O-Phenylenediamine
oxalic acid dehydrate
8-hydroxyquinoline
mixed ligand
complexes
spectral studies
thermal analysis and bioactivities.
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Metal (III) and (II) coordination compounds of o- phenylenediamine, oxalic acid
dihydrate and 8-hydroxyquinoline were synthesized for mixed ligand complexes and
characterized using FT-IR, UV-Vis and mass spectra, atomic absorption, elemental analysis,
electric conductance and magnetic susceptibility measurements. In addition, thermal behavior
(TGA) of the metal complexes (1-6) showed good agreement with the formula suggested from
the analytical data. The stoichiometric reaction between the metal (III) and (II) ions with three
various ligands in molar ratio at aqueous ethyl alchol for (1:1:1:1) (M: O-PDA: OA: 8-HQ)
[where M = Cr+3, Mn+2, Co+2, Ni+2. Cu+2 and Zn+2; O-PDA = O-Phenylenediamine; OA =
Oxalic acid and 8-HQ = 8-Hydroxyquinoline]. R
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