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Schiff base ligand (H2CANPT) was prepared by two steps: first, by the condensation
of curcumin with 4-amino antipyrin produces4,4'-(((1E,3Z,5Z,6E)-1,7-bis(4-hydroxy-3-
methoxyphenyl)hepta-1,6-diene-3,5-diylidene)bis(azanylylidene))bis(1,5-dimethyl-2-phenyl-
1,2-dihydro-3H-pyrazol-3-one) (CANP). Second, by the condensation of (CANP) with
L-tyrosine produces2,2'-(((3Z,3'Z)-(((1E,3Z,5Z,6E)-1,7-bis(4-hydroxy-3-methoxyphenyl)hepta
1,6-diene-3,5-diylidene)bis(azanylylidene))bis(1,5-dimethyl-2-phenyl-1,2-dihydro-3-H-pyrazole-
4-yl-3-ylidene))bis(azanylylidene))bis(3-(4-hydroxyphenyl)propanoic acid) (H2CANPT).
The resulted Schiff comported as hexadentate coordinated with (N4O2) atoms, then it was
treated with some transition and non-transaction met
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