Preferred Language
Articles
/
lxbemIoBVTCNdQwC0qBR
تحضير ودراسة طيفية وحرارية لمعقدات بعض العناصر الإنتقالية مع ليكانـــــد 4- (2- بريديل آزو)- ريزورسينول
...Show More Authors

لقد حضر في هذا البحث عدد من المعقدات الجديدة لبعض ايونات العناصر الانتقالية وهي كل من Fe(II) , Fe(III) , Co(II) , Ni(II) , Cu(II) و Zn(II) مع الكاشف العضوي -4 ( -2 بريديل آزو ) ريزورسينول المعروف ب (PAR) . حيث تم التحضير بعد تثبيت الظروف المثلى من دالة حامضية وتركيز مولاري بوساطة أطياف الاشعة فوق البنفسجية – المرئية لمحاليل مزج الايونات الفلزية مع محاليل الكاشف العضوي اعلاه ولمدى واسع من الدالة الحامضية والتركيز المولارية الخاضعة لقانون لامبرت – بير وقد تباينت ظروف التحضير بتابين الايونات الفلزية المدروسة . إذ تم تحضير ثلاثة معقدات لكل من آيوني النيكل (II) ومعقدين لآيون الكوبلت (II) ومعقدين لكل من الحديد (II) و (III) والخارصين (II) بأختلاف ظروف التحضير . كما تم التعرف على تراكيب هذه المعقدات عن طريق ايجاد النسبة المولية للفلز : الليكاند من خلال الدراسات الطيفية لمحاليل معقدات الفلزات المذكورة آنفا وذلك بأستخدام طريقة النسب المولية وقد تراوحت هذه النسب ما بين 1:1 أو 2:1 . وبعد تنقية المركبات الصلبة الناتجة درست بوساطة أطياف الاشعة فوق البنفسجية – المرئية حيث أظهرت أطياف محاليلها في الميثانول ازاحة حمراء لوحظت في منطقة الطيف المرئي لجميع المعقدات . كما درست بوساطة اطياف الاشعة تحت الحمراء إذ سجلت تغييرات واضحة لاطياف المعقدات نسبة الى طيف الليكاند الحر . ولوحظ ظهور حزم جديدة لم تكن موجودة في طيف الليكاند تدل على الاتباط الثنائي او الثلاثي السن لليكاند بالآيون الفلزي . إذ أنه من المتوقع ان تكون مواقع الارتباط لليكاند من خلال اوكسجين مجموعة الهيدروكسيل اورثو لحلقة الريزورسينول ( بعد ان تفقد بروتونها) ونيتروجين مجموعة الآزو القريبة من حلقة الريزوسينول ونيتروجين حلقة البريدين إذ تتكون حلقتان خماسيتان مستقرتان مما تعطيان استقرارا عاليا لهذه المعقدات . كما تم اجراء التحاليل الدقيقة لعناصر (N , H , C) لهذه المعقدات وتم تعيين النسب المئوية للأيونات الفلزية باستخدام مطيافية الامتصاص الذري اللهبي كما تم تعيين نسبة عنصر الكبريت وآيون الكلوريد بأستخدام طرق تحليلية مختلفة . وقد أظهرت نتائج هذه التحاليل جميعاً تقاربا للنسب المئوية المستحصلة مع النسب النظرية المحسوبة للصيغ التركيبية المقترحة لهذه المعقدات. أما دراسة التوصيلة الكهربائية لمحاليل المعقدات المحضرة في مذيبي الميثانول وثنائي ميثل فورم امايد فقد أظهرت ان المعقدات لا تمتلك صفات آيونية . كذلك فقد شملت الدراسة أيضا اجراء التحاليل الحرارية TGو DTG لليكاند الـ PAR وللمعقدات المحضرة جميعاً . وقد أثبتت هذه التحاليل وجود جزيئة ماء تبلور واحدة في جميع المعقدات ومن النسب المئوية للفقدان في الوزن التي سجلتها المنحنيات الحرارية ومقارنتها مع النسب المحسوبة نظريا فقد تم التوصل الى ان الخط العام للتحلل الحراري تضمن تكون جذور حرة للريزورسينول والبريدين مع تحرر غاز النيتروجين أثناء عملية التحلل . اما المواد الصلبة المتبقية من نواتج فهي أما العناصر او اكاسيد العناصر لكل معقد . واخيرا فقد دعمت النتائج أعلاه باجراء تحاليل طيف الكتلة الذي أثبت بما لايقبل الشك الصيغ الجزيئية المقترحة المحضرة . وتعتبر الدراستان الاخيرتان ( التحلل الحرارية وأطياف الكتلة ) الاولى من نوعها التي تجرى على ليكاند الـ PAR ومعقداتها الفلزية .

