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(Cu1-x,Agx)2ZnSnSe4 alloys have been fabricated with different Ag content(x=0, 0.1, and
0.2) successfully from their elements. Thin films of these alloys have been deposited on
coring glass substrate at room temperature by thermal evaporation technique under
vacuum of 10-5Torr with thickness of 800nm and deposition rate of 0.53 nm/sec. Later,
films have been annealed in vacuum at (373, and 473)K, for one hour. The crystal
structure of fabricated alloys and as deposited thin films had been examined by XRD
analysis, which confirms the formation of tetragonal phase in [112] direction, and no
secondary phases are founded. The shifting of main polycrystalline peak (112) to lower
Bragg’s angle as compared to Cu2ZnSnSe4 angle refers to incorpora
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