Back ground: Knowledge about the causes of death in children is important to evaluate health system progress and provide what is needed for an efficient design of health care delivery system. Objective: To find out the main causes of death in children under 5years & evaluate the effects of different variables like: age, gender, body weight, residency, and months of year for the causes of death. Patient& Method: This is a retrospective study which was carried out in order to find out the main causes of death among admitted children younger than 5 year in Sulaymani Pediatrics Teaching Hospital for the period of 5 years from of January 1st 2001 to December 31st 2005 included. The total numbers of admitted cases was 137,739 out of which 1455 had died. We obtained the information from case files of the deceased patients. Results: The incidence of death among admitted patients was (1.06%), the rate was higher in male gender (59.3%), while in female it was (40.7 %), with a P-value of <0.05 which is significant statistically with male to female ratio 1.48:1. Deaths were mainly in neonates (61.8 % of all age groups in the study) with a p-value of <0.05. Death was mainly in those with body weights <2.5kg, which accounts for (42.1%). The main cause of death in neonate was prematurity (54.7%) while diarrhea and Acute Respiratory Infections (ARI) were main causes during infancy (57.4%, 15.9%) respectively. Seasonal variation of died cases showed that were two peaks of death, one in June and another in November with a p-value of <0.05. The percentage of death in the rural and urban area were (64.5%, 35.5 %) respectively, with a p-value of <0.05 which is also significant. Conclusion: This study has revealed that prematurity was the main cause of death among neonate while diarrhea and acute respiratory diseases were the main causes of death during infancy. Malignancy was the least common cause of death. Deaths were mainly in neonates. There was a significant association between deaths and gender, body weight, residency& the months of the year. Key words: mortality rate, death cause, children under five.
New Schiff base ligand (E)-6-(2-(4-(dimethylamino)benzylideneamino)-2-(4-hydroxyphenyl)acetamido)-3,3- dimethyl-7-oxo-4-thia-1- azabicyclo[3.2.0]heptane-2-carboxylic acid = (HL) was synthesized via condensation of Amoxicillin and 4(dimethylamino)benzaldehyde in methanol. Figure -1 Polydentate mixed ligand complexes were obtained from 1:1:2 molar ratio reactions with metal ions and HL, 2NA on reaction with MCl2 .nH2O salt yields complexes corresponding to the formulas [M(L)(NA)2Cl],where M=Fe(II),Co(II),Ni(II),Cu(II),and Zn(II), A=nicotinamide .
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Eight different Dichloro(bis{2-[1-(4-R-phenyl)-1H-1,2,3-triazol-4-yl-κN3]pyridine-κN})iron(II) compounds, 2–9, have been synthesised and characterised, where group R=CH3 (L2), OCH3 (L3), COOH (L4), F (L5), Cl (L6), CN (L7), H (L8) and CF3 (L9). The single crystal X-ray structure was determined for the L3 which was complemented with Density Functional Theory calculations for all complexes. The structure exhibits a distorted octahedral geometry, with the two triazole ligands coordinated to the iron centre positioned in the equatorial plane and the two chloro atoms in the axial positions. The values of the FeII/III redox couple, observed at ca. −0.3 V versus Fc/ Fc+ for complexes 2–9, varied over a very small potential range of 0.05 V.
... Show MoreThe purpose of the current work was to evaluate the effect of Radiation of Gamma on the superconducting characteristics of the compound PbBr2Ca1.9Sb0.1Cu3O8+δ utilizing a 137Cs source at doses of 10, 15, and 20MRad. Solid state reaction technology was used to prepare the samples. Before and after irradiation, X-ray diffraction (XRD) and superconductor properties were examined. Results indicated that the tetragonal structure of our chemical corresponds to the Pb-1223 phase with an increase in the ratio c/a as a result of gamma irradiation. (Tc (onset) ) and on set temperature Tc (offset)) were also dropping from 113 to the 85.6 K and 129.5 to 97 K, respectively, for a transition temperatu
New Schiff base [3-(3-acetylthioureido)pyrazine-2-carboxylic acid][L] has been prepared through 2 stages, the chloro acetyl chloride has been reacting with the ammonium thiocyanate in the initial phase for producing precursor [A], after that [A] has been reacting with the 3-amino pyrazine-2-carboxilic acid to provide a novel bidentate ligand [L], such ligand [L] has been reacting with certain metal ions in the Mn(II), VO(II), Ni(II), Co(II), Zn(II), Cu(II), Hg(II), and Cd(II) for providing series of new metal complexes regarding general molecular formula [M(L)2XY], in which; VO(II); X=SO4,Y=0, Co(II), Mn(II), Cu(II), Ni(II), Cd(II), Zn(II), and Hg(II); Y=Cl, X=Cl. Also, all the compounds were characterized through spectroscopic techniques [
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The preparation and spectral characterization of complexes for Co(II), Ni(II), Cu(II), Cd(II), Zn(II) and Hg(II) ions with new organic heterocyclic azo imidazole dye as ligand 2-[(2`-cyano phenyl) azo ]-4,5-diphenyl imidazole ) (2-CyBAI) were prepared by reacting a dizonium salt solution of 2-cyano aniline with 4,5-diphenyl imidazole in alkaline ethanolic solution .These complexes were characterized spectroscopically by infrared and electronic spectra along with elemental analysis‚ molar conductance and magnetic susceptibility measurements. The data show that the ligand behaves a bidantate and coordinates to the metal ion via nitrogen atom of azo and with imidazole N3 atom. Octahedral environment is suggested for all metal complex
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