Publication Date
Thu Feb 07 2019
Journal Name
Iraqi Journal Of Laser
Synthesis Characterization and Optical Properties of Nanostructured Zinc Sulfide Thin Films Obtained by Spray Pyrolysis Deposition
...Show More Authors

In this work, nanostructure zinc sulfide (ZnS) thin films at temperature of substrate 450 oC and thickness (120) nm have been produced by chemical spray pyrolysis method. The X-Ray Diffraction (XRD) measurements of the film showed that they have a polycrystalline structure and possessed a hexagonal phase with strong crystalline orientation of (103). The grain size was measured using scanning electron microscope (SEM) which was approximately equal to 80 nm. The linear optical measurements showed that ZnS nanostructure has direct energy gap. Nonlinear optical properties experiments were performed using Q-switched 532 nm Nd:YAG laser Z-scan system. The nonlinear refractive index (n2) and nonlinear absorption coefficient (β) estimated for Z

... Show More
View Publication Preview PDF
Publication Date
Tue Dec 05 2023
Journal Name
Baghdad Science Journal
Synthesis, Characterization and Properties of Trimethylolpropane Triesters from Coconut (Cocos nucifera) Methyl Esters
...Show More Authors

In this study, the acid-alkaline transesterification of refined coconut seed oil (RCOSO) to fatty acid methyl ester was followed by the production of a trimethylolpropane-based thermosensitive biolubricant using potassium hydroxide, and its physicochemical characteristics were evaluated. The American Standard Test for Materials (ASTM) was employed to ascertain the biolubricant's pour point and index of viscosity, which were found to be -4 oC and 283.75, respectively. The opposite connection between lubricant viscosity and temperature was shown by the measured viscosities at varied transesterification to be transformed into biodiesel. Following this, a biolubricant was created by further transesterifiedtemperature. The ester gr

... Show More
View Publication Preview PDF
Scopus Crossref
Publication Date
Mon Dec 20 2021
Journal Name
Baghdad Science Journal
Isolation and identification of some bacterial isolates from soil contaminated with crude oil and Testing Their Effectiveness
...Show More Authors

Bacterial strains were isolated from oil-contaminated soil, in 2018, these isolates were identified, and with the aim of finding out the ability of these isolates to degrede the oil compounds, the color change of medium which added to it isolates was read by the method of Pacto Bushnell Hans. Then the change in the petroleum compounds was read by gas chromatography, for the most effective isolates.

The nine isolated bacterial showed different degrees of color change, and the isolates (Pseudomonas, Bacillus, Micrococcus) outperformed the color change amount (78, 78, 77) %, respectively, compared to the control, and the three isolates together showed the best color change of 90.7. % Compared to the control, and the

... Show More
View Publication Preview PDF
Scopus (3)
Scopus Clarivate Crossref
Publication Date
Tue Jul 01 2008
Journal Name
Journal Of Educational And Psychological Researches
Synthesis of 1,3 – Diazepine -4-7 diones Analogue to valium which is used for the control of anxiety, tension states and an antidepressant
...Show More Authors

Oxazepine [1] is non – nomologous seven –member ring  that contain two netroatoms (oxygen and nitrogen ). Meanwhile diazepine [2] contains to nitrogen atoms in seven – member  ring.

       
     
   
 

 

 

 

 

 

 

Diazepam (valium) [3] is used to relive anxiety tension associated with anxiety disorder and muscle spasms (1, 2, 3

... Show More
View Publication Preview PDF
Publication Date
Sun Dec 03 2017
Journal Name
Al-khwarizmi Engineering Journal
Performance of Turbo-Codes with Some Proposed Interleaver Schemes
...Show More Authors

This paper describes a number of new interleaving strategies based on the golden section. The new interleavers are called golden relative prime interleavers, golden interleavers, and dithered golden interleavers. The latter two approaches involve sorting a real-valued vector derived from the golden section. Random and so-called “spread” interleavers are also considered. Turbo-code performance results are presented and compared for the various interleaving strategies. Of the interleavers considered, the dithered golden interleaver typically provides the best performance, especially for low code rates and large block sizes. The golden relative prime interleaver is shown to work surprisingly well for high puncture rates. These interleav

... Show More
View Publication Preview PDF
Publication Date
Wed Feb 01 2023
Journal Name
Baghdad Science Journal
Synthesis and Structural Determination of 6-O-prop-2-ynyl-1,2:3,4-di-O-Isopropylidene-α-D-Galactose
...Show More Authors

