Preferred Language
Articles
/
jih-1675
IR and Uv-Visible Study of the Thermal Stabilization for pvc Stabilized with ( Ho,Tb and Dy ) Stearate and Synergistic Mixtures
...Show More Authors

Three  types of  metal  carboxylates  (Ho,Tb  and  Dy) stearates were LLSed  as thennal stabi lizers for PVC. Infrared spectra (1500-1900

 

)

 

cm.1

 

were   studied   for  PVC   films   stabilized   with   these   metal

 

carboxylatcs.  Two types of oxygen  were round -containing  products that were formed during  the thermal degradation  .On the other hand , the  presence  of  atmospheric  oxygen  leading  to  the  formation   of carbonyl  groups  on  the  chain  seems   to  play  a  great   role  in  the stabilization of PVC.It was found that IR spectroscopy was suitable to follow the consumption  of the carboxylatcs  within the thermal  stress periods via antisymmetrical  stretching  vi bration of COO. The thermal stability ior  the PVC in present of synergistic mixtures (Ho-Tb,Ho-Dy and Tb-Dy)  stem·ates was studied  by U l traviolet-visi ble spectra.The results indicate that these mixtures have considerable stabilization efficiency for the PVC.

View Publication Preview PDF
Quick Preview PDF
Publication Date
Sat Jun 03 2023
Journal Name
Iraqi Journal Of Science
Effect Effect Effect Effect Effect Effect Effect of Thickness on Some Physical PropertiesThickness on Some Physical PropertiesThickness on Some Physical PropertiesThickness on Some Physical PropertiesThickness on Some Physical Properties Thickness on Some
...Show More Authors

The effect of thickness variation on some physical properties of hematite α-Fe2O3 thin films was investigated. An Fe2O3 bulk in the form of pellet was prepared by cold pressing of Fe2O3 powder with subsequent sintering at 800 . Thin films with various thicknesses were obtained on glass substrates by pulsed laser deposition technique. The films properties were characterized by XRD, and FT-IR. The deposited iron oxide thin films showed a single hematite phase with polycrystalline rhombohedral crystal structure .The thickness of films were estimated by using spectrometer to be (185-232) nm. Using Debye Scherrerś formula, the average grain size for the samples was found to be (18-32) nm. Atomic force microscopy indicated that the films had

... Show More
View Publication Preview PDF