Background: Diabetes mellitus has been suggested
to be the most common metabolic disorder
associated with magnesium deficiency, and because
available data suggest that adverse outcomes are
associated with hypomagnesemia, it is prudent that
routine surveillance for hypomagnesemia be done
and the condition be treated whenever possible.
Aim of the study:To explore the serum Mg
concentrations of diabetic patients and healthy
controls in our locality.
Mehtods: One hundred and forty four diabetic
patients (22 with type I and 122 with type II diabetes
mellitus) recruited from the outpatient diabetes clinic
at the Specialized Center For Endocrine DiseasesBaghdad (62 patients), National Diabetes Center-Al
Mustansiria University (20 patients), and from
private endocrinologic practice clinics in Baghdad
(62 patients), during the period from 1st October
2005 to 30th April 2006. Ninety non-diabetic healthy
controls matched for age and sex were participated in
this study. Exclusion criteria for both groups
included diarrhea and loop diuretics. None were
taking Mg supplements. Level of Mg and Albumin
were determined spectrophotometerically in the
same serum samples.
Results: Mean serum Mg concentrations of the
diabetics was significantly lower than in controls
(p<0.001). Serum albumin was not a significant
predictor of serum Mg neither among diabetic
patients (r = 0.005) nor control subjects (r = 0.139).
In 88.9% of the diabetic patients and 11.1% of the
control subjects serum Mg concentrations were
below the normal reference range of 0.70 mmol/L.
The prevalence is increased when hypomagnesemia
is defined by a reference limit of 0.75 mmol/L
(98.6% and 28.9 % for diabetics and controls,
respectively), a further higher prevalence among
controls (91.1 %) was noted when 0.80 mmol/L is
adopted as the lower normal limit. All diabetics
(100%) and controls (100%) were identified as
hypomagnesemic with a lower reference limit of
0.90 mmol/L.
Conclusion: The tremendous hot climate of ours,
can be suggested as an influential cause for increased
Mg losses, and may provide a coherent explanation
for the exceedingly high prevalence of
hypomagnesemia observed in diabetic and control
subjects participated in this study. Which therefore
may suggest an inevitable requirement for
magnesium supplementation to avert
hypomagnesemia, not only among diabetics, but as
well for controls, particularly through the hot
summer episode
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A novel Schiff base ligand (DBC) synthesized from 4-chlorobenzoic acid, along with its Cu (II) and Co (II) complexes, was prepared and characterized using FT-IR, 1H and 13C-NMR, UV-Vis spectroscopy, as well as magnetic and conductivity measurements. Based on this, a tetrahedral structure of [M(DBC)Cl2] was proposed for the complexes. Antioxidant activity of the compounds was assessed and compared to ascorbic acid, revealing that the copper complex exhibited superior antioxidant properties compared to the cobalt complex and the ligand. Furthermore, the antibiofilm potential of the copper and cobalt complexes was assessed against five clinically relevant bacterial species (P.aeruginosa, E.coli, K.pneumoniae, S.aureus and S.typhi) usin
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New chelating ligand derived from triazole and its complexes with metal ions Rhodium, Platinum and Gold were synthesized. Through a copper (I)-catalyzed click reaction, the ligand produced 1,3-dipolar cycloaddition between 2,6-bis((prop-2-yn-1-yloxy) methyl) pyridine and 1-azidododecane. All structures of these new compounds were rigorously characterized in the solid state using spectroscopic techniques like: 1HNMR, 13CNMR, Uv-Vis, FTIR, metal and elemental analyses, magnetic susceptibility and conductivity measurements at room temperature, it was found that the ligand acts as a penta and tetradentate chelate through N3O2, N2O2, and the geometry of the new complexes are identified as octahedral for (Rh & Pt) complexes a
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