In this work, an important sugar alkynyl ether has been synthesized in two subsequent steps starting from commercially available D-galactose (3). This kind of compounds is highly significant in the synthesis of biologically active molecules such as 1,2,3-triazole and isoxazoles. In the first step, galactose (3) was reacted with acetone in the presence of anhydrous copper (II) sulfate to produce 1,2:3,4-di-O-isopropylidene-α-D-galactose (4) in good yield. The latter was reacted with excess of 3-bromoprop-1-yne in DMF in the presence of NaOH pellets to afford the target molecule 5 in a very good yield. The temperature of this step is crucial in determining the reaction yi

... Show More
View Publication Preview PDF
Scopus Clarivate Crossref
Publication Date
Fri Mar 01 2024
Journal Name
Baghdad Science Journal
Synthesis and Characterization of New 2-amino-5-chlorobenzothiazole Derivatives Containing Different Types of Heterocyclic as Antifungal Activity
...Show More Authors

Nine new compounds of 2-amino-5-chlorobenzothiazole derivatives were synthesized. These new compounds were formed through the reaction of 2-amino-5-chlorobenzothiazole 1 with ethyl chloroacetate and KOH, which gave an ester derivative 2, followed by refluxing compound 2 with hydrazine hydrate to afford hydrazide derivative 3. The reaction of compound 3 with CS2 and KOH gave 1,3,4-oxadiazole-2-thiol derivative 4, and then the reaction of compound 2 with thiosemicarbazide to produce compound 5  then treated it with 4%NaOH led to ring closure to provide 1,2,4-triazole-3-thiol derivative

... Show More
View Publication Preview PDF
Scopus (4)
Crossref (2)
Scopus Crossref
Publication Date
Fri Apr 01 2022
Journal Name
Baghdad Science Journal
Determining the Mobility of some Essential Elements in Saffron (Crocus sativus L.) by the Neutron Activation Analysis
...Show More Authors

The main purpose of this investigation is to evaluate the concentrations of six essential metals (Na+, Mg2+, K+, Ca2+, Fe2+ and Zn2+) in saffron and a farm soil using the neutron activation analysis (NAA) as a nuclear spectrometry method. The stratified random sampling method was used here. The NAA results showed the well uptake of Mg2+, K+, Ca2+, Fe2+, and Zn2+ in saffron, which is lower than the toxicity range. Based on the contamination factor and geoaccumulation index, soil contamination levels were determined uncontaminated by Zn, moderately contaminated by Na+ and Fe2+, and strongly contamin

... Show More
View Publication Preview PDF
Scopus (3)
Crossref (3)
Scopus Clarivate Crossref
Publication Date
Sun Sep 01 2019
Journal Name
Baghdad Science Journal
Synthesis, Characterization and Antimicrobial Activity Study of Some New Substituted Benzoxazole Derivatives
...Show More Authors

This research included the preparation of 2-mercaptobenzoxazole (N1) by the reaction of ortho-aminophenol with carbon disulfide in an alcoholic potassium hydroxide solution. The 2-mercapto benzoxazole (N1) was then treated with hydrazine to obtain the 2-hydrazino benzoxazole (N2). A number of hydrazones (N3-N5) were prepared through the reaction of N2 with different benzaldehydes. The compound (N6) was also prepared whereby the ring closing of hydrazone (N3) using chloroacetylchloride, while the compound (N7) was prepared by treating 2-hydrazino benzoxazole with acetylacetone. When the compound (N1) was treated with formaldehyde, it afforded the compound (N8). Also, the N9 was obtained from the reaction of N1 with chloroacetic acid in th

... Show More
View Publication Preview PDF
Scopus (12)
Crossref (10)
Scopus Crossref
Publication Date
Wed Mar 10 2021
Journal Name
Baghdad Science Journal
DFT Calculations and Experimental Study to Inhibit Carbon Steel Corrosion in Saline Solution by Quinoline-2-One Derivative: Carbon Steel Corrosion
...Show More Authors

A theoretical and protection study was conducted of the corrosion behavior of carbon steel surface with different concentrations of the derivative (Quinolin-2-one), namly (1-Amino-4,7-dimethyl-6-nitro-1H-quinolin-2-one (ADNQ2O)). Theoretically, Density Functional Theory (DFT) of B3LYP/ 6-311++G (2d, 2p) level was used to calculate the optimized geometry, physical properties and chemical inhibition parameters, with the local reactivity to predict both the reactive centers and to locate the possible sites of nucleophilic and electrophilic attacks, in vacuum, and in two solvents (DMSO and H2O), all at the equilibrium geometry. Experimentally, the inhibition efficiencies (%IE) in the saline solution (of 3.5%) NaCl were st

... Show More
View Publication Preview PDF
Scopus (18)
Crossref (3)
Scopus Clarivate Crossref