by 950°C for 10 hours.at a rate of 10 degrees Celsius, the temperature of the electric furnace was increased, and then the ampoule was subjected to rapid cooling with cold water to reach a state of solidity glass-like. The research aims to investigate the effect of adding lead to selenium on the properties of thermal conductivity and heat flux density. It has been noted that the partial replacement of selenium with lead affected these properties significantly.

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Publication Date

Wed May 01 2024

Journal Name

Journal Of Physics: Conference Series

A study of the Electrical and Dialectical proprieties of S60-Se40-X-PbXChalcogenide Compound

electrical conductivity

imaginary dielectric constant

insulating properties

partial replacement

real dielectric constant

solid-state reaction

Mohamed

Kareem

...Show More Authors

AbstractIn this study, the melting-cooling method was used to prepare the chalcogenide compound S60-Se40-X-PbX. Four samples were obtained by partial replacement of Selenium with Lead in the weight ratios x = 0, 10, 20, and 30, respectively. The materials were mixed separately, ground, placed in quartz ampoules, and heated to 500 degrees Celsius. After conducting several operations on the samples, their insulating properties were studied, represented by the real dielectric constant and the imaginary dielectric constant, and the electrical conductivity was measured as a function of the frequency. It was found that partial replacement plays an impo ... Show More

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(1)

Publication Date

Fri Feb 01 2019

Journal Name

Journal Of Physics: Conference Series

Manufacturing and studying the effect of partial substitution on the properties of the compound Bi2-x AgxSr1.9Ba0.1Ca2Cu3O10+δ superconductors.

Noor S.

Abdulsalam S.

Bilal A.

Shatha

Kareem A.

Saja Amer

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(4)

(3)

Publication Date

Tue May 01 2018

Journal Name

Journal Of Physics: Conference Series

The partial substitution of copper with nickel oxide on the Structural and electrical properties of HgBa2 Ca2 Cu3xNix O8+δ superconducting compound

Laheeb A

L A

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(31)

(15)

Publication Date

Sat May 01 2021

Journal Name

Journal Of Physics: Conference Series

The substitutions of Strontium by yttrium and their effects on Bi2Sr2-xYxCa2Cu3O10+δ superconducting compound

Laheeb A.

Kareem A.

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AbstractSuperconducting compound Bi2Sr2-xYxCa2Cu3O10+δ were Synthesized by method of solid state reaction, at 1033 K for 160 hours temperature of the sintering at normal atmospheric pressure where substitutions Yttrium oxide with Strontium. When Y2O3 concentration (0.0, 0.1, 0.2, 0.3, 0.4 and 0.5). All specimens of Bi2Sr2Ca2Cu3O10+δ superconducting compounds were examined. The resistivity of electrical was checked by the four point probe technique, It was found th ... Show More

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(6)

Publication Date

Mon Jul 01 2019

Journal Name

Journal Of Physics: Conference Series

Effect of Nickel Substitution On Structural and Electrical Properties of Hg0.5Pb0.5Ba2Ca2Cu3-yNiyO8+δ Superconductor Composite

Laheeb A.

Kareem A.

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Abstractsix specimens of the Hg0.5Pb0.5Ba2Ca2Cu3-y <italic>Niy </italic>O8+δ (y=0.2,0.4,0.6,0.8,1.0) superconducting compound were prepared by solid state reaction method, with sintering temperature equal to 1123K for 24 hours. The electrical resistivity was examined by the four probe technique, It was found that all the specimens have metallic behavior and increasing the critical temperature with increasing nickel concentration. The optimum critical temperature Tc was found equal ... Show More

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(3)

Publication Date

Tue May 01 2018

Journal Name

Journal Of Physics: Conference Series

Partial substitution of Zn Effects on the Structural and Electrical Properties of High Temperature Hg0.95Ag0.05Ba2Ca2Cu3O8+δ Superconductors

Noor S.

Sabah J.

Kareem A.

Shatha

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(9)

(6)

Publication Date

Tue Oct 01 2024

Journal Name

Journal Of Physics: Conference Series

An Effect of Al on the Properties of ZnIn2Se4 Thin Film

Husham Kamil

Bushra H.

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AbstractZinc-indium-selenide ZnIn2Se4 (ZIS) ternary chalcopyrite thin film on glass with a 500 nm thickness was fabricated by using the thermal evaporation system with a pressure of approximately 2.5×10−5 mbar and a deposition rate of 12 Å/s. The effect of aluminum (Al) doping with 0.02 and 0.04 ratios on the structural and optical properties of film was examined. The utilization of X-ray diffraction (XRD) was employed to showcase the influence of aluminum doping on structural properties. XRD shows that thin ZIS-pure, Al-doped films at RT are polycrystalline with tetragonal structure and preferred (112) orientation. Where the ... Show More

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(1)

Publication Date

Mon Sep 20 2021

Journal Name

Key Engineering Materials

Fabrication of Ge30Te 70-xSbx Glasses Alloys and Studying the Effect of Partial Substitution on D.C Electrical Energy Parameters

Riyadh Kamil

Sarab Saadi

Kassim Mahdi

Kareem Ali

Auday H.

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The non-linear components has been emphasized for its multiple applications in rewritable recording and data storage devices. Chalcogenide glasses materials are promising due to their high refractive index. In this paper, alloys for Ge₃₀Te_70-xSb_xglasses semiconductor (where x =0.0, 5, 10, 15 and 20) will be fabricated by melt quenching method. The effect of partial substitution on DC electric power parameters, and its knowledge of electrical conduction mechanisms, were investigated to determine the effect of Antimony on the density of extended states, local states, and in Fermi energy states. The electrical measurements revealed the existence of three conduction mechanis

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(36)

(30)

Publication Date

Mon Sep 20 2021

Journal Name

Key Engineering Materials

Effect of Partial Substitution of Sr by Ba on the Structural Properties of Tl0.8Ni0.2Sr2-xBrxCa2Cu3O9-δ System

Mohammed Abdul Nebi

Rihab Nassr

Shatha

Kareem Ali

Auday H.

...Show More Authors

In this manuscript, the effect of substituting strontium with barium on the structural properties of Tl_0.8Ni_0.2Sr_2-xBr_xCa₂Cu₃O_9-δcompound with x= 0, 0.2, 0.4, have been studied. Samples were prepared using solid state reaction technique, suitable oxides alternatives of Pb₂O₃, CaO, BaO and CuO with 99.99% purity as raw materials and then mixed. They were prepared in the form of discs with a diameter of 1.5 cm and a thickness of (0.2-0.3) cm under pressures 7 tons / cm², and the samples were sintered at a constant temperature o

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(4)

(1)

Publication Date

Sun Mar 01 2020

Journal Name

Iop Conference Series: Materials Science And Engineering

The Influence of x ratio and Annealing Temperatures on Structural and Optical Properties for (CuO)x(ZnO)1-x Composite Thin Films Prepared by PLD

E M

M F A

A N

...Show More Authors

AbstractThin films of (CuO)x(ZnO)1-x composite were prepared by pulsed laser deposition technique and x ratio of 0≤ x ≤ 0.8 on clean corning glass substrate at room temperatures (RT) and annealed at 373 and 473K. The X-ray diffraction (XRD) analysis indicated that all prepared films have polycrystalline nature and the phase change from ZnO hexagonal wurtzite to CuO monoclinic structure with increasing x ratio. The deposited films were optically characterized by UV-VIS spectroscopy. The optical measurements showed that (CuO)x(ZnO)1-x films have direct energy gap. The energy band gaps of prepared thin films ... Show More

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