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Synthesis Of New Asymmetrical Pyromellitdiimides Derived From Pyromellitic Dianhydride

This work involves the synthesis and characterization of asymmetrical pyromellitdiimide
derivatives [IV]a-f
by four sequence steps selective reaction . One mole of pyromellitic dianhydride
was reacted with one mole of various primary aromatic amines [ 4-nitro aniline , 4-chloro aniline , 4-toludine and 4-anisidine] in excess of dry acetone to produce six compounds (N-substituted-pyromellitamic monoacid) [I]a-f . These new compounds [I]a-d were converted to the corresponding
N- substituted- pyromellitmonoimide [II]a-d via their heating at (80-90)
0
C in sodium acetate-acetic
anhydride mixture .
The compounds [II]a-f
were allowed to react with one mole of another primary amines in
excess of dry acetone to give new derivatives of amic acid [II]a-d followed by intramolecular
cyclization reaction of these compounds [IV]a-f in sodium acetate-acetic anhydride system to yield the
desired asymmetrical pyromellitdiimide derivatives [IV]a-f
, the above reactions can be summarized in
Scheme 1.
All the synthesized compounds have been studied and charachterized by their melting points
, FTIR , and
1
HNMR spectroscopy (for some of them)

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Publication Date
Sun Apr 03 2005
Journal Name
Journal Of The Faculty Of Medicine Baghdad
Early Embryology of the Prechordal Region

Background: Prechordal plate is important midline structure in the head region. It has been shown that it plays a bivotal role in the development of the brain and the eyes.
Aim of study: There is confunsion, in the literatures and textbooks concerning of terms: prechordal plate, prechordal mesoderm and the Buccopharyngeal membrane. The aim of this work is to study is based on histological changes of the early stages of the chick embryo hoping to illuminate these aspects especially after the recent revival of attention to the importance of this region in the process of induction of the brain region of the newral tub & the development of the prosencephalon & the eyes as shown by genes activities & expression in the prechorda

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Publication Date
Mon Sep 30 2002
Journal Name
Iraqi Journal Of Chemical And Petroleum Engineering
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Publication Date
Sun May 21 2017
Journal Name
Ibn Al-haitham Journal For Pure And Applied Sciences
Bayesian Analyses of Ridge Regression Prooblems

   A Bayesian formulation of the ridge regression problem is considerd, which derives from a direct specification of prior informations about parameters of general linear regression model when data suffer from a high degree of multicollinearity.A new approach for deriving the conventional estimator for the ridge parameter proposed by Hoerl and Kennard (1970) as well as  Bayesian estimator  are presented. A numerical example is studied in order to   compare the performance of these estimators.

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Publication Date
Mon Sep 02 2019
Journal Name
Journal Of Legal Sciences
Impact of error in criminal sin

The basis of criminalization hi the penal code is the protection of rights whether the rights are related to human life or its property or the rights related to the protection of public property any attack on these rights is a crime the crime does not take place unless there is a physical and moral corner  In addition the criminal intent of the offender must be available to the offender ie that he has knowledge of all the crimes  of the crime as one of the elements of the intention But what if the person was wrong during the commission of the act the elements of the crime or all of it does this affect the criminal intent of the perpetrator or not since the importance of organizing the provisions of error and the impact of it wh

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Publication Date
Sun Jan 03 2016
Journal Name
Journal Of Educational And Psychological Researches
Test the effectiveness of Method EMDR

Our country faced lots of crises specially Wars and still living under the traumatic events. This would result in psychological disorder specially the Acute Stress Disorder (ASD). That’s if not treated, it will turn to be over Post Traumatic Stress Disorder(PTSD). Also not mentioning the shortage of recourses speaks about war and crises. That treat with its inflections psychologically and sociologically theses cases if happened.

The importance of this study arise through it is objective to introduce a program for EMDR which give benefit for treat in health, social, educational institutes.

Aims:

The objective of this Study is the identification of a Test the effectiveness of Eye Movement Desensi

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Publication Date
Sat Apr 13 2019
Journal Name
Journal Of The College Of Languages (jcl)
A Study of Collocation in English

We used to think of grammar as the bones of the language and vocabulary as the flesh to be added given that language consisted largely of life generated chunks of lexis. This “skeleton image” has been proverbially used to refer to that central feature of lexis named collocation- an idea that for the first 15 years of language study and analysis gave a moment‟s thought to English classroom material and methodology.
The work of John Sinclair, Dave Willis, Ron Carter, Michael McCarthy, Michael Lewis, and many others have all contributed to the way teachers today approach the area of lexis and what it means in the teaching/learning process of the language. This also seems to have incorporated lexical ideas into the teaching mechanis

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Publication Date
Sun Oct 02 2016
Journal Name
Journal Of Educational And Psychological Researches
Aesthetic awareness among teachers of kindergarten

All - Mighty Allah is beautiful and loves beauty and  Man is the only living  that is given by  the gift of Almighty Allah  the ability to awareness of beauty and the taste of  everything which recognized by him  around all aspects of life.

So the  children have more  ability  than others towards  feeling the  sense of beauty and the distinction between the beautiful and the ugly understanding , as they are attracted to the beauty , so we  should promote and encourage  their sense of beauty in future  the beauty in behavior , in psychology and in the community, as well.

This is definitely be done through all of

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Publication Date
Fri Jul 01 2016
Journal Name
Journal Of Engineering
FRACTURE PROPERTIES OF LOCAL ASPALT CONCRETE

The local asphalt concrete fracture properties represented by the fracture energy, J-integral, and stress intensity factor are calculated from the results of the three point bending beam test made for pre notches beams specimens with deformation rate of 1.27 mm/min. The results revealed that the stress intensity factor has increased by more than 40% when decreasing the testing temperature 10˚C and increasing the notch depth from 5 to 30mm. The change of asphalt type and content have a limited effect of less than 6%.

 

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Publication Date
Sat Oct 13 2018
Journal Name
Bulletin Of The Iraq Natural History Museum (p-issn: 1017-8678 , E-issn: 2311-9799)
SURVEY OF BRACHYCERA FLIES ON ALFALFA

     Brachycerous Dipteran species on alfalfa plant Medicago sativa surveyed in several regions of Iraq from March to November 2012. The study was registered 14 species belonging to nine genera and four families. The results showed that Limnophra quaterna, Atherigona laevigata and Atherigona theodori as new records to Iraq and new pests of alfalfa.

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Publication Date
Sat Dec 30 2023
Journal Name
Iraqi Journal Of Science
Complex of Lascoux in Partition (4,4,4)

In this paper the diagrams and divided power of the place polarization
(k )
ij  , with
its capelli identities have been used, to study the complex of Lascoux in case of the
partition (4,4,4).

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