Viscosity
density
refractive index
sulfolane
excess properties and Mono
alcohol
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The refractive indices, nD densities 𝜌, and viscosities of binary
mixtures of sulfolane + n -butanol + sec- butanol + iso- butanol + tert –
butanol + n-propanol and iso- propanol were measured at 298.15K. Form
experimental data, excess molar volum VE
, excess molar refractivity ∆nD,
excess molar viscosity
E
and excess molar Gibbs free energy of activation
of viscous flow G
*E were calculated. From n-propanol – sulfolane and
iso- propanol sulfolane mixtures showed negative ∆nD, n-butanol –
sulfolane, sec-butanal – sulfolane, iso-butanol – sulfolane and tert- butanol
sulfolane , nD was positive over the whole mole fraction rang , while VE
,
E
and G
*E show a negative deviation. The
...
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