Theoretically description of the electron transfer of the electron transfer of met/mol has been investigated in this work according to the quantum theory. By using a model that is derived depending on the first order perturbation theory, the rate constant at met/mol interface can be calculated with the calculated reorganization energy. The reorganization energy that is evaluated according to the outer sphere model is based on the electstatistics potential of the molecular donor and acceptor. The molecular parameters introduced in this model are the molecular weight, mass, density, and radius of molecule have been evaluated according to the apparent molar volume using spherical approach. The theoretical results are obtained according to our model of rate constant for electron transfer, a corresponding with the experimental data for some qualilative metal/molecule interface some qualitative of the experimental studies .
The unsteady state laminar mixed convection and radiation through inclined
cylindrical annulus is investigated numerically. The two heat transfer mechanisms of
convection and radiation are treated independently and simultaneously. The outer
cylinder was kept at a constant temperature while the inner cylinder was heated with
constant heat flux. The study involved numerical solution of the governing equations
which are continuity, momentum and energy equations using finite difference method
(FDM), where the body fitted coordinate system (BFC) was used to generate the grid
mesh for computational plane. A computer program (Fortran 90) was built to calculate
the bulk Nusselt number (Nub) after reaching steady state con
The com pton profiles for Ti02 have been measured using a SCi
Am-241 compton spectrometer .A pellet of the oxide was prepared from a polycrystalline powder having a thickness of 1.54 mm ,about J 00000 counts have been accumulated at the compton peak
.Theoreti cal compton profiles have been calculated for different ionic anangements using free atom compton profile for the core electrons.The theoretical and experimental results ahrce well for (Ti/4(0 .2 arrangement which support complete transfer of valence electrons from metal to oxygen ions, i.e., full ionic &nbs
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This paper discusses Ree–Eyring fluid’s peristaltic transport in a rotating frame and examines the impacts of Magnetohydrodynamics (MHD). The results deal with systematically (analytically) applying each of the governing equations of Ree–Eyring fluid, the axial and secondary velocities, flow rate due to auxiliary stream, and bolus. The effects of some distinctive variables, such as Hartman number, heat source/sink, and amplitude ratio, are taken under consideration and illustrated through graphs.
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Flavonoid-metal complexes from the medicinal plant, Chromolaena Odorata were synthesized in this study using a standard method. Flavonoid extracts complexes, namely Mn-flavonoid complex, Co-flavonoid complex, Zn-flavonoid complex, and Cd-flavonoid complex were characterized using Fourier-Transform Infrared spectroscopy technique (FT-IR). Based on IR data, it was observed that the complexes shifted to lower frequencieswhen compared with the extract, indicating the interaction of the C=O and O-H groups during the complex formation. It was observed that the complexes were synthesized at a certain condition, which is acidic,with pH values ranging from 2.11 to 3.68. The conductance values (Λm) of the complexes were fou
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The result of concentration varying of mixture methane with argon and neon gas are believed to study the change in electrons energy distribution function and then the change of the electrons transport parameters including the drift velocity, the mean energy, characteristics energy and diffusion coefficient. In the present work,a contemporary developed computer, simulation program known as Bolsig+ is being used for calculating the electron transport parameters.
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Was appointed acid steady disintegration of organic EkandThe results proved that organic Allicand acting and Konnh solid baseBy Tgrav Pearson has possible account Maamat hardness and softness of organic Ekand
In this work ,glass-metal apparatus was designed and manufactured which used for preparing ahigh purity uranium. The reaction is simply take place between iodine vapour and uranium metal at 500C in closed system to form uranium tetra iodide which is decomposed on hot wire at high temperature around 1100C. Also another apparatus was made from Glass and used for preparing ahigh purity of UI4 more than 99.9% purity.