In this study, we fabricated nanofiltration membranes using the electrospinning technique, employing pure PAN and a mixed matrix of PAN/HPMC. The PAN nanofibrous membranes with a concentration of 13wt% were prepared and blended with different concentrations of HPMC in the solvent N, N-Dimethylformamide (DMF). We conducted a comprehensive analysis of these membranes' surface morphology, chemical composition, wettability, and porosity and compared the results. The findings indicated that the inclusion of HPMC in the PAN membranes led to a reduction in surface porosity and fiber size. The contact angle decreased, indicating increased surface hydrophilicity, which can enhance flux and reduce fouling tendencies. Subsequently, we evaluated the efficiency of all prepared nanofiber membranes in separating emulsified oil from water using a crossflow filtration system. It was observed that the 60:40wt% PAN/HPMC nanofiber membrane exhibited optimal performance in removing emulsion oil due to its favorable porosity and permeability, along with effective oil rejection.
Two different oxidative desulfurization strategies based on oxidation/adsorption or oxidation/extraction were evaluated for the desulfurization of AL-Ahdab (AHD) sour crude oil (3.9wt% sulfur content). In the oxidation process, a homogenous oxidizing agent comprising of hydrogen peroxide and formic acid was used. Activated carbons were used as sorbent/catalyst in the oxidation/adsorption process while acetonitrile was used as an extraction solvent in the oxidation/extraction process. For the oxidation/adsorption scheme, the experimental results indicated that the oxidation desulfurization efficiency was enhanced on using activated carbon as catalyst/sorbent. The effects of the operating conditions (contact time, temperat
... Show MoreThe Buzurgan oil field is one of the most important oil fields border in southern Iraq.
Adjacent to the Fauqi and Abu Ghirab oil fields common with Iran. The 3D seismic data showed the structural and stratigraphic of the Buzurgan oil field, where the results showed that the structure is an anticline fold with two structural domes separated by a saddle, the northern culmination is shallower and less deformation. Thirty-one faults were detected and most of them at the south part of the field which are small while the north faults are larger.
Empirical equation has been presented to predict the optimum hydrodynamic
pressure gradient with optimum mud flow rate (one equation) of five Iraqi oil wells
to obtain the optimum carrying capacity of the drilling fluid ( optimum transport
cuttings from the hole to the surface through the annulus).
This equation is a function of mud flow rate, mud density and penetration
rate without using any charts or graphs.
The correlation coefficient accuracy is more than 0.9999.
The efficiency of attapulgite liners as anti-seepage for crude oil is examined. Consideration is given to the potential use of raw attapulgite and mixture attapulgite with prairie hay and coconut husk as liners to prevent crude oil seepage. Attapulgite clay used in this study was brought from Injana formation /Western Desert of Iraq. Two types of Crude oil brought from Iraqi oil fields were used in experiments; heavy crude oil from East-Baghdad oil field and light crude oil from Nassiriya oil field. Initially the basic properties of attapulgite and crude oils were determined. The attapulgite clay was subjected to mineralogical, chemical and scanning electron microscope analyses. Raw Attapulgite 150µm, 75µm, and 53µm were tested
... Show MoreChanging oil-wet surfaces toward higher water wettability is of key importance in subsurface engineering applications. This includes petroleum recovery from fractured limestone reservoirs, which are typically mixed or oil-wet, resulting in poor productivity as conventional waterflooding techniques are inefficient. A wettability change toward more water-wet would significantly improve oil displacement efficiency, and thus productivity. Another area where such a wettability shift would be highly beneficial is carbon geo-sequestration, where compressed CO2 is pumped underground for storage. It has recently been identified that more water-wet formations can store more CO2. We thus examined how silica based nanofluids can induce such a wettabil
... Show MoreEfficient cuttings transport and hole cleaning are very important factors for obtaining an effective drilling operation. In an inclined and horizontal drilling, hole cleaning issue is a common and complex problem.
The scope of this research is to study the drilling parameters which affect hole cleaning in Iraqi directional wells through studying and analyzing some drilled wells ( vertical , directional (30 degree) , directional (60 degree) and horizontal ).An excel sheet is prepared to calculate carrying capacity index which represents an indicator for good hole cleaning in different sections. The study indicated through the field investigations, practical experiences and theoretical calculations tha
... Show MoreAn investigation was conducted for the improvement of viscosity index of a lubricating oil fraction (SAE – 30) obtained from vacuum distillation unit of lube oil plant of Daura Refinery, using solvent extraction process. In this study two type of extraction solvents were used to extract the undesirable materials which reduce the viscosity index of raw lubricating oil fraction, the first solvent was furfural which is un use today in the Iraqi refineries and the second was NMP (N-methyl, 2, pyrrolidone) which is used for the first time in this work to extract the lubricating oil fraction produced from Iraqi crude oils. The studied effecting variables of extraction are extraction temperature range from 70 to 110 oC for furfural and NMP ex
... Show MoreThe study of petroleum systems by using the PetroMoD 1D software is one of the most prominent ways to reduce risks in the exploration of oil and gas by ensuring the existence of hydrocarbons before drilling.
The petroleum system model was designed for Dima-1 well by inserting several parameters into the software, which included the stratigraphic succession of the formations penetrating the well, the depths of the upper parts of these formations, and the thickness of each formation. In addition, other related parameters were investigated, such as lithology, geological age, periods of sedimentation, periods of erosion or non-deposition, nature of units (source or reservoir rocks), total organic carbon (TOC)
... Show MoreGas Chromatography GC, Gas Chromatography–Mass spectrometry GC/MS techniques used for analysis of the crude oils that taken from (10) producing wells in Nasiriyah oil field including (NS-1, NS-3, NS-4, NS-5, NS-6, NS-7, NS-8, NS-9, NS-10, and NS-12) from Mishrif reservoir . This reservoir is one of the important reservoirs in Al-Nasiriyah oil field, and it will be the main subject in the current study in order to provide information of crude oil analysis in this area, also to provide information on its characterizations. Mishrif Formation is one of the principle carbonate reservoir in central and southern Iraq. It is part of the wasia group and widespread throughout the Arabian gulf, It is deposited during Cenomanian-Early Turonian cyc
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