...Show More Authors
A new ligand [N- (1,5- dimethyl -3- oxo- 2 – phenyl - 2 ,3 – dihydro -1H- pyrazol -4-
ylcarbamothioyl) acetamide] (AAD) was synthesized by reaction of acetyl isothiocyanate
with 4-aminoantipyrine, The ligand was characterized by micro elemental analysis C.H.N.S.,
FT-IR ,UV-Vis and 1H-13CNMR spectra, some transition metals complex of this ligand were
prepared and characterized by FT-IR, UV-Vis spectra, conductivity measurements, magnetic
susceptibility and atomic absorption. From the obtained results the molecular formula of all
prepared complexes were [M(AAD)2(H2O)2]Cl2 (M+2 = Mn, Co, Ni, Cu, Zn, Cd and Hg),the
proposed geometrical structure for all complexes were octahedral.