A Genetic Algorithm optimization model is used in this study to find the optimum flow values of the Tigris river branches near Ammara city, which their water is to be used for central marshes restoration after mixing in Maissan River. These tributaries are Al-Areed, AlBittera and Al-Majar Al-Kabeer Rivers. The aim of this model is to enhance the water quality in Maissan River, hence provide acceptable water quality for marsh restoration. The model is applied for different water quality change scenarios ,i.e. , 10%,20% increase in EC,TDS and BOD. The model output are the optimum flow values for the three rivers while, the input data are monthly flows(1994-2011),monthly water requirements and water quality parameters (EC, TDS, BOD, DO and pH).The objective function adopted in the optimization model is in a form the sum of difference in each of the 5 water quality parameters, resulting from the
mixing equation of the waters of the rivers, from the accepted limits of these parameters , weighted by a penalty factor assigned for each water quality parameter according to its importance. The adopted acceptable limits are 1500,1000, 6,4 and 7, while the penalty factors are 1,0.8,0.8,0.8,and 0.2 for EC,TDS,BOD,DO,and pH respectively. The constraints adopted on the decision variables which the monthly flows of the three rivers are those that provide the monthly demands downstream each river, and not exceed a maximum monthly flow
limits. The maximum flow limits adopted are for three flow cases, wet, average and dry years. For each flow case three scenarios for the monthly water quality parameters were adopted , the average values(scenario 1),the 10% increase in EC,TDS, and BOD (Scenario
2),and the 20% increase in these three water quality parameters (Scenario 3). Hence nine cases are adopted and for each an optimum monthly flows are found for each river. The genetic optimization model adopt a variable number of population of 100 to 1000 in a step of
100,0.8 and 0.2 cross over and mutation rates, and three iterations to reach the stable optimum solutions. The results indicates that the flow analysis shows a significant decrease in the flow values of the three rives after year 2000,hence, the flow values for the period of (1994-1999), are excluded and the only used values are those for (2000-2011). The estimated monthly demands exhibits low variation. The observed optimum monthly flow values decrease in general as the case flow changed from wet to normal and dry cases. The change in Scenarios from S1 to S2 and S3 , do not necessarily increase all the required optimum monthly flow values. The obtained minimum objective functions do not exhibits a certain trend with the change in the flow cases and/or the change in the scenarios.
Tetradentate bidentate Schiff base (L1) from 4-amino-1.5-dimethyl-2-phenyl-1.2-dihydropyrazol-3-one and 2-(1H-indol-3-yl)-ethylamine and benzene-1.4-dicarbaldehyde was synthesized and characterized as novel antioxidants. The Schiff base and its metal complexes Mn(II), Co(II),Cu(II), Zn(II), Cd(II) and Re(V) have been characterized by elemental microanalysis, metal content, chloride-containing, molar conductance, FT-IR, 1H-NMR, UVVis spectroscopy, magnetic susceptibility, mass spectra (MS), and thermal analysis (TGA). The structures of the prepared compounds were observed by antioxidant activities of the Schiff bases derivatives were investigated due to the imine group (-C=N-) and promising results were obtained. The results confirmed that c
... Show MoreSemiconductor-based photocatalytic processes are widely applied as ecofriendly technology for degrading organic pollutants. Establishing photocatalytic heterojunctions with Z-type photocarriers transfer pathways is projected to be a superb strategy to enhance photocatalytic behavior. In this paper, novel and stable (0D/2D) heterojunctions of CoS-embedded boron-doped g-C3N4 (CoS/BCN) with a high rate of charges transfer/separation were assembled for degradation of malachite green dye (MG). The CoS/BCN photocatalyst achieves a photodegradation efficiency of 96.9 % within 1 h of LED illumination, which is 2.5 and 1.4-fold enhancement compared with bare g-C3N4 and BCN, respectively. Besides, the results of species-trapping trials exhibited that
... Show MoreA new optoelectronic flow injection method is proposed for the determination of ferrous ions (Fe 2+ ) based on thiocyanate complexation to form a deep-red FeSCN 2+ complex.
Innovative various Schiff bases and their Co(II), Ni(II) and Cu(II) and Hg(II) compounds made by the condensation of 4-amino antipyrine with derived aminobenzoic acid (2-aminobenzoic acid, 3-aminobenzoic acid, and 4-aminobenzoic acid ) have been prepared by conventional approaches. These complexes were described by magnetic sensibility analysis, FT-IR spectra, and molar-conductance and elemental analysis. Analytical values appeared which the mixed-ligand complexes presented ratio about 2:1 (ligand: metal) with the chelation 4 or 6. The prepared compounds offered a good effect on the organisms; bacteria Staphylococcus-aurous, Escherichia-coli and fungi C. albicans, A. niger. Also, the biological products signalize which the mixed compl
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