The tax certainty base is one of the rules based on the proven tax system so that it must be taken to consider when the tax texts are being confused the absence of causes the effects of astate, The end sought by tax certainty rule is to make the tax law fixed clear, precise, accessible and recognizable.Throught that the aim of the legislation isaccomplished and the taxpayers guarantee about their right and the do the obligation imposed on them.All this is achieved by avoiding continuous amendments to tax laws and attention to legal formulation, so that tax laws are clear free from mystery, confusion and understandable for all people and easily implemetable.
Eight different Dichloro(bis{2-[1-(4-R-phenyl)-1H-1,2,3-triazol-4-yl-κN3]pyridine-κN})iron(II) compounds, 2–9, have been synthesised and characterised, where group R=CH3 (L2), OCH3 (L3), COOH (L4), F (L5), Cl (L6), CN (L7), H (L8) and CF3 (L9). The single crystal X-ray structure was determined for the L3 which was complemented with Density Functional Theory calculations for all complexes. The structure exhibits a distorted octahedral geometry, with the two triazole ligands coordinated to the iron centre positioned in the equatorial plane and the two chloro atoms in the axial positions. The values of the FeII/III redox couple, observed at ca. −0.3 V versus Fc/ Fc+ for complexes 2–9, varied over a very small potential range of 0.05 V.
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