Preferred Language
Articles
/
lxaRxIsBVTCNdQwCFN1H
Synthesis, characterization and liquid crystalline properties of novel benzimidazol-8-hydroxyquinoline complexes
...Show More Authors

The synthesis, characterization and liquid crystalline properties of N4,N40-bis((1 H-benzo[d]imidazol-2- yl)methyl)-3,30-dimethyl-[1,10-biphenyl]-4,40-diamine and of their corresponding Mn(II), Fe(II), Ni (II), Cu(II), and Zn(II) complexes are described. The ligand and complexes have been characterized by elemental analysis, magnetic susceptibility measurements (meff), conductometric measurements and Fourier Transform Infrared (FTIR), Nuclear Magnetic Resonance (1H NMR), (13C-NMR) and UV–Vis spectroscopy. Spectral investigations suggested octahedral coordination geometrical arrangement for M(II) complexes. The phase transition temperatures were detected by differential scanning calorimetry (DSC) analysis and the phases are confirmed by optical polarizing microscopy (POM). The DSC and POM supported the mesomorphic properties of the uncoordinated ligand in which the enantiotropic smectic phases were recorded. However, not all of their corresponding M(II) complexes are liquid crystal.

Preview PDF
Quick Preview PDF
Publication Date
Tue Mar 28 2017
Journal Name
Iraqi Journal Of Pharmaceutical Sciences ( P-issn 1683 - 3597 E-issn 2521 - 3512)
Synthesis and Preliminary Antimicrobial Study of 2-Amino-5-Mercapto-1,3,4-Thiadiazole Derivatives
...Show More Authors

Nitrogen heterocycles are of a special interest because they constitute an important class of natural and non natural products, many of which exhibit useful biological activities.Among these nitrogen heterocycles are 1, 3, 4-thiadiazole containing compounds. The therapeutic effects of these derivatives have been well studied for a number of pathological conditions including inflammation, pain, or hypertension. Moreover, synthesis of thiadiazoles has attracted wide-spread attention due to their diverse applications as antibacterial, anticancer, antifungal anti-inflammatory and antidepressant agents.According to this information’s new derivatives of 1, 3, 4-thiadiazole were designed and synthesized and in the hope of having some act

... Show More
View Publication Preview PDF
Crossref (2)
Crossref
Publication Date
Thu Mar 30 2017
Journal Name
Iraqi Journal Of Pharmaceutical Sciences ( P-issn 1683 - 3597 E-issn 2521 - 3512)
Synthesis of New Opioid Analgesic Peptide Analogues to Enkephalin (Leucine- and Methionine-Enkephalin)
...Show More Authors

A small number of researches were done in the design and synthesis of enkephalin analogues that are able to resist degradation effect of proteolytic enzymes with good bioavailability and half-lives.Through studying structure activity relationships we tried to incorporate phthalyl group, tryptophan and lysine amino acids in different positions in the basic backbone structure of the naturally occurring opioid Leu5- and Met5- enkephalin, in the hope that such insertion of these amino acids could induce interesting addition in the biological activity of these analogues with enhancement of their bioavailability, in addition to decrease side effects as addiction liability.

These synthesized peptides are:

    ... Show More
    View Publication Preview PDF
    Crossref
    Publication Date
    Thu Oct 20 2022
    Journal Name
    2022 International Symposium On Multidisciplinary Studies And Innovative Technologies (ismsit)
    Effect of Gamma Radiation and Borax on Mechanical Properties of Polyvinyl Alcohol and Chitosan Blend Film
    ...Show More Authors

    The creation and characterisation of biodegradable blend films based on chitosan and polyvinyl alcohol for application in a range of packaging is described. The compatibility between the chitosan and PVA polymers was good. Composite films had a compact and homogeneous structure, according to the morphology analysis. The mechanical test result of PVA/CH at concentrations 5% showed, that The higher values of TS recorded in sample (p1, with 40 MPa) while the lower values appeared in sample (p9, with 22.09 MPa), the TS decreased gradually as the amount of PVA increased in blend film. While the blend film of pure Chitosan exhibits a poor mechanical strength which makes it a poor candidate for packaging but Blending CH with PVA together improved

    ... Show More
    View Publication
    Scopus (1)
    Scopus Crossref
    Publication Date
    Fri Nov 29 2019
    Journal Name
    Iraqi Journal Of Physics
    A comparison study of the Structural and magnetic properties of pure Ni metal and NiZnMn ferrite
    ...Show More Authors

    The magnetic properties of a pure Nickel metal and Nickel-Zinc-Manganese ferrites having the chemical formula Ni0.1(Zn0.4Mn0.6)0.9Fe2O4 were studied. The phase formation and crystal structure was studied by using x-ray diffraction which confirmed the formation of pure single spinel cubic phase with space group (Fd3m) in the ferrite. The samples microstructure was studied with scanning electron microstructure and EDX. The magnetic properties of the ferrite and nickel metal were characterized by using a laboratory setup with a magnetic field in the range from 0-500 G. The ferrite showed perfect soft spinel phase behavior while the nickel sample showed higher magnetic loss an

    ... Show More
    View Publication Preview PDF
    Crossref
    Publication Date
    Thu Oct 01 2009
    Journal Name
    Iraqi Journal Of Physics
    Crystal Growth of Semiconductor CuAl0.4Ti0.6Se2 and studding the Structural Properties of its Alloy and Thin Film
    ...Show More Authors

    Tetragonal compound CuAl0.4Ti0.6Se2 semiconductor has been prepared by
    melting the elementary elements of high purity in evacuated quartz tube under low
    pressure 10-2 mbar and temperature 1100 oC about 24 hr. Single crystal has been
    growth from this compound using slowly cooled average between (1-2) C/hr , also
    thin films have been prepared using thermal evaporation technique and vacuum 10-6
    mbar at room temperature .The structural properties have been studied for the powder
    of compound of CuAl0.4Ti0.6Se2u using X-ray diffraction (XRD) . The structure of the
    compound showed chalcopyrite structure with unite cell of right tetragonal and
    dimensions of a=11.1776 Ao ,c=5.5888 Ao .The structure of thin films showed

    ... Show More
    View Publication Preview PDF
    Publication Date
    Tue Oct 01 2019
    Journal Name
    Ceramics International
    A first-principles study of the electronic, structural, and optical properties of CrN and Mo:CrN clusters
    ...Show More Authors

    View Publication
    Scopus (15)
    Crossref (15)
    Scopus Clarivate Crossref
    Publication Date
    Tue Feb 12 2019
    Journal Name
    Iraqi Journal Of Physics
    Structural, electrical and optical properties of CdS thin films and the effect of annealing on photoconductivity
    ...Show More Authors

    Cadmium sulfide (CdS) thin films with n-type semiconductor characteristics were prepared by flash evaporating method on glass substrates. Some films were annealed at 250 oC for 1hr in air. The thicknesses of the films was estimated to be 0.5µ by the spectrometer measurement. Structural, morphological, electrical, optical and photoconductivity properties of CdS films have been investigated by X-ray diffraction, AFM, the Hall effect, optical transmittance spectra and photoconductivity analysis, respectively. X-ray diffraction (XRD) pattern shows that CdS films are in the stable hexagonal crystalline structure. Using Debye Scherrerś formula, the average grain size for the samples was found to be 26 nm. The transmittance of the

    ... Show More
    View Publication Preview PDF
    Crossref
    Publication Date
    Tue Jul 17 2018
    Journal Name
    Materials Research Express
    Structural, electronic and thermodynamic properties of bulk and surfaces of terbium dioxide (TbO<sub>2</sub>)
    ...Show More Authors

    This contribution reports a comprehensive investigation into the structural, electronic and thermal properties of bulk and surface terbium dioxide (TbO2); a material that enjoys wide spectra of catalytic and optical applications. Our calculated lattice dimension of 5.36 Å agrees well with the corresponding experimental value at 5.22 Å. Density of states configuration of the bulk structure exhibits a semiconducting nature. Thermo-mechanical properties of bulk TbO2 were obtained based on the quasi-harmonic approximation formalism. Heat capacities, thermal expansions and bulk modulus of the bulk TbO2 were obtained under a wide range of temperatures and pressures. The dependency of these properties on operational pressure is very evident. Cle

    ... Show More
    View Publication
    Scopus (18)
    Crossref (15)
    Scopus Clarivate Crossref
    Publication Date
    Tue Feb 05 2019
    Journal Name
    Journal Of The College Of Education For Women
    The study of physical and chemical properties of wells water in district of Samarra
    ...Show More Authors

    The Study was achieved adjectives physical and chemical water wells in the district of
    Samarra , where a study has 42 sample groundwater in different regions of the judiciary
    randomly distributed all over the judiciary and examined in vitro.
    The study showed that the quality of groundwater in the general area of study
    Kipritateh punctuated Klordih water quality and other quality Bicarboonatih.
    Varied the key components of groundwater in the study area in concentrations
    between periods of rain and drought, especially because of the cation ion exchange processes
    as well as mitigation as a result of filtering rain water and dominated the calcium ion,
    followed by sodium.
    As for the negative ions has dominated ion s

    ... Show More
    View Publication Preview PDF
    Publication Date
    Thu Apr 01 2021
    Journal Name
    Biochemical And Cellular Archives
    Design, Synthesis and Antibacterial Evaluoation of mutual Prodrugs of Antioxidants With Different quinolone Antibiotics
    ...Show More Authors

    Scopus (3)
    Scopus