In this study new derivatives of Schiff bases 5-8 , 1,3- oxazepine 9-16 and tetrazoles 17-19 have been synthesized from the new starting material 1 which has synthesized the reaction of one mole of dichloro acetic acid and two moles of thiophenol , the esters 2-3 were synthesized from the reaction of compound 1 with methanol or ethanol respectively in the presence of H2SO4 as catalyst then 2,2-dithiophenylaceto Hydrazide 4 were synthesized from the reaction of 2 or 3 with hydrazine hydrate 80 % , Schiff bases 5-8 were synthesized from the reaction of 4 with appropriate aldehyde or ketone .Treatment of Schiff bases with maleic and phathalic anhydride in dry benzene to give 1,3-oxazepen derivatives 9-16 and with sodium azide in tetrahydrofuran (THF) afforded tetrazole derivatives 17-19. All these compounds have been characterized from their melting pointes, FTIR , 1HNMR and compounds 1,5 and 18 by mass spectrometry . Derivatives 6,7,11,16,17 and 18 were tested against inhibition of E.coli and. Staphylococcus- aureus and were all funds to be active. Scheme (1).
This article includes the preparation of luminescence materials from rare earth (Eu ) ion doping Yttrium Oxide (Y2O3) 70% and SiO2 25% and study the characteristics of phosphors for ultraviolet to visible conversion. The phosphor materials have been synthesized by two steps: Preparing the powder by solid state method using Y2O3, SiO2 and Eu2O3 with doping materials concentration (70%, 25% and 5%) respectively and different calcination temperature (1000, 1200 and 1400 oC).
The second step is to prepare the colloid solution by dispersing the produced powder in a polyvinyl alcohol solution (4%) .
Powde
... Show MoreA simple, inexpensive, and home–built electrostatic spray deposition (ESD) system with stable cone-jet mode was used to obtain nickel oxide (NiO) thin films on glass substrates kept at temperature of 400°C. The primary precursor solution of 0.1 M concentration hydrated nickel chloride dissolved in isopropyl alcohol. The structural, optical and electrical parameters were studied. The optical absorbance spectra for the studied samples showed its maximum around 280 nm. On the other hand, thickness interferometry measurements on the tested samples showed that film thickness was around 400 nm. The optical energy gap of the prepared NiO samples was determined to be 3.75 eV and the maximum value of refractive index was determined to be 2.1 a
... Show MoreBiomimatic basic calcium phosphate ,known as Hydroxy apatite(HA), was
synthesised using calcium acetate and disodium phosphate dilute hot (boiling) solution of
both salts were added slowly to each other. A colloidal suspension formed was aged for few
days, then boiled for one hour to induced setting and coagulation of preapatite, and left to cool
until they reached room temperature.
The precipitate was filtered and washed with distilled water, then ethanol and dried.
The dried sample was calcined at 1100
o
C.The obtained solid lumps were then crushed
reground fine powder and analyzed for calcium to phosphorous ratio. X-ray analysis was
carried out to examine the solid sample. Chemical analysis for phos
This work concerned on nanocrystalline NiAl2O4 and ZnAl2O4 having spinel structure prepared by Sol–gel technique. The structural and characterization properties for the obtained samples were examined using different measurements such as X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), finally, Field emission scanning electron microscope (FESEM).The Spinel-type for two prepared compound (NiAl2O4) and (ZnAl2O4) at different calcination temperature examined by XRD. Williamson-Hall Methods used to estimate crystallite size, Average distribution crystallite size of two compound were, 34.2 nm for NiAl2O4 and32.6 for ZnAl2O4, the increase in crystallite size affecting by increasing in calcination temperature for both comp
... Show MoreHydrothermal technology has many advantages compared to other growth methods such as the availability of their simple equipment,catalyst-free growth,Environmental friendliness, less dangerous environmental, and low costs. Combine spinning method technology with Hydrothermal could improve the structural of ZnO NS by increasing the formation of ZnO NS due to influence of heat annealed treatments on the structure of ZnO NS. ZnONano-Sheets (NS)were prepared to employ hydrothermal process utilizing zinc acetate, that has the chemical composition (Zn (CH3CO2)2.2H2O),as a precursor. After preparing the material, it is deposited in two methods, the first being disti
... Show MoreFive oil sample of Mashrif and Nahr Umr Formation for Amarah oil field,
southern Iraq, were taken and analyzed in Geo Mark laboratory in USA center in
order to determine the bulk properties of crude oils and carbon isotopes for these
samples in addition to determine biomarker parameters using Gas
Chromatography(GC), and Gas Chromatography Mass Spectrometry )GCMS
(analytical technique. According to these biomarker analyses of the two formation, it
is indicated that they are non-degraded, marine, non-waxy, derived from
carbonate source and deposition in anoxic marine environment. This study also
showed that the bulk properties (terpanes and steranes) of Amarah oil field are one
family, and the source rocks contai
In the present study, pure Poly(viny1 alcohol) (PVA) and pyromellitic dianhydride (PMDA) cross linked PVA with (0,5,10,15 and 20)wt.% and doped with different molarity (5,9)M of sulfuric acid (H2SO4) were prepared by the solution casting method and were characterized as a function of frequency in the range (1-100) KHz.
The FT-IR results showed that the strong broad band observed at 3738.05 and 3857.63 cm-1 may be assigned to O-H stretching due to the strong hydrogen bond of intramolecular and intermolecular type in PVA film. When PVA is doped with 5M and 9M H2SO4, a new peak was noticed at 813 cm-1, this peak may be due to the fo
... Show MoreIn this paper, CdS/Si hetrojunction solar cell has been made by
Chemical Bath Deposition (CBD) of CdS thin film on to
monocrystalline silicon substrate. XRD measurements approved that
CdS film is changing the structure of CdS films from mixed
hexagonal and cubic phase to the hexagonal phase with [101]
predominant orientation. I-V characterization of the hetrojunction
shows good rectification, with high spectral responsivity of 0.41
A/W, quantum efficiency 90%,and specific detectivity 2.9*1014
cmHz1/2W -1 .
Piroxicam (PIR) is a nonsteroidal anti-inflammatory drug of oxicam category, used in gout, arthritis, as well as other inflammatory conditions (topically and orally). PIR is practically insoluble in water, therefore the aim is prepare and evaluate piroxicam as liquid self-nanoemulsifying drug delivery system to enhance its dispersibility and stability. The Dispersibilty and Stability study have been conducted in Oil, Surfactant and Co-surfactant for choosing the best materials to dissolve piroxicam. The pseudo ternary phase diagrams have been set at 1:1, 2:1, 3:1 as well as 4:1 ratio of surfactants and co-surfactants, also there are 4 formulations were prepared by using various concentrations of transcutol HP, cremophore EL and triacetin
... Show MoreAcute myeloid leukemia is a malignant disease results from mutation in a multipotent haemopoietic stemcell. The study aimed to investigate NPM1 and FLT3-ITD mutations in Iraqi patients with AML and correlateresults with other clinical and laboratory findings. Fifty-eight AML patients, admitted to Baghdad TeachingHospital from October 2019 till March 2020 in addition to 25 normal controls, were included in the study.A detailed history, laboratory investigations including FLT3-ITD and NPM1 mutations were collected fromand analyzed. FLT3-ITD was detected in 17.24% of patients, NPM1 mutation in 10.34%. Most of thepatients are presented with pallor. FLT3-ITD mutation had a higher blast cell count (74%) while NPM1mutation had higher WBCs
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