Valine
4-chloro benzoyl isothiocyanate
transition metal
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A new ligand [N-(4-chlorobenzoyl amino) -thioxomethyl] valine (cbv) is synthesized by reaction of 4-
chloro benzoyl iso thio cyanate with valine acid. The ligand is Characterized by elemental analysis ,FT-IR, and
13C 1H NMR spectra, some transition metals complex of this ligand were prepared and Characterized by FTIR
, UV-Visible spectra , conductivity measurement's ,magnetic susceptibility , atomic absorption and
determination of molar ratio (M:L), from results obtained , the following formula [M(cbv)2] where M+2 =Mn,
Fe ,Co , Ni , Cu,Zn,Cd, and Hg and the proposed molecular structure for these complexes as tetrahedral
geometry, except copper complex is have square planer geometry