Accurate description of thermodynamic, structural, and electronic properties for bulk and surfaces of ceria (CeO₂) necessitates the inclusion of the Hubbard parameter (U) in the density functional theory (DFT) calculations to precisely account for the strongly correlated 4f electrons. Such treatment is a daunting task when attempting to draw a potential energy surface for CeO₂-catalyzed reaction. This is due to the inconsistent change in thermo-kinetics parameters of the reaction in reference to the variation in the U values. As an illustrative example, we investigate herein the discrepancy in activation and reaction energies for steps underlying the partial and full hydrogenation of acetyl

Background: The posterior slope of the articular eminence of completely edentulous patients compared to patients with maintained occlusion shows significant flattening. This study aimed to correlate between the flattening of the posterior slope of the articular eminence, with dental status, age, genders, on both sides using computed tomography. Materials and Methods: The sample of the present study was a total of 117 Iraqi subjects, who admitted to the maxillofacial department at Al-Sadr Teaching Hospital in Al-Najaf city. The examination was performed on CT scanner; the eminence inclination was measured in two methods using sagittal section. Results: Clinically, the inclination of articular eminence was higher in edentulous subjects than i

This work describes the synthesis of novel ligand (H₂L²) (4-((2-hydroxy-5-nitrophenyl)imino)methyl)-5(hydroxymethyl)-2methylpyridin-3-ol)  type (NOO) donor atoms. When it coordinates with metal ions[V²⁺,Mn²⁺,Fe²⁺,Co²⁺,Ni²⁺,Cu²⁺and Pt⁴⁺] with the general formula K₂[M(L²)₂].XH₂O and K₂[VO(L²)(OSO₃)].H₂O . This ligand can form tridentate structures. The ligand was synthesized from the reaction of pyridoxal hydrochloride with 2-amino-4-nitrophenol in ethanol (as a solvent) at a mole ratio of 1:1 and thoroughly mixed and refluxed for 6-8  hrs . The reaction

New types of modules named Fully Small Dual Stable Modules and Principally Small Dual Stable are studied and investigated. Both concepts are generalizations of Fully Dual Stable Modules and Principally Dual Stable Modules respectively. Our new concepts coincide when the module is Small Quasi-Projective, and by considering other kind of conditions. Characterizations and relations of these concepts and the concept of Small Duo Modules are investigated, where every fully small dual stable R-module M is small duo and the same for principally small dual stable.

Let R be a ring and let M be a left R-module. In this paper introduce a small pointwise M-projective module as generalization of small M- projective module, also introduce the notation of small pointwise projective cover and study their basic properties.
.

    Let R be a commutative ring with unity and let M, N be unitary R-modules. In this research, we give generalizations for the concepts: weakly relative injectivity, relative tightness and weakly injectivity of modules. We call M weakly N-quasi-injective, if for each f  Hom(N,) there exists a submodule X of  such that  f (N)  X ≈ M, where  is the quasi-injective hull of M. And we call M N-quasi-tight, if every quotient N / K of N which embeds in  embeds in M. While we call M weakly quasi-injective if M is weakly N-quasiinjective for every finitely generated R-module N.         Moreover, we generalize some properties of weakly N-injectiv