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Gallium Selective PVC Membrane Electrodes Based on Crown Ethers

Gallium  selective  e lectrodes   based  on  12-crown-4  (12C4)  and benzo-15-crown-5   (B15C5)  and  plasticizers   dioctyl  phenyl phosphonate   (DOPP),   dibutyl  phosphate  (DBP),  dibutyl  phthalate (DBPH)  in  PVC  matrix  membranes  are  constructed.  Specific properties  of  the electrodes  are  studied  including  calibration  curve, slope  detection limit, concentration  range, response time and life tiMe as well as the effect of pH on electrode response. Interference for Li1  ,

Mg2+,     Zn2+,     Al 3 +,     Cr3+     on   electrode   respons.e   have   been   also

investigated.  The  polymetic   liquid  membrane  electrode   based  on

12C4 using DBPH plasticizer exhibits the best over all performances as  a  gallium  selective  electrod e  over  a  wide  concentration  range (l.O x l0-5 - 3.3x10-2 M) with Nemestian slope (20mV/decade). It has a relatively  fast response  time excellent  detection  limit (7x 1o-6M) and good  durability  (about  2  m onths).  The  electrode  revealed  a  good

 

+

 

+

 

selectivity  for Ga3

 

over a variety of other  metal  ions and could  be

 

used in a pH range of 3.0-5.0. It was used as an indicator electrode in potentiometric titration of gallium ions.

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Publication Date
Mon Jul 01 2019
Journal Name
Materials Research Express
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Publication Date
Sun Apr 26 2020
Journal Name
Iraqi Journal Of Science
Selective Image Encryption Based on DCT, Hybrid Shift Coding and Randomly Generated Secret Key

Most of today’s techniques encrypt all of the image data, which consumes a tremendous amount of time and computational payload. This work introduces a selective image encryption technique that encrypts predetermined bulks of the original image data in order to reduce the encryption/decryption time and the
computational complexity of processing the huge image data. This technique is applying a compression algorithm based on Discrete Cosine Transform (DCT). Two approaches are implemented based on color space conversion as a preprocessing for the compression phases YCbCr and RGB, where the resultant compressed sequence is selectively encrypted using randomly generated combined secret key.
The results showed a significant reduct

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Publication Date
Tue Oct 01 2024
Journal Name
Separation And Purification Technology
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Publication Date
Tue May 01 2012
Journal Name
Iraqi Journal Of Physics
Nano-Scale core effects on electronic structure properties of gallium arsenide

Ab – initio density function theory (DFT) calculations coupled with Large Unit Cell (LUC) method were carried out to evaluate the electronic structure properties of III-V zinc blend (GaAs). The nano – scale that have dimension (1.56-2.04)nm. The Gaussian 03 computational packages has been employed through out this study to compute the electronic properties include lattice constant, energy gap, valence and conduction band width, total energy, cohesive energy and density of state etc. Results show that the total energy and energy gap are decreasing with increase the size of nano crystal . Results revealed that electronic properties converge to some limit as the size of LUC increase .

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Publication Date
Tue Aug 01 2023
Journal Name
Baghdad Science Journal
The Effect of Electrospinning Parameters on Morphological and Mechanical Properties of PAN-based Nanofibers Membrane

The electrospun nanofibers membranes (ENMs) have gained great attention due to their superior performance. However, the low mechanical strength of ENMs, such as the rigidity and low strength, limits their applications in many aspects which need adequate strength, such as water filtration. This work investigates the impact of electrospinning parameters on the properties of ENMs fabricated from polyacrylonitrile (PAN) solved in N, N-Dimethylformamide (DMF). The studied electrospinning parameters were polymer concentration, solution flow rate, collector rotating speed, and the distance between the needle and collector. The fabricated ENMs were characterized using scanning electron microscopy (SEM) to understand the surface morphology and es

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Publication Date
Thu Dec 31 2020
Journal Name
Iraqi Journal Of Market Research And Consumer Protection
SYNTHESIS OF THE NEW NAPROXEN SELECTIVE ELECTRODE BASED ON IMPRINTED POLYMER USING DIFFERENT MONOMERS AND ITS DETERMINATION AT PHARMACEUTICAL PREPARATION: SYNTHESIS OF THE NEW NAPROXEN SELECTIVE ELECTRODE BASED ON IMPRINTED POLYMER USING DIFFERENT MONOMERS AND ITS DETERMINATION AT PHARMACEUTICAL PREPARATION

ABSTRACT

Naproxen(NPX) imprinted liquid electrodes of polymers are built using polymerization precipitation. The molecularly imprinted (MIP) and non imprinted (NIP) polymers were synthesized using NPX as a template. In the polymerization precipitation involved, styrene(STY) was used as monomer, N,N-methylenediacrylamide (N,N-MDAM) as a cross-linker and benzoyl peroxide (BPO) as an initiator. The molecularly imprinted membranes and the non-imprinted membranes were prepared using acetophenone(AOPH) and di octylphathalate(DOP)as plasticizers in PVC matrix. The slopes and detection limits of the liquid electrodes ranged from)-18.1,-17.72 (mV/decade and )4.0 x 10-

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Publication Date
Fri Dec 29 2017
Journal Name
Ibn Al-haitham Journal For Pure And Applied Sciences
Modification of PVC and PVC Copolymer by Substitution Imide Groups

In this work the poly vinyl imides were prepared as thermal l y stable polymers by modified PVC and PVC copolymers \'lith different cyclic imides such as naphtha imide, phtbal imide, male imide and succin imide as a pendant groups.

This method gave new polyimides, from considered  especially plastic because of their outstanding high  performance properties. As

such, they are priced well above commodity polymers such as PVC

and PVC copolymers.

All the prepared polymers were characterized by IR, UV spectroscopy, elemental analysis and chemical reactions, and thermal analysis such as DTA and TG. Physical properties and the viscosities for all prepared polyimides were determined by using DMF as a sol

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Publication Date
Thu Dec 01 2011
Journal Name
Journal Of Engineering
The Effect of Shear on the Properties of Rigid PVC

The rheological and fusion behavior of polyvinyl chloride (PVC) compounds plays a dominant role in
the processing operations and in the development of physical properties in the processed material. A
comprehensive study was made in this work to evaluate the effect of shear and thermal history on stability, mechanical and rheological properties of rigid PVC compounds. Different samples of Rigid Poly vinyl chloride including dry blend powder, granules, and bottles molded from both were examined. A study was also made on recycled RPVC where 25% of reclaimed material was continuously blended with fresh dry blend and processed for 15 cycles. Results showed that compaction of the PVC material took place in the brabender plastograph at co

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Publication Date
Tue Nov 01 2022
Journal Name
Solid State Communications
Chlorine trifluoride gas adsorption on the Fe, Ru, Rh, and Ir decorated gallium nitride nanotubes

The impact of decorating Fe, Ru, Rh, and Ir metals upon the sensing capability of a gallium nitride nanotube (GaNNT) in detecting chlorine trifluoride (CT) was scrutinized using the density functionals B3LYP and B97D. The interaction of the pristine GaNNT with CT was a physical adsorption with the sensing response (SR) of approximately 6.9. After decorating the above-mentioned metals on the GaNNT, adsorption energy of CT changed from −5.8 to −18.6, −18.9, −19.4, and −20.1 kcal/mol by decorating the Fe, Ru, Rh, and Ir metals into the GaNNT surface, respectively. Also, the corresponding SR dramatically increased to 39.6, 52.3, 63.8, and 106.6. This shows that the sensitivity of the metal-decorated GaNNT (metal@GaNNT) increased by in

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Publication Date
Tue Feb 13 2018
Journal Name
Journal Of Optics